CHEM 125a - Lecture 6 - Seeing Bonds by Electron Difference Density

Professor McBride uses a hexagonal “benzene” pattern and Franklin’s X-ray pattern of DNA, to continue his discussion of X-ray crystallography by explaining how a diffraction pattern in “reciprocal space” relates to the distribution of electrons in molecules and to the repetition of molecules in a crystal lattice. He then uses electron difference density mapping to reveal bonds, and unshared electron pairs, and their shape, and to show that they are only one-twentieth as dense as would be expected for Lewis shared pairs.

CHEM 125a - Lecture 5 - X-Ray Diffraction

Professor McBride introduces the theory behind light diffraction by charged particles and its application to the study of the electron distribution in molecules by x-ray diffraction. The roles of molecular pattern and crystal lattice repetition are illustrated by shining laser light through diffraction masks to generate patterns reminiscent of those encountered in X-ray studies of ordered solids.

CHEM 125a - Lecture 4 - Coping with Smallness and Scanning Probe Microscopy

This lecture asks whether it is possible to confirm the reality of bonds by seeing or feeling them. It first describes the work of “clairvoyant” charlatans from the beginning of the twentieth century, who claimed to “see” details of atomic and molecular structure, in order to discuss proper bases for scientific belief. It then shows that the molecular scale is not inconceivably small, and that Newton and Franklin performed simple experiments that measure such small distances.

CHEM 125a - Lecture 3 - Double Minima, Earnshaw's Theorem and Plum-Puddings

Continuing the discussion of Lewis structures and chemical forces from the previous lecture, Professor McBride introduces the double-well potential of the ozone molecule and its structural equilibrium. The inability for inverse-square force laws to account for stable arrangements of charged particles is prescribed by Earnshaw’s Theorem, which may be visualized by means of lines of force. J.J. Thomson circumvented Earnshaw’s prohibition on structure by postulating a “plum-pudding” atom.

CHEM 125a - Lecture 2 - Force Laws, Lewis Structures and Resonance

Professor McBride begins by following Newton’s admonition to search for the force law that describes chemical bonding. Neither direct (Hooke’s Law) nor inverse (Coulomb, Gravity) dependence on distance will do - a composite like the Morse potential is needed. G. N. Lewis devised a “cubic-octet” theory based on the newly discovered electron, and developed it into a shared pair model to explain bonding.

CHEM 125a - Lecture 1 - How Do You Know?

Professor McBride outlines the course with its goals and requirements, including the required laboratory course. To the course’s prime question “How do you know” he proposes two unacceptable answers (divine and human authority), and two acceptable answers (experiment and logic). He illustrates the fruitfulness of experiment and logic using the rise of science in the seventeenth century. London’s Royal Society and the “crucial” experiment on light by Isaac Newton provide examples.

ITAL 310 - Lecture 4 - Inferno V, VI, VII

This lecture examines Inferno IV -VII. Dante’s Limbo, modeled on the classical locus amoenus, is identified as a place of repose and vulnerability. Here, in fact, among the poets of antiquity, the pilgrim falls prey to poetic hubris by joining in their ranks. The pilgrim is faced with the consequences of his poetic vocation when he descends to the circle of lust (Inferno V), where Francesca da Rimini, in her failure to distinguish romance from reality, testifies to the dangers inherent to the act of reading.

ITAL 310 - Lecture 3 - Inferno I, II, III, IV

Professor Mazzotta introduces students to the Divine Comedy, focusing on the first four cantos of Inferno. Stylistic, thematic and formal features of the poem are discussed in the context of its original title, Comedy. The first canto is read to establish the double voice of the poet-pilgrim and to contrast the immanent journey with those described by Dante’s literary precursors. Among these is the pilgrim’s guide, Virgil.

ITAL 310 - Lecture 2 - Vita Nuova

This lecture is devoted to the Vita nuova, Dante’s autobiographical account of his “double apprenticeship” in poetry and love. The poet’s love for Beatrice is explored as the catalyst for his search for a new poetic voice. Medieval theories of love and the diverse poetics they inspired are discussed in contrast. The novelty of the poet’s final resolution is tied to the relationship he discovers between love and knowledge.

ITAL 310 - Lecture 1 - Introduction

Professor Mazzotta introduces students to the general scheme and scope of the Divine Comedy and to the life of its author. Various genres to which the poem belongs (romance, epic, vision) are indicated, and special attention is given to its place within the encyclopedic tradition. The poem is then situated historically through an overview of Dante’s early poetic and political careers and the circumstances that led to his exile. Professor Mazzotta concludes by discussing the central role Dante’s exile was to play in his poetic project.

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