CHEM 125a - Lecture 21 - Berzelius to Liebig and Wöhler (1805-1832)
Lecture 21 - Berzelius to Liebig and Wöhler (1805-1832)
Overview
The most prominent chemist in the generation following Lavoisier was Berzelius in Sweden. Together with Gay-Lussac in Paris and Davy in London, he discovered new elements, and improved atomic weights and combustion analysis for organic compounds. Invention of electrolysis led not only to new elements but also to the theory of dualism, with elements being held together by electrostatic attraction. Wöhler's report on the synthesis of urea revealed isomerism but also persistent naiveté about treating quantitative data. In their collaborative investigation of oil of bitter almonds Wöhler and Liebig extended dualism to organic chemistry via the radical theory.
Resources
Professor McBride's web resources for CHEM 125 (Fall 2008)
http://webspace.yale.edu/chem125_oyc/#L21
This website may include third-party materials pertaining to relevant topics, provided for the user's convenience. Yale does not control or take responsibility for the content of any off-site pages or linked sites.
Assignment
Reading assignments, problem sets, PowerPoint presentations, and other resources for this lecture can be accessed from Professor McBride's on-campus course website, which was developed for his Fall 2008 students. Please see Resources section below.
Lecture Chapters
- Confusion over Silicon Chloride: Discussion on Atomic Weights and Equivalents [0]
- Combustion Analysis and the Beginnings of Electrolysis [366]
- Dualism: An Organizing Principle [956]
- The Honest Experimenter and the Persistent Naivety on Quantitative Data [1387]
- Ammonium Cyanate, Urea, and the Idea of Isomerism [1758]
- Wohler, Liebig, and Transmission of Dualism via the Radical Theory [2312]
Lecture Chapters
- Confusion over Silicon Chloride: Discussion on Atomic Weights and Equivalents [0]
- Combustion Analysis and the Beginnings of Electrolysis [366]
- Dualism: An Organizing Principle [956]
- The Honest Experimenter and the Persistent Naivety on Quantitative Data [1387]
- Ammonium Cyanate, Urea, and the Idea of Isomerism [1758]
- Wohler, Liebig, and Transmission of Dualism via the Radical Theory [2312]