WEBVTT 00:02.310 --> 00:07.310 Prof: All right, today's topic is the theory of 00:07.314 --> 00:09.774 nearly everything, okay? 00:09.770 --> 00:11.430 You wanted to know the theory of everything? 00:11.430 --> 00:15.940 You're almost there, because I'm finally ready to 00:15.940 --> 00:21.200 reveal to you the laws of quantum dynamics that tells you 00:21.202 --> 00:24.212 how things change with time. 00:24.210 --> 00:27.700 So that's the analog of F = ma. 00:29.940 --> 00:34.110 and just about anything you see in this room, 00:34.110 --> 00:37.740 or on this planet, anything you can see or use is 00:37.735 --> 00:41.955 really described by this equation I'm going to write down 00:41.964 --> 00:42.724 today. 00:42.720 --> 00:47.340 It contains Newton's laws as part of it, because if you can 00:47.338 --> 00:51.398 do the quantum theory, you can always find hidden in 00:51.400 --> 00:53.630 it the classical theory. 00:53.630 --> 00:57.050 That's like saying if I can do Einstein's relativistic 00:57.054 --> 01:00.414 kinematics at low velocities, I will regain Newtonian 01:00.414 --> 01:01.324 mechanics. 01:01.320 --> 01:05.120 So everything is contained in this one. 01:05.120 --> 01:09.610 There are some things left, of course, that we won't do, 01:09.613 --> 01:11.823 but this goes a long way. 01:11.819 --> 01:14.749 So I'll talk about it probably next time near the end, 01:14.754 --> 01:16.864 depending on how much time there is. 01:16.860 --> 01:21.530 But without further ado, I will now tell you what the 01:21.534 --> 01:25.314 laws of motion are in quantum mechanics. 01:25.310 --> 01:32.030 So let's go back one more time to remember what we have done. 01:32.030 --> 01:36.880 The analogous statement is, in classical mechanics for a 01:36.882 --> 01:40.062 particle moving in one dimension, 01:40.060 --> 01:45.070 all I need to know about it right now is the position and 01:45.068 --> 01:46.408 the momentum. 01:46.410 --> 01:47.180 That's it. 01:47.180 --> 01:49.460 That's the maximal information. 01:49.459 --> 01:51.669 You can say, "What about other things? 01:51.670 --> 01:52.920 What about angular momentum? 01:52.920 --> 01:54.120 What about kinetic energy? 01:54.120 --> 01:55.470 What about potential energy? 01:55.470 --> 01:57.070 What about total energy?" 01:57.069 --> 01:59.969 They're all functions of x and p. 01:59.970 --> 02:02.130 For example, in 3 dimensions, x will 02:02.131 --> 02:05.061 be replaced by r, p will be replaced by some 02:05.063 --> 02:06.873 vector p, and there's a 02:06.867 --> 02:08.747 variable called angular momentum, 02:08.750 --> 02:11.220 but you know that once you know r 02:11.222 --> 02:14.302 and p by taking the cross product. 02:14.300 --> 02:15.490 That's it. 02:15.490 --> 02:19.000 And you can say, "What happens when I 02:19.002 --> 02:23.462 measure any variable for a classical particle in this 02:23.460 --> 02:25.860 state, x,p?" 02:25.860 --> 02:29.330 Well, if you know the location, it's guaranteed to be x 02:29.325 --> 02:31.575 100 percent, momentum is p, 02:31.575 --> 02:32.545 100 percent. 02:32.550 --> 02:34.560 Any other function of x and p, 02:34.555 --> 02:37.025 like r X p, is guaranteed to have 02:37.026 --> 02:38.236 that particular value. 02:38.240 --> 02:40.260 So everything is completely known. 02:40.258 --> 02:42.588 That's the situation at one time. 02:42.590 --> 02:46.190 Then you want to say, "What can you say about 02:46.193 --> 02:47.153 the future? 02:47.150 --> 02:49.240 What's the rate of change of these things?" 02:49.240 --> 02:54.350 And the answer to that is, d^(2)x/dt^(2) times 02:54.352 --> 02:58.822 m is the force, and in most problems you can 02:58.816 --> 03:02.466 write the force as a derivative of some potential. 03:02.468 --> 03:05.938 So if you knew the potential, 1/2kx^(2) or whatever it 03:05.942 --> 03:06.972 is, or mgx, 03:06.974 --> 03:09.574 you can take the derivative on the right hand side, 03:09.568 --> 03:13.558 and the left hand side tells you the rate of change of 03:13.561 --> 03:14.391 x. 03:14.389 --> 03:19.489 I want you to note one thing - we know an equation that tells 03:19.492 --> 03:22.812 you something about the acceleration. 03:22.810 --> 03:28.040 Once the forces are known, there's a unique acceleration. 03:28.038 --> 03:31.908 So you are free to give the particle any position you like, 03:31.914 --> 03:34.124 and any velocity, dx/dt. 03:34.120 --> 03:35.760 That's essentially the momentum. 03:35.759 --> 03:38.059 You can pick them at random. 03:38.060 --> 03:40.580 But you cannot pick the acceleration at random, 03:40.580 --> 03:43.430 because the acceleration is not for you to decide. 03:43.430 --> 03:47.950 The acceleration is determined by Newton's laws to equal the 03:47.953 --> 03:51.023 essentially the force divided by mass. 03:51.020 --> 03:53.890 That comes from the fact mathematically that this is a 03:53.885 --> 03:56.965 second order equation in time, namely involving the second 03:56.967 --> 03:57.777 derivative. 03:57.780 --> 04:01.130 And that, from a mathematical point of view, 04:01.128 --> 04:04.058 if the second derivative is determined by external 04:04.055 --> 04:06.985 considerations, initial conditions are given by 04:06.990 --> 04:09.570 initial x and the first derivative. 04:09.568 --> 04:12.858 All higher derivatives are slaved to the applied force. 04:12.860 --> 04:16.120 You don't assign them as you wish. 04:16.120 --> 04:19.540 You find out what they are from the equations of motion. 04:19.540 --> 04:23.800 That's really all of classical mechanics. 04:23.800 --> 04:26.900 Now you want to do quantum mechanics, and we have seen many 04:26.896 --> 04:29.676 times the story in quantum mechanics is a little more 04:29.675 --> 04:30.525 complicated. 04:30.528 --> 04:34.278 You ask a simple question and you get a very long answer. 04:34.279 --> 04:36.619 The simple question is, how do you describe the 04:36.617 --> 04:39.107 particle in quantum mechanics in one dimension? 04:39.110 --> 04:41.360 And you say, "I want to assign to it a 04:41.355 --> 04:43.275 function Y(x)." 04:43.279 --> 04:48.629 Y(x) is any reasonable function which can be 04:48.634 --> 04:52.774 squared and integrated over the real line. 04:52.769 --> 04:55.499 Anything you write down is a possible state. 04:55.500 --> 04:58.400 That's like saying, any x and any p 04:58.403 --> 04:59.253 are allowed. 04:59.250 --> 05:01.630 Likewise, Y(x) is nothing special. 05:01.629 --> 05:04.869 It can be whatever you like as long as you can square it and 05:04.872 --> 05:07.952 integrate it to get a finite answer over all of space. 05:07.949 --> 05:10.009 That's the only condition. 05:10.009 --> 05:13.249 And if your all of space goes to infinity, then Y 05:13.252 --> 05:15.142 should vanish a and- infinity. 05:15.139 --> 05:16.919 That's the only requirement. 05:16.920 --> 05:19.360 Then you say, "That tells me everything. 05:19.360 --> 05:23.030 Why don't you tell me what the particle is doing?" 05:23.028 --> 05:24.968 And you can say, "What do you want to 05:24.966 --> 05:25.576 know?" 05:25.579 --> 05:27.829 Well, I want to know where it is. 05:27.829 --> 05:29.729 That's when you don't get a straight answer. 05:29.730 --> 05:31.390 You are told, "Well, it can be here, 05:31.387 --> 05:33.167 it can be there, it can be anywhere else. 05:33.170 --> 05:37.790 And the probability density that it's at point x is 05:37.785 --> 05:42.315 proportional to the absolute square of Y." 05:42.319 --> 05:44.449 That means you take the Y and you square it, 05:44.446 --> 05:46.186 so it will have nothing negative in it. 05:46.190 --> 05:49.690 Everything will be real and positive, and Y itself 05:49.687 --> 05:50.747 may be complex. 05:50.750 --> 05:53.680 But this Y^(2), I told you over and over, 05:53.675 --> 05:55.975 is defined to be Y*Y. 05:55.980 --> 05:59.650 That's real and positive. 05:59.649 --> 06:01.449 Then you can say, "What if I measure 06:01.451 --> 06:03.301 momentum, what answer will I get?" 06:03.300 --> 06:05.740 That's even longer. 06:05.740 --> 06:07.770 First you are supposed to expand--I'm not going to do the 06:07.771 --> 06:11.351 whole thing too many times-- you're supposed to write this 06:11.348 --> 06:15.808 Y as some coefficient times these very special 06:15.812 --> 06:16.932 functions. 06:16.930 --> 06:20.360 In a world of size L, you have to write the given 06:20.355 --> 06:24.935 Y in this fashion, and the coefficients are 06:24.935 --> 06:31.785 determined by the integral of the complex conjugate of this 06:31.790 --> 06:38.410 function times the function you gave me, Y(x). 06:38.410 --> 06:40.850 Now I gave some extra notes, I think. 06:40.850 --> 06:42.610 Did people get that? 06:42.610 --> 06:44.820 Called the "Quantum Cookbook?" 06:44.819 --> 06:46.299 That's just the recipe, you know. 06:46.300 --> 06:51.030 Quantum mechanics is a big fat recipe and that's all we can do. 06:51.029 --> 06:53.459 I tell you, you do this, you get these answers. 06:53.459 --> 06:57.119 That's my whole goal, to simply give you the recipe. 06:57.120 --> 07:00.700 So the recipe says--what's interesting about quantum 07:00.697 --> 07:03.807 mechanics, what makes it hard to teach, 07:03.807 --> 07:08.677 is that there are some physical principles which are summarized 07:08.677 --> 07:12.017 by these rules, which are like axioms. 07:12.019 --> 07:15.349 Then there are some purely mathematical results which are 07:15.346 --> 07:16.116 not axioms. 07:16.120 --> 07:19.150 They are consequences of pure mathematics. 07:19.149 --> 07:22.079 You have to keep in mind, what is a purely mathematical 07:22.077 --> 07:23.957 result, therefore is deduced from the 07:23.956 --> 07:26.476 laws of mathematics, and what is a physical result, 07:26.478 --> 07:28.088 that's deduced from experiment. 07:28.089 --> 07:31.949 The fact that Y describes everything is a 07:31.951 --> 07:33.431 physical result. 07:33.430 --> 07:39.120 Now it tells you to write Y as the sum of these 07:39.122 --> 07:42.772 functions, and then the probability to 07:42.771 --> 07:47.691 obtain any momentum p is A_p^(2), 07:47.690 --> 07:49.640 where A_p is defined by this. 07:49.639 --> 07:52.959 The mathematics comes in in the following way - first question 07:52.961 --> 07:56.171 is, who told you that I can write every function Y in 07:56.173 --> 07:57.103 this fashion? 07:57.100 --> 07:58.530 That's called the Fourier's theorem, 07:58.529 --> 08:01.849 that guarantees you that in a circle of size L, 08:01.850 --> 08:04.500 every periodic function, meaning that returns to its 08:04.495 --> 08:06.925 starting value, may be expanded in terms of 08:06.932 --> 08:07.882 these functions. 08:07.879 --> 08:09.929 That's the mathematical result. 08:09.930 --> 08:13.500 The same mathematical result also tells you how to find the 08:13.497 --> 08:14.417 coefficients. 08:14.420 --> 08:19.170 The postulates of quantum mechanics tell you two things. 08:19.170 --> 08:23.700 A_p^(2) is the probability that you will get 08:23.704 --> 08:27.034 the value p when you measure momentum, 08:27.028 --> 08:27.708 okay? 08:27.709 --> 08:30.639 That's a postulate, because you could have written 08:30.639 --> 08:33.689 this function 200 years before quantum mechanics. 08:33.690 --> 08:37.520 It will still be true, but this function did not have 08:37.522 --> 08:41.652 a meaning at that time as states of definite momentum. 08:41.649 --> 08:43.889 How do I know it's a state of definite momentum? 08:43.889 --> 08:47.129 If every term vanished except one term, 08:47.129 --> 08:50.259 that's all you have, then one coefficient will be 08:50.255 --> 08:53.005 A something = 1, everything is 0, 08:53.010 --> 08:56.860 that means the probability for getting momentum has a non 0 08:56.856 --> 08:58.976 value only for that momentum. 08:58.980 --> 09:04.720 All other momenta are missing in that situation. 09:04.720 --> 09:07.790 Another postulate of quantum mechanics is that once you 09:07.785 --> 09:10.735 measure momentum and you get one of these values, 09:10.740 --> 09:15.180 the state will go from being a sum over many such functions, 09:15.178 --> 09:20.208 and collapse to the one term and the sum that corresponds to 09:20.208 --> 09:21.998 the answer you got. 09:22.000 --> 09:25.110 Then here is another mathematical result - p is not 09:25.109 --> 09:27.969 every arbitrary real number you can imagine. 09:27.970 --> 09:30.730 We make the requirement, if you go around on a circle, 09:30.730 --> 09:33.510 the function should come back to the starting value, 09:33.509 --> 09:35.799 therefore p is restricted to be 09:35.801 --> 09:38.651 2pℏ /L times some 09:38.649 --> 09:39.949 integer n. 09:39.950 --> 09:42.410 That's a mathematical requirement, because if you 09:42.405 --> 09:45.165 think Y ^(2) is the probability, Y should 09:45.169 --> 09:46.859 come back to where you start. 09:46.860 --> 09:49.350 It cannot get two different values of Y when you go 09:49.346 --> 09:50.216 around the circle. 09:50.220 --> 09:55.520 That quantizes momentum to these values. 09:55.519 --> 10:00.169 The last thing I did was to say, if you measure energy, 10:00.173 --> 10:02.503 what answer will you get? 10:02.500 --> 10:05.290 That's even longer. 10:05.288 --> 10:08.998 There you're supposed to solve the following equations, 10:09.000 --> 10:13.980 (((h^(2)/2m)d^(2) Y_E 10:13.977 --> 10:20.497 /dx^(2)) V(x)) Y_E(x) = 10:20.498 --> 10:24.408 EY_E(x). 10:24.408 --> 10:26.468 In other words, for energy the answer's more 10:26.471 --> 10:29.111 complicated, because before, I can tell you anything. 10:29.110 --> 10:32.040 I want you to solve this equation. 10:32.038 --> 10:35.558 This equation says, if in classical mechanics the 10:35.557 --> 10:40.097 particle was in some potential V(x) and the particle had 10:40.101 --> 10:43.131 some mass m, you have to solve this 10:43.131 --> 10:46.141 equation, then it's a purely mathematical problem, 10:46.139 --> 10:49.269 and you try to find all solutions that behave well at 10:49.268 --> 10:51.358 infinity, that don't blow up at infinity, 10:51.356 --> 10:52.456 that vanish at infinity. 10:52.460 --> 10:56.880 That quantizes E to certain special values. 10:56.879 --> 11:00.649 And there are corresponding functions, Y_E 11:00.653 --> 11:02.283 for each allowed value. 11:02.278 --> 11:05.378 Then you are done, because then you make a similar 11:05.378 --> 11:08.918 expansion, you write the unknown Y and namely some 11:08.919 --> 11:11.639 arbitrary Y that's given to you. 11:11.639 --> 11:13.369 You write it as a ΣA_E 11:13.369 --> 11:15.809 Y _E(x), 11:15.809 --> 11:18.759 where A_E is found by a similar rule. 11:18.759 --> 11:21.889 Just replace p by E and replace this 11:21.892 --> 11:23.812 function by these functions. 11:23.808 --> 11:27.138 Then if you square A_E you will 11:27.139 --> 11:30.399 get the probability you will get the energy. 11:30.399 --> 11:33.919 So what makes the energy problem more complicated is that 11:33.918 --> 11:37.688 whereas for momentum we know once and for all these functions 11:37.690 --> 11:41.400 describe a state of definite momentum where you can get only 11:41.398 --> 11:44.178 one answer, states of definite energy 11:44.178 --> 11:47.608 depend on what potential is acting on the particle. 11:47.610 --> 11:49.900 If it's a free particle, V is 0. 11:49.899 --> 11:53.859 If it's a particle that in Newtonian mechanics is a 11:53.861 --> 11:57.031 harmonic oscillator, V(x) would be 11:57.033 --> 11:59.493 �kx^(2) and so on. 11:59.490 --> 12:02.970 So you should know the classical potential and you've 12:02.967 --> 12:06.647 got it in for every possible potential you have to solve 12:06.647 --> 12:07.247 this. 12:07.250 --> 12:10.370 But that's what most people in physics departments are doing 12:10.373 --> 12:11.383 most of the time. 12:11.379 --> 12:16.489 They're solving this equation to find states of definite 12:16.493 --> 12:17.333 energy. 12:17.330 --> 12:20.940 So today, I'm going to tell you why states of definite energy 12:20.937 --> 12:22.077 are so important. 12:22.080 --> 12:23.350 What's the big deal? 12:23.350 --> 12:26.110 Why is state of momentum not so important? 12:26.110 --> 12:28.550 Why is the state of definite position not so interesting? 12:28.548 --> 12:31.348 What is privileged about the states of definite momentum? 12:31.350 --> 12:35.630 And now you will see the role of energy. 12:35.629 --> 12:41.179 So I'm going to write down for you the equation that's analog 12:41.181 --> 12:42.941 of F = ma. 12:42.940 --> 12:44.760 So what are we trying to do? 12:44.759 --> 12:51.589 Y(x) is like x and p. 12:51.590 --> 12:53.800 You don't have a time label here. 12:53.798 --> 12:57.318 These are like saying at some time a particle has a position 12:57.316 --> 12:58.326 and a momentum. 12:58.330 --> 13:00.810 In quantum theory or some time, it has a wave function 13:00.807 --> 13:01.787 Y(x). 13:01.788 --> 13:04.118 But the real question in classical mechanics is, 13:04.123 --> 13:06.903 how does x vary with time and how does p vary with 13:06.903 --> 13:07.353 time. 13:07.350 --> 13:10.960 The answer is, according to F = ma. 13:10.960 --> 13:13.340 And here the question is, how does Y vary with 13:13.339 --> 13:13.659 time? 13:13.658 --> 13:17.648 First thing you've got to do is to realize that Y itself 13:17.648 --> 13:19.898 can be a function of time, right? 13:19.899 --> 13:22.979 That's the only time you've got to ask, "What does it do 13:22.984 --> 13:23.914 with time?" 13:23.908 --> 13:27.148 So at t = 0 it may look like this. 13:27.149 --> 13:29.149 A little later, it may look like that. 13:29.149 --> 13:34.009 So it's flopping and moving, just like say a string. 13:34.009 --> 13:36.749 It's changing with time and you want to know how it changes with 13:36.745 --> 13:37.045 time. 13:39.980 --> 13:44.290 It says iℏd Y(x,t)/dt (it's 13:44.292 --> 13:47.002 partial, because this depends on 13:46.998 --> 13:52.008 x and t so this is the t derivative) = the 13:52.008 --> 13:57.858 following, [-ℏ^(2) /2m 13:57.860 --> 14:06.200 d^(2)Y/dx^(2) V(x) Y(x,t)]. 14:06.200 --> 14:09.960 That's the equation. 14:09.960 --> 14:14.610 x comma t. 14:14.610 --> 14:17.730 So write this down, because if you know this 14:17.730 --> 14:21.500 equation, you'll be surprised how many things you can 14:21.504 --> 14:22.524 calculate. 14:22.519 --> 14:25.359 From this follows the spectrum of the atoms, 14:25.363 --> 14:28.743 from this follows what makes a material a conductor, 14:28.735 --> 14:31.245 a semiconductor, a superconductor. 14:36.842 --> 14:38.052 equation. 14:38.048 --> 14:41.038 This is an equation in which you must notice that we're 14:41.039 --> 14:43.919 dealing for the first time with functions of time. 14:43.918 --> 14:45.978 Somebody asked me long back, "Where is time?" 14:45.980 --> 14:49.010 Well, here is how Y varies with time. 14:49.009 --> 14:53.229 So suppose someone says, "Here is initial 14:53.227 --> 14:55.757 Y(x) and 0. 14:55.759 --> 14:59.149 Tell me what is Y a little later, 14:59.153 --> 15:01.593 1 millisecond later." 15:01.590 --> 15:04.480 Well, it's the rate of change of Y with time multiplied 15:04.479 --> 15:05.379 by 1 millisecond. 15:05.379 --> 15:08.159 The rate of change of Y at the initial time is obtained 15:08.164 --> 15:10.684 by taking that derivative of Y and adding to it V 15:10.676 --> 15:12.436 times Y, you get something. 15:12.440 --> 15:14.900 That's how much Y changes. 15:14.899 --> 15:17.319 Multiply by Dt, that's the change in Y. 15:17.320 --> 15:20.360 That'll give you Y at a later time. 15:20.360 --> 15:22.840 This is the first order equation in time. 15:22.840 --> 15:26.620 What that means mathematically is, the initial Y 15:26.620 --> 15:29.070 determines the future completely. 15:29.070 --> 15:33.020 This is different from position where you need x and 15:33.024 --> 15:35.484 dx/dt are the initial time. 15:35.480 --> 15:39.460 The equation will only tell you what d^(2)x/dt^(2)^( )is. 15:39.460 --> 15:41.830 But in quantum mechanics, dY /dt 15:41.827 --> 15:43.967 itself is determined, so you don't get to choose 15:43.970 --> 15:44.380 that. 15:44.379 --> 15:46.679 You just get to choose the initial Y. 15:46.678 --> 15:50.908 That means an initial wave function completely determines 15:50.913 --> 15:53.943 the future according to this equation. 15:53.940 --> 15:55.080 So don't worry about this equation. 15:55.080 --> 15:59.050 I don't expect you all to see it and immediately know what to 15:59.054 --> 16:02.704 do, but I want you to know that there is an equation. 16:02.700 --> 16:03.750 That is known now. 16:03.750 --> 16:06.580 That's the analog of F = ma. If you solve this 16:06.575 --> 16:09.825 equation, you can predict the future to the extent allowed by 16:09.833 --> 16:11.033 quantum mechanics. 16:11.028 --> 16:13.458 Given the present, and the present means 16:13.462 --> 16:15.962 Y(x,0) is given, 16:15.960 --> 16:17.340 then you go to the math department and say, 16:17.340 --> 16:18.990 "This is my Y(x,0). 16:18.994 --> 16:21.174 Please tell me by some trick what is Y(x) and 16:21.174 --> 16:21.894 t." 16:21.889 --> 16:26.069 It turns out there is a trick by which you can predict 16:26.072 --> 16:30.652 Y(x) and t. Note also that this number 16:30.649 --> 16:35.069 i is present in the very equations of motion. 16:35.070 --> 16:37.960 So this is not like the i we used in electrical 16:37.956 --> 16:40.786 circuits where we really meant sines and cosines, 16:40.788 --> 16:42.448 but we took e^(t)^(q)or 16:42.446 --> 16:44.236 e^(i)^(w) ^(t), 16:44.240 --> 16:47.270 always hoping in the end to take the real part of the answer 16:47.272 --> 16:50.052 because the functions of classical mechanics are always 16:50.047 --> 16:50.507 real. 16:50.509 --> 16:53.139 But in quantum theory, Y is intrinsically 16:53.143 --> 16:56.563 complex and it cannot get more complex than that by putting an 16:56.562 --> 16:58.862 i in the equations of motion, 16:58.860 --> 17:00.250 but that's just the way it is. 17:00.250 --> 17:05.520 You need the i to write the equations. 17:05.519 --> 17:10.419 Therefore our goal then is to learn different ways in which we 17:10.423 --> 17:11.793 can solve this. 17:11.788 --> 17:13.948 Now remember, everybody noticed, 17:13.951 --> 17:17.651 this looks kind of familiar here, this combination. 17:17.650 --> 17:19.010 It's up there somewhere. 17:19.009 --> 17:20.489 It looks a lot like this. 17:20.490 --> 17:22.160 You see that? 17:22.160 --> 17:24.270 But it's not quite that. 17:24.269 --> 17:26.989 That is working on a function only of x; 17:26.990 --> 17:31.030 this is working on a function of x and t. 17:31.028 --> 17:33.328 And there are partial derivatives here and there are 17:33.334 --> 17:34.514 total derivatives there. 17:34.509 --> 17:36.019 They are very privileged functions. 17:36.019 --> 17:38.199 They describe states of definite energy. 17:38.200 --> 17:41.570 This is an arbitrary function, just evolving with time, 17:41.567 --> 17:43.747 so you should not mix the two up. 17:43.750 --> 17:48.680 This Y is a generic Y changing with time. 17:48.680 --> 17:52.000 So let's ask, how can I calculate the future, 17:52.000 --> 17:53.510 given the present? 17:53.509 --> 17:55.979 How do I solve this equation? 17:55.980 --> 17:58.140 So here is what you do. 17:58.140 --> 18:00.330 I'm going to do it at two levels. 18:00.328 --> 18:03.928 One is to tell you a little bit about how you get there, 18:03.930 --> 18:05.490 and for those of you who say, "Look, 18:05.490 --> 18:07.460 spare me the details, I just want to know the 18:07.458 --> 18:09.288 answer," I will draw a box around the 18:09.292 --> 18:11.452 answer, and you are free to start from 18:11.451 --> 18:11.831 there. 18:11.828 --> 18:15.768 But I want to give everyone a chance to look under the hood 18:15.772 --> 18:17.612 and see what's happening. 18:17.608 --> 18:21.758 So given an equation like this, which is pretty old stuff in 18:21.759 --> 18:24.919 mathematical physics from after Newton's time, 18:24.923 --> 18:28.093 people always ask the following question. 18:28.088 --> 18:30.868 They say, "Look, I don't know if I can solve it 18:30.874 --> 18:33.444 for every imaginable initial condition." 18:33.440 --> 18:35.070 It's like saying, even the case of the 18:35.065 --> 18:36.765 oscillator, you may not be able to solve 18:36.773 --> 18:40.313 every initial condition, you say, "Let me find a 18:40.308 --> 18:44.808 special case where Y(x, t), 18:44.808 --> 18:47.528 which depends on x and on t, 18:47.529 --> 18:54.639 has the following simple form - it's a function of t alone times 18:54.642 --> 18:58.822 a function of x alone." 18:58.819 --> 18:59.629 Okay? 18:59.630 --> 19:04.030 I want you to know that no one tells you that every solution to 19:04.030 --> 19:06.090 the equation has this form. 19:06.088 --> 19:08.778 You guys have a question about this? 19:08.779 --> 19:10.409 Over there. 19:10.410 --> 19:12.020 Okay, good. 19:12.019 --> 19:15.259 All right, so this is an assumption. 19:15.259 --> 19:19.109 You want to see if maybe there are answers like this to the 19:19.105 --> 19:19.765 problem. 19:19.769 --> 19:22.949 The only way to do that is to take their assumed form, 19:22.953 --> 19:26.443 put it into the equation and see if you can find a solution 19:26.438 --> 19:27.458 of this form. 19:27.460 --> 19:28.940 Not every solution looks like this. 19:28.940 --> 19:33.580 For example, you could write 19:33.575 --> 19:37.005 e^((x-t)2). 19:37.009 --> 19:39.289 That's the function of x and t. 19:39.288 --> 19:42.058 But it's not a function of x times the function of 19:42.058 --> 19:42.948 t, you see that? 19:42.950 --> 19:45.590 x and t are mixed up together. 19:45.588 --> 19:48.448 You cannot rip it out at the two parts, so it's not the most 19:48.454 --> 19:51.264 general thing that can happen; it's a particular one. 19:51.259 --> 19:54.609 Right now, you are eager to get any solution. 19:54.608 --> 19:56.258 You want to say, "Can I do anything? 19:56.259 --> 19:59.299 Can I calculate even in the simplest case what the future 19:59.299 --> 20:00.929 is, given the present?" 20:00.930 --> 20:04.200 You're asking, "Can this happen?" 20:04.200 --> 20:09.820 So I'm going to show you now that the equation does admit 20:09.819 --> 20:12.329 solutions of this type. 20:12.328 --> 20:16.648 So are you guys with me now on what I'm trying to do? 20:16.650 --> 20:22.390 I'm trying to see if this equation admits solutions of 20:22.390 --> 20:23.690 this form. 20:23.690 --> 20:27.410 So let's take that and put it here. 20:27.410 --> 20:31.770 Now here's where you've got to do the math, okay? 20:31.769 --> 20:33.919 Take this Y and put it here and start taking 20:33.917 --> 20:34.517 derivatives. 20:34.519 --> 20:37.089 Let's do the left hand side first. 20:37.088 --> 20:40.438 Left hand side, I have iℏ. 20:40.440 --> 20:44.920 Then I bring the d by dt to act on this product. 20:44.920 --> 20:50.100 d by dt partial means only time has to be differentiated; 20:50.099 --> 20:51.979 x is to be held constant. 20:51.980 --> 20:53.040 That's the partial derivative. 20:53.038 --> 20:54.678 That's the meaning of the partial derivative. 20:54.680 --> 20:57.500 It's like an ordinary derivative where the only 20:57.501 --> 21:00.571 variable you'd ever differentiate is the one in the 21:00.568 --> 21:01.488 derivative. 21:01.490 --> 21:04.280 So the entire Y(x) doesn't do 21:04.278 --> 21:05.008 anything. 21:05.009 --> 21:06.349 It's like a constant. 21:06.348 --> 21:08.298 So you just put that Y(x) there. 21:08.298 --> 21:10.638 Then the derivative, d by dt, 21:10.640 --> 21:14.720 comes here, and I claim it becomes the ordinary derivative. 21:14.720 --> 21:18.730 That's the left hand side. 21:18.730 --> 21:22.520 You understand that, why that is true? 21:22.519 --> 21:24.819 Because on a function only of time there's no difference 21:24.816 --> 21:27.026 between partial derivative and ordinary derivative. 21:27.029 --> 21:28.849 It's got only one variable. 21:28.848 --> 21:31.608 The other potential variable this d by dt, 21:31.609 --> 21:34.909 doesn't care about so it's just standing there. 21:34.910 --> 21:36.990 That's the left hand side. 21:36.990 --> 21:41.630 Now look at the right hand side, all of this stuff, 21:41.634 --> 21:47.024 and imagine putting for this function Y this product 21:47.022 --> 21:47.862 form. 21:47.858 --> 21:50.488 Is it clear to you, in the right hand side the 21:50.491 --> 21:52.541 situation's exactly the opposite? 21:52.538 --> 21:54.758 You've got all these d by dx's partials, 21:54.762 --> 21:57.472 they're only interested in this function because it's got 21:57.470 --> 21:58.630 x dependence. 21:58.630 --> 22:01.990 F(t) doesn't do anything. 22:01.990 --> 22:05.690 All the derivatives, they go right through F, 22:05.692 --> 22:08.382 so you can write it as F(t). 22:08.380 --> 22:12.940 Now you have to take the derivative with respect to 22:12.944 --> 22:13.954 Y. 22:13.950 --> 22:17.930 That looks like d^(2)Y 22:17.933 --> 22:24.493 /dx^(2) V(x)Y(x). 22:24.490 --> 22:27.270 If you follow this, you're almost there, 22:27.273 --> 22:30.133 but take your time to understand this. 22:30.130 --> 22:32.780 The reason you write it as a product of two functions is the 22:32.778 --> 22:35.068 left hand side is only interested in differentiating 22:35.067 --> 22:37.587 the function F, where it becomes the total 22:37.593 --> 22:38.203 derivative. 22:38.200 --> 22:40.780 The right hand side is only taking derivatives with respect 22:40.775 --> 22:43.035 to x so it acts on this part of the function, 22:43.039 --> 22:44.239 it depends on x. 22:44.240 --> 22:48.520 And all partial derivatives become total derivatives because 22:48.518 --> 22:52.578 if you've got only one variable, there's no need to write 22:52.578 --> 22:54.318 partial derivatives. 22:54.318 --> 22:59.508 This combination I'm going to write to save some time as 22:59.507 --> 23:01.297 HY. 23:01.298 --> 23:05.118 Let's just say between you and me it's a shorthand. 23:05.118 --> 23:11.088 HY is a shorthand for this entire mess here. 23:11.088 --> 23:12.908 Don't ask me why it looks like H times Y, 23:12.913 --> 23:13.863 where are the derivatives? 23:13.859 --> 23:16.639 It is a shorthand, okay. 23:16.640 --> 23:20.900 I don't feel like writing the combination over and over, 23:20.895 --> 23:23.445 I can call it HY. 23:23.450 --> 23:26.090 So what equation do I have now? 23:26.088 --> 23:31.038 I have iℏ Y(x)dF/dt = 23:31.041 --> 23:36.321 F(t)HY, where all I want you to notice, 23:36.317 --> 23:41.267 HY depends only on x. 23:41.269 --> 23:42.619 It has no dependence on time. 23:42.619 --> 23:43.949 Do you see that? 23:43.950 --> 23:52.970 There's nothing here that depends on time. 23:52.970 --> 23:55.140 Okay, now this is a trick which if you learned, 23:55.140 --> 23:57.490 you'll be quite pleased, because you'll find that as you 23:57.489 --> 23:59.969 do more and more stuff, at least in physics or 23:59.970 --> 24:04.160 economics or statistics, the trick is a very old trick. 24:04.160 --> 24:06.890 The problem is quantum mechanics, but the mathematics 24:06.885 --> 24:07.615 is very old. 24:07.619 --> 24:09.399 So what do you do next? 24:09.400 --> 24:13.140 You divide both sides by YF. 24:13.140 --> 24:25.010 So I say divide by F(t)Y(x). 24:25.009 --> 24:26.899 What do you think will happen if I divide by F(t), 24:26.900 --> 24:27.610 Y(x)? 24:27.608 --> 24:29.918 On the left hand side, I say divide by 24:29.924 --> 24:32.684 YF and the right hand side, 24:32.680 --> 24:35.140 I say divide by YF, 24:35.141 --> 24:38.681 can you see that the Y cancels here, 24:38.680 --> 24:40.340 and you have a 1/F. 24:40.338 --> 24:43.668 F cancels here and you have a 1/Y. 24:43.670 --> 24:48.450 The equation then says iℏ(1/ 24:48.454 --> 24:53.244 F(t))dF/dt = 1/Y(x)H 24:53.240 --> 24:59.580 Y. I've written this very slowly because 24:59.584 --> 25:02.854 I don't know, you'll find this in many 25:02.846 --> 25:05.146 advanced books, but you may not find it in our 25:05.146 --> 25:05.666 textbook. 25:05.670 --> 25:08.310 So if you don't follow something, you should tell me. 25:08.308 --> 25:12.648 There's plenty of time to do this, so I'm in no rush at all. 25:12.650 --> 25:15.680 These are purely mathematical manipulations. 25:15.680 --> 25:20.230 We have not done anything involving physics. 25:20.230 --> 25:23.860 You all follow this? 25:23.859 --> 25:25.079 Yes? 25:25.079 --> 25:26.249 Okay. 25:26.250 --> 25:27.650 Now you have to ask yourself the following. 25:27.650 --> 25:29.240 I love this argument. 25:29.240 --> 25:31.900 Even if you don't follow this, I'm just going to get it off my 25:31.896 --> 25:33.446 chest, it is so clever, 25:33.449 --> 25:37.869 and here is the clever part - this is supposedly a function of 25:37.867 --> 25:39.747 time, you agree? 25:39.750 --> 25:42.870 All for a function of time. 25:42.869 --> 25:45.699 This is a function of x. 25:45.700 --> 25:47.870 This guy doesn't know what time it is; 25:47.868 --> 25:49.428 this guy doesn't know what x is. 25:49.430 --> 25:52.820 And yet they're supposed to be equal. 25:52.819 --> 25:56.449 What can they be equal to? 25:56.450 --> 25:59.170 They cannot be equal to a function of time, 25:59.171 --> 26:01.891 because then, as you vary time--suppose you 26:01.893 --> 26:04.683 think it's a function of time, suppose. 26:04.680 --> 26:06.060 It's not so. 26:06.058 --> 26:08.678 Then as time varies, this part is okay. 26:08.680 --> 26:11.940 It can vary with time to match that, but this cannot vary with 26:11.936 --> 26:14.336 time at all, because there is no time here. 26:14.339 --> 26:16.919 So this cannot depend on time. 26:16.920 --> 26:19.200 And it cannot depend on x, because if it was a 26:19.202 --> 26:21.182 function of x that it was equal to, 26:21.180 --> 26:23.060 as you vary x, this can change with x 26:23.056 --> 26:23.916 to keep up with that. 26:23.920 --> 26:25.860 This has no x dependence. 26:25.859 --> 26:27.509 It cannot vary with x. 26:27.509 --> 26:31.779 So this thing that they are both equal to is not a function 26:31.781 --> 26:34.951 of time and it's not a function of space. 26:34.950 --> 26:36.650 It's a constant. 26:36.650 --> 26:38.220 That's all it can be. 26:38.220 --> 26:43.500 So the constant is going to very cleverly be given the 26:43.497 --> 26:45.287 symbol E. 26:45.288 --> 26:47.578 We're going to call the constant E. 26:47.578 --> 26:50.578 It turns out E is connected to the energy of the 26:50.583 --> 26:51.143 problem. 26:51.140 --> 26:55.070 So now I have two equations, this = E and that = 26:55.066 --> 26:58.116 E and I'm going to write it down. 26:58.118 --> 27:06.128 So one of them says i ℏ (1/F) dF/dt = 27:06.134 --> 27:07.474 E. 27:07.470 --> 27:09.770 So let me bring the F here. 27:09.769 --> 27:14.079 Other one says H Y = E 27:14.079 --> 27:20.769 Y. These two equations, if you solve them, 27:20.773 --> 27:26.563 will give you the solution you are looking for. 27:26.558 --> 27:28.808 In other words, going back here, 27:28.810 --> 27:31.250 yes, this equation does admit 27:31.253 --> 27:34.423 solutions of this form, of the product form, 27:34.423 --> 27:37.713 provided the function F you put in the product that 27:37.711 --> 27:40.021 depends on time obeys this equation, 27:40.019 --> 27:43.339 and the function Y that depends only on x obeys 27:43.343 --> 27:44.233 this equation. 27:44.230 --> 27:46.650 Remember, HY is the shorthand for this long 27:46.646 --> 27:47.636 bunch of derivatives. 27:47.640 --> 27:51.680 We'll come to that in a moment, but let's solve this equation 27:51.681 --> 27:52.221 first. 27:52.220 --> 27:54.100 Now can you guys do this in your head? 27:54.099 --> 28:03.309 iℏdF/dt = EF. 28:03.308 --> 28:06.538 So it's saying F is a function of time whose time 28:06.537 --> 28:08.647 derivative is the function itself. 28:08.650 --> 28:12.060 Everybody knows what such a function is. 28:12.059 --> 28:14.509 It's an exponential. 28:14.509 --> 28:16.779 And the answer is, I'm going to write it down and 28:16.784 --> 28:20.434 you can check, F(t) is F(0) 28:20.428 --> 28:26.748 e^(−iEt/ℏ). If you want now, 28:26.750 --> 28:29.240 take the derivative and check. 28:29.240 --> 28:31.650 F(0) is some constant. 28:31.650 --> 28:34.840 I call it F(0) because if t = 0, 28:34.844 --> 28:38.184 this goes away and F(t) = F(0). 28:38.180 --> 28:39.920 But take the time derivative and see. 28:39.920 --> 28:41.650 When you take a time derivative of this, 28:41.650 --> 28:45.110 you get the same thing times −iE/ℏ, 28:45.108 --> 28:47.528 and when you multiply by iℏ, 28:47.529 --> 28:50.359 everything cancels except EF. 28:50.359 --> 28:52.699 So this is a very easy solution. 28:52.700 --> 28:54.950 So let's stop and understand. 28:54.950 --> 28:58.510 It says that if you are looking for solutions that are products 28:58.505 --> 29:00.565 of F(t) times f(x), 29:00.568 --> 29:05.398 F(t) necessarily is this exponential function, 29:05.400 --> 29:08.700 which is the only function you can have. 29:08.700 --> 29:11.170 But now once you pick that E, you can pick E 29:11.170 --> 29:13.420 to be whatever you like, but then you must also solve 29:13.423 --> 29:14.943 this equation at the same time. 29:14.940 --> 29:16.810 But what is this equation. 29:16.808 --> 29:21.008 This says -ℏ^(2)/2md^(2) 29:21.006 --> 29:25.796 Y/dx^(2) VY = 29:25.801 --> 29:30.461 EY, and you guys know who that is, 29:30.462 --> 29:31.022 right? 29:31.019 --> 29:32.889 What is it? 29:32.890 --> 29:39.300 What can you say about the function that satisfies that 29:39.295 --> 29:40.595 equation? 29:40.599 --> 29:43.029 Have you seen it before? 29:43.029 --> 29:44.149 Yes? 29:44.150 --> 29:45.120 What is it? 29:46.690 --> 29:48.540 Prof: It's the state of definite energy. 29:48.538 --> 29:51.948 Remember, we said functions of definite energy obey that 29:51.948 --> 29:52.628 equation. 29:52.630 --> 30:02.420 So that Y is really just Y_E. 30:02.420 --> 30:04.460 So now I'll put these two pieces together, 30:04.460 --> 30:09.090 and this is where those of you who drifted off can come back, 30:12.557 --> 30:15.777 equation in fact admits a certain solution which is a 30:15.778 --> 30:19.368 product of a function of time and a function of space. 30:19.368 --> 30:22.428 And what we found by fiddling around with it is that F(t) 30:22.430 --> 30:24.350 and Y are very special, 30:24.348 --> 30:28.378 and F(t) must look like e^(−iEt/ 30:28.380 --> 30:32.450 ℏ), and Y is just our 30:32.450 --> 30:37.030 friend, Y _E(x), which 30:37.025 --> 30:42.205 are functions associated with a definite energy. 30:42.210 --> 30:43.110 Yes? 30:43.108 --> 30:46.078 Student: Is it possible that there are other solutions, 30:46.077 --> 30:48.897 x/Y(x, t) that don't satisfy the 30:48.901 --> 30:49.621 conditions? 30:49.618 --> 30:51.948 Prof: Okay, the question is, 30:51.953 --> 30:55.943 are there other solutions for which this factorized form is 30:55.936 --> 30:56.826 not true? 30:56.828 --> 31:00.708 Yes, and I will put you out of your suspense very soon by 31:00.705 --> 31:02.155 talking about that. 31:02.160 --> 31:06.230 But I want everyone to understand that you can at least 31:09.849 --> 31:10.709 So what does this mean? 31:10.710 --> 31:13.210 I want you guys to think about it. 31:13.210 --> 31:18.140 This says if you start Y in some arbitrary configuration, 31:18.140 --> 31:21.010 that's my initial state, let it evolve with time, 31:25.567 --> 31:26.477 equation. 31:26.480 --> 31:31.280 But if I start it at t = 0, in a state which is a state 31:31.282 --> 31:34.912 of definite energy, namely a state obeying that 31:34.905 --> 31:35.925 equation. 31:35.930 --> 31:38.550 Then its future is very simple. 31:38.548 --> 31:43.358 All you do is attach this phase factor, e^(−iEt/ 31:43.362 --> 31:44.912 ℏ). 31:44.910 --> 31:47.620 Therefore it's not a generic solution, because you may not in 31:47.622 --> 31:50.562 general start with a state which is a state of definite energy. 31:50.558 --> 31:53.128 You'll start with some random Y(x) and it's made 31:53.130 --> 31:55.110 up of many, many Y_E's 31:55.114 --> 31:57.494 that come in the expansion of that Y, 31:57.490 --> 31:59.160 so it's not going to always work. 31:59.160 --> 32:02.510 But if you picked it so that there's only one such term in 32:02.510 --> 32:05.270 the sum over E, namely one such function, 32:05.273 --> 32:07.453 then the future is given by this. 32:07.450 --> 32:10.120 For example, if you have a particle in a 32:10.119 --> 32:12.859 box, you remember the wave function 32:12.861 --> 32:17.541 Y_n looks like square root of 2/Lsine(n 32:17.535 --> 32:21.605 px/L). An arbitrary Y doesn't look 32:21.605 --> 32:23.335 like any of these. 32:23.338 --> 32:27.278 These guys, remember, are nice functions that do many 32:27.281 --> 32:28.421 oscillations. 32:28.420 --> 32:32.860 But if you chose it initially to be exactly the sine function, 32:32.858 --> 32:35.078 for example, Y_1, 32:35.077 --> 32:39.807 then I claim as time evolves, the future state is just this 32:39.810 --> 32:44.530 initial sine function times this simple exponential. 32:44.529 --> 32:52.929 This behavior is very special and it called normal modes. 32:52.930 --> 32:56.060 It's a very common idea in mathematical physics. 32:56.058 --> 32:59.428 It's the following - it's very familiar even before you did 32:59.434 --> 33:00.604 quantum mechanics. 33:00.598 --> 33:06.198 Take a string tied at both ends and you pluck the string and you 33:06.202 --> 33:07.362 release it. 33:07.358 --> 33:10.328 Most probably if you pluck it at one point, 33:10.329 --> 33:14.149 you'll probably pull it in the middle and let it go. 33:14.150 --> 33:17.350 That's the initial Y(x,t), 33:17.348 --> 33:19.398 this time for a string. 33:19.400 --> 33:21.240 Pull it in the middle, let it go. 33:21.240 --> 33:24.560 There's an equation that determines the evolutions of 33:24.556 --> 33:25.446 that string. 33:25.450 --> 33:27.370 I remind you what that equation is. 33:27.368 --> 33:31.898 It's d^(2)Y /dx^(2)=(1/veloc 33:31.901 --> 33:36.331 ity^(2))d^(2)Y /dt^(2). 33:36.328 --> 33:38.708 That's the wave equation for a string. 33:38.710 --> 33:41.280 It's somewhat different from this problem, 33:41.276 --> 33:44.156 because it's a second derivative in time that's 33:44.155 --> 33:44.965 involved. 33:44.970 --> 33:48.160 Nonetheless, here is an amazing property of 33:48.163 --> 33:51.513 this equation, derived by similar methods. 33:51.509 --> 33:53.849 If you pull a string like this and let it go, 33:53.846 --> 33:55.916 it will go crazy when you release it. 33:55.920 --> 33:57.070 I don't even know what it will do. 33:57.068 --> 34:00.438 It will do all kinds of things, stuff will go back and forth, 34:00.435 --> 34:01.385 back and forth. 34:01.390 --> 34:06.410 But if you can deform the string at t = 0 to look 34:06.412 --> 34:10.882 exactly like this, sine(px/L) 34:10.875 --> 34:14.465 times a number A, that's not easy to do. 34:14.469 --> 34:17.279 Do you understand that to produce the initial profile, 34:17.282 --> 34:19.992 one hand is not enough, two hands are not enough? 34:19.989 --> 34:22.889 You've got to get infinite number of your friends, 34:22.893 --> 34:24.793 who are infinitesimally small. 34:24.789 --> 34:28.359 You line them up along the string until each one--tell the 34:28.360 --> 34:31.180 person here to pull it exactly this height. 34:31.179 --> 34:33.199 Person here has to pull it exactly that height. 34:33.199 --> 34:35.529 You all lift your hands up, then I follow you. 34:35.530 --> 34:37.240 You follow this perfect sine. 34:37.239 --> 34:40.639 Then you let go. 34:40.639 --> 34:46.589 What do you think will happen then? 34:46.590 --> 34:50.760 What do you think will be the subsequent evolution of the 34:50.759 --> 34:51.429 string? 34:51.429 --> 34:52.029 Do you have any guess? 34:52.030 --> 34:52.510 Yes? 34:52.510 --> 34:54.560 Student: > 34:54.559 --> 35:01.219 Prof: It will go up and down, and the future of that 35:01.222 --> 35:07.312 string will look like cosine(pxvt/L). 35:07.309 --> 35:08.149 Look at it. 35:08.150 --> 35:10.360 This is a time dependence, that t = 0, 35:10.355 --> 35:12.205 this goes away, this initial state. 35:12.210 --> 35:14.790 But look what happens at a later time. 35:14.789 --> 35:20.049 Every point x rises and falls with the same period. 35:20.050 --> 35:22.580 It goes up and down all together. 35:22.579 --> 35:25.139 That means a little later it will look like that, 35:25.139 --> 35:26.359 a little later it will look like that, 35:26.360 --> 35:28.300 then it will look like this, then it will look like this, 35:28.300 --> 35:30.310 then it will look like that, then it will go back and forth. 35:30.309 --> 35:32.899 But at every instant, this guy, this guy, 35:32.900 --> 35:36.270 this guy are all rescaled by the same amount from the 35:36.268 --> 35:37.498 starting value. 35:37.500 --> 35:39.930 That's called a normal mode. 35:39.929 --> 35:42.259 Now your question was, are there other solutions to 35:42.262 --> 35:42.872 the string? 35:42.869 --> 35:43.969 Of course. 35:43.969 --> 35:46.279 Typically, if you don't think about it and pluck the string, 35:46.280 --> 35:49.570 your initial state will be a sum of these normal modes, 35:49.570 --> 35:51.990 and that will evolve in a complicated way. 35:51.989 --> 35:54.649 But if you engineered it to begin exactly this way, 35:54.650 --> 35:58.580 or in any one of those other functions where you put an extra 35:58.583 --> 36:01.043 n here, they all have the remarkable 36:01.043 --> 36:03.753 property that they rise and fall in step. 36:03.750 --> 36:07.650 What we have found here is in the quantum problem, 36:07.650 --> 36:11.290 if you start the system in that particular configuration, 36:11.289 --> 36:15.319 then its future has got a single time dependence common to 36:15.315 --> 36:15.665 it. 36:15.670 --> 36:20.760 That's the meaning of the factorized solution. 36:20.760 --> 36:22.860 So we know one simple example. 36:22.860 --> 36:24.890 Take a particle in a box. 36:24.889 --> 36:28.529 If it's in the lowest energy state or ground state the wave 36:28.525 --> 36:30.215 function looks like that. 36:30.219 --> 36:35.049 Then the future of that will be Y_1/x 36:35.052 --> 36:38.682 and t will be the Y_1x 36:38.677 --> 36:41.817 times e^(-iE1t/ℏ), 36:41.820 --> 36:45.460 where E_1 = ℏ^(2) 36:45.460 --> 36:48.940 p^(2) 1^(2)/2mL^(2). 36:48.940 --> 36:53.160 That's the energy associated with that function. 36:53.159 --> 36:57.739 That's how it will oscillate. 36:57.739 --> 37:01.479 Now you guys follow what I said now, with an analogy with the 37:01.481 --> 37:03.541 string and the quantum problem? 37:03.539 --> 37:05.189 They're slightly different equations. 37:05.190 --> 37:06.860 One is second order, one is first order. 37:06.860 --> 37:09.940 One has cosines in it, one has exponentials in it. 37:09.940 --> 37:13.720 But the common property is, this is also a function of time 37:13.722 --> 37:15.682 times the function of space. 37:15.679 --> 37:26.259 Here, this is a function of time and a function of space. 37:26.260 --> 37:30.610 Okay, so I'm going to spend some time analyzing this 37:30.612 --> 37:32.492 particular function. 37:32.489 --> 37:37.949 Y(x) and t = e^(−iEt/ℏ)^( 37:37.945 --> 37:41.125 )Y _E(x). 37:41.130 --> 37:45.530 And I'm going to do an abuse in rotation and give the subscript 37:45.525 --> 37:47.505 E to this guy also. 37:47.510 --> 37:50.090 What I mean to tell you by that is, this Y, 37:52.731 --> 37:54.421 I invite you to go check it. 37:56.583 --> 37:58.373 equation and you will find it works. 37:58.369 --> 38:01.599 In the notes I've given you, I merely tell you that this is 38:04.050 --> 38:06.330 I don't go through this argument of assuming it's a 38:06.329 --> 38:07.469 product form and so on. 38:07.469 --> 38:08.269 That's optional. 38:08.268 --> 38:10.278 I don't care if you remember that or not, 38:12.030 --> 38:16.460 and I call it Y_E because the 38:16.458 --> 38:22.358 function of the right hand side are identified with states of 38:22.362 --> 38:24.332 definite energy. 38:24.329 --> 38:31.309 Okay, what will happen if you measure various quantities in 38:31.313 --> 38:32.883 this state? 38:32.880 --> 38:34.680 For example, what's the position going to 38:34.684 --> 38:34.914 be? 38:34.909 --> 38:37.399 What's the probability for definite position? 38:37.400 --> 38:39.510 What's the probability for definite momentum? 38:39.510 --> 38:41.850 What's the probability for definite anything? 38:41.849 --> 38:43.319 How will they vary with time? 38:43.320 --> 38:47.030 I will show you, nothing depends on time. 38:47.030 --> 38:49.700 You can say, "How can nothing depend on 38:49.704 --> 38:50.144 time? 38:50.139 --> 38:52.899 I see time in the function here." 38:52.900 --> 38:55.100 But it will go away. 38:55.099 --> 38:59.779 Let us ask, what is the probability that the particle is 38:59.780 --> 39:03.950 at x at time t for a solution like this? 39:03.949 --> 39:08.029 You know, the answer is Y *(x,t) 39:08.030 --> 39:13.600 Y(x,t), and what do you get when you do 39:13.603 --> 39:14.503 that? 39:14.500 --> 39:18.050 You will get Y_E *(x 39:18.048 --> 39:21.518 )Y _E(x). Then you 39:21.519 --> 39:25.609 will get the absolute value of this guy squared, 39:25.610 --> 39:27.850 e^(iEt)^( )times e^(-iEt), 39:27.849 --> 39:34.709 and that's just 1. 39:34.710 --> 39:38.540 I hope all of you know that this e^(i)^( )absolute 39:38.541 --> 39:39.981 value squared is 1. 39:39.980 --> 39:42.350 So it does not depend on time. 39:42.349 --> 39:45.869 Even though Y depends on time, Y *Y has no 39:45.867 --> 39:46.887 time dependence. 39:46.889 --> 39:50.509 That means the probability for finding that particle will not 39:50.512 --> 39:51.662 change with time. 39:51.659 --> 39:57.049 That means if you start the particle in the ground state, 39:57.050 --> 40:00.640 Y, and let's say Y^(2) in fact looks 40:00.641 --> 40:04.931 pretty much the same, it's a real function, 40:04.925 --> 40:10.215 this probability does not change with time. 40:10.219 --> 40:13.549 That means you can make a measurement any time you want 40:13.545 --> 40:16.195 for position, and the odds don't change with 40:16.195 --> 40:16.745 time. 40:16.750 --> 40:17.950 It's very interesting. 40:17.949 --> 40:20.289 It depends on time and it doesn't depend on time. 40:20.289 --> 40:22.979 It's a lot like e^(ipx/ℏ). 40:22.980 --> 40:26.130 It seems to depend on x but the density does not depend 40:26.130 --> 40:28.610 on x because the exponential goes away. 40:28.610 --> 40:30.470 Similarly, it does depend on time. 40:30.469 --> 40:32.989 Without the time dependence, it won't satisfy 40:36.018 --> 40:38.018 absolute value, this goes away. 40:38.018 --> 40:41.438 That means for this particle, I can draw a little graph that 40:41.443 --> 40:43.943 looks like this, and that is the probability 40:43.938 --> 40:46.258 cloud you find in all the textbooks. 40:46.260 --> 40:47.510 Have you seen the probability cloud? 40:47.510 --> 40:51.150 They've got a little atom that's a little fuzzy stuff all 40:51.150 --> 40:51.930 around it. 40:51.929 --> 40:54.589 They are the states of the hydrogen atom or some other 40:54.588 --> 40:54.938 atom. 40:54.940 --> 40:56.910 How do you think you get that? 40:56.909 --> 40:59.889 You solve a similar equation, except it will be in 3 40:59.887 --> 41:02.047 dimensions instead of 1 dimension, 41:02.050 --> 41:08.530 and for V(x), you write -Ze^(2)/r, if you want 41:08.532 --> 41:12.382 r as x^(2) y^(2) z^(2). 41:12.380 --> 41:15.600 Ze is the nuclear charge, and -e is the electron 41:15.599 --> 41:16.099 charge. 41:16.099 --> 41:20.919 You put that in and you solve the equation and you will find a 41:20.918 --> 41:24.788 whole bunch of solutions that behave like this. 41:24.789 --> 41:27.059 They are called stationary states, because in that 41:27.061 --> 41:29.711 stationary state-- see, if a hydrogen atom starts 41:29.710 --> 41:32.280 out in this state, which is a state of definite 41:32.275 --> 41:33.695 energy, as time goes by, 41:33.704 --> 41:35.844 nothing happens to it essentially. 41:35.840 --> 41:38.540 Something trivial happens; it picks up the phase factor, 41:38.538 --> 41:41.978 but the probability for finding the electron never changes with 41:41.976 --> 41:42.416 time. 41:42.420 --> 41:45.160 So if you like, you can draw a little cloud 41:45.161 --> 41:46.991 whose thickness, if you like, 41:46.987 --> 41:50.967 measures the probability for finding it at that location. 41:50.969 --> 41:52.069 So that will have all kinds of shape. 41:52.070 --> 41:54.650 It looks like dumbbells, pointing to the north pole, 41:54.654 --> 41:57.344 south pole, maybe uniformly spherical distribution. 41:57.340 --> 42:01.930 They're all the probability of finding the electron in that 42:01.932 --> 42:05.182 state, and it doesn't change with time. 42:05.179 --> 42:08.059 So a hydrogen atom, when you leave it alone, 42:08.056 --> 42:10.796 will be in one of these allowed states. 42:10.800 --> 42:12.040 You don't need the hydrogen atom; 42:12.039 --> 42:14.889 this particle in a box is a good enough quantum system. 42:14.889 --> 42:16.659 If you start it like that, it will stay like that; 42:16.659 --> 42:19.469 if you start it like that, it will stay like that, 42:19.474 --> 42:20.974 times that phase factor. 42:20.969 --> 42:25.359 So stationary states are important, because that's where 42:25.356 --> 42:27.506 things have settled down. 42:27.510 --> 42:31.230 Okay, now you should also realize that that's not a 42:31.231 --> 42:32.721 typical situation. 42:32.719 --> 42:37.029 Suppose you have in 1 dimension, there's a particle on 42:37.025 --> 42:41.165 a hill, and at t = 0, it's given by some wave 42:41.168 --> 42:43.928 function that looks like this. 42:43.929 --> 42:47.029 So it's got some average position, and if you expand it 42:47.032 --> 42:50.432 in terms of exponentials of p, it's got some range of 42:50.425 --> 42:51.455 momenta in it. 42:51.460 --> 42:54.560 What will happen to this as a function of time? 42:54.559 --> 42:56.939 Can you make a guess? 42:56.940 --> 43:01.070 Let's say it's right now got an average momentum to the left. 43:01.070 --> 43:04.730 What do you think will happen to it? 43:04.730 --> 43:05.370 Pardon me? 43:05.369 --> 43:06.279 Student: It will move to the left. 43:06.280 --> 43:07.140 Prof: It will move to the left. 43:07.139 --> 43:10.589 Except for the fuzziness, you can apply your classical 43:10.588 --> 43:11.368 intuition. 43:11.369 --> 43:13.369 It's got some position, maybe not precise. 43:13.369 --> 43:15.369 It's got some momentum, maybe not precise, 43:15.369 --> 43:17.569 but when you leave something on top of a hill, 43:17.565 --> 43:19.415 it's going to slide down the hill. 43:19.420 --> 43:21.900 The average x is going to go this way, 43:21.898 --> 43:24.208 and the average momentum will increase. 43:24.210 --> 43:27.280 So that's a situation where the average of the physical 43:27.282 --> 43:28.992 quantities change with time. 43:28.989 --> 43:31.859 That's because this state is not a function 43:31.862 --> 43:34.122 Y_E(x). 43:34.119 --> 43:35.379 It's some random function you picked. 43:35.380 --> 43:38.710 Random functions you picked in some potential will in fact 43:38.713 --> 43:42.283 evolve with time in such a way that measurable quantities will 43:42.280 --> 43:43.510 change with time. 43:43.510 --> 43:45.840 The odds for x or the odds for p, 43:45.836 --> 43:48.206 odds for everything else, will change with time, 43:48.213 --> 43:48.673 okay? 43:48.670 --> 43:50.880 So stationary states are very privileged, 43:50.880 --> 43:52.860 because if you start them that way, 43:52.860 --> 43:55.020 they stay that way, and that's why when you look at 43:55.021 --> 43:58.051 atoms, they typically stay that way. 43:58.050 --> 44:01.000 But once in a while, an atom will jump from one 44:00.998 --> 44:05.038 stationary state to another one, and you can say that looks like 44:05.036 --> 44:06.316 a contradiction. 44:06.320 --> 44:08.240 If it's stationary, what's it doing jumping from 44:08.244 --> 44:08.904 here to there? 44:08.900 --> 44:14.340 You know the answer to that? 44:14.340 --> 44:15.760 Why does an atom ever change then? 44:15.760 --> 44:18.930 If it's in a state of definite E, it should be that way 44:18.929 --> 44:19.449 forever. 44:19.449 --> 44:22.369 Why do they go up and down? 44:22.369 --> 44:23.339 Want to guess? 44:23.340 --> 44:26.670 Student: > 44:26.670 --> 44:27.180 Prof: That's correct. 44:27.179 --> 44:28.859 So she said by absorbing photons. 44:28.860 --> 44:33.020 And what I really mean by that is, this problem V(x) 44:33.023 --> 44:37.263 involves only the coulomb force between the electron and the 44:37.260 --> 44:38.050 proton. 44:38.050 --> 44:40.650 If that's all you have, an electron in the field of a 44:40.654 --> 44:42.664 proton, it will pick one of these levels, 44:42.657 --> 44:44.157 it can stay there forever. 44:44.159 --> 44:46.489 When you shine light, you're applying an 44:46.487 --> 44:47.917 electromagnetic field. 44:47.920 --> 44:51.360 The electric field and magnetic field apply extra forces in the 44:51.358 --> 44:54.518 charge and V(x) should change to something else. 44:54.518 --> 44:57.108 So that this function is no longer a state of definite 44:57.106 --> 44:59.696 energy for the new problem, because you've changed the 44:59.695 --> 45:00.765 rules of the game. 45:00.769 --> 45:03.709 You modified the potential. 45:03.710 --> 45:06.920 Then of course it will move around and it will change from 45:06.916 --> 45:08.206 one state to another. 45:08.210 --> 45:11.780 But an isolated atom will remain that way forever. 45:11.780 --> 45:15.330 But it turns out even that's not exactly correct. 45:15.329 --> 45:19.489 You can take an isolated atom, in the first excited state of 45:19.492 --> 45:23.592 hydrogen, you come back a short time later, you'll find the 45:23.585 --> 45:25.345 fellow has come down. 45:25.349 --> 45:27.109 And you say, "Look, I didn't turn on 45:27.112 --> 45:28.042 any electric field. 45:28.039 --> 45:30.209 E = 0, B = 0. 45:30.210 --> 45:32.810 What made the atom come down?" 45:32.809 --> 45:37.089 Do you know what the answer to that is? 45:37.090 --> 45:37.800 Any rumors? 45:37.800 --> 45:38.510 Yes? 45:38.510 --> 45:40.280 Student: Photon emission? 45:40.280 --> 45:42.290 Prof: Its photon is emitted, 45:42.289 --> 45:45.319 but you need an extra thing, extra electrical magnetic field 45:45.318 --> 45:47.678 to act on it before it will emit the photon. 45:47.679 --> 45:48.489 But where is the field? 45:48.489 --> 45:49.969 I've turned everything off. 45:49.969 --> 45:53.799 E and B are both 0. 45:53.800 --> 45:59.240 So it turns out that the state E = B = 0 is like 45:59.237 --> 46:03.867 a state say in a harmonic oscillator potential x = 46:03.871 --> 46:06.301 p = 0, sitting at the bottom of the 46:06.304 --> 46:06.544 well. 46:06.539 --> 46:08.769 We know that's not allowed in quantum mechanics. 46:08.768 --> 46:11.958 You cannot have definite x and definite p. 46:11.960 --> 46:16.680 It turns out in quantum theory, E and B are like 46:16.681 --> 46:18.541 x and p. 46:18.539 --> 46:21.039 That means the state of definite E is not a state 46:21.036 --> 46:22.076 of definite B. 46:22.079 --> 46:24.219 A state of definite B is not a state of definite 46:24.222 --> 46:24.662 E. 46:24.659 --> 46:26.879 It looks that way in the macroscopic world, 46:26.882 --> 46:29.902 because the fluctuations in E and B are very 46:29.900 --> 46:30.430 small. 46:30.429 --> 46:33.469 Therefore, just like in the lowest energy state, 46:33.469 --> 46:36.869 an oscillator has got some probability to be jiggling back 46:36.873 --> 46:39.563 and forth in x and also in p. 46:39.559 --> 46:42.499 The vacuum, which we think has no E and no B, 46:42.500 --> 46:45.140 has small fluctuations, because E and B 46:45.135 --> 46:48.275 both vanishing is like x and p both vanishing. 46:48.280 --> 46:49.200 Not allowed. 46:49.199 --> 46:51.779 So you've got to have a little spread in both E and both 46:51.780 --> 46:52.240 B. 46:52.239 --> 46:54.859 They're called quantum fluctuations of the vacuum. 46:54.860 --> 46:57.480 So that's a theory of nothing. 46:57.480 --> 47:00.160 The vacuum you think is the most uninteresting thing, 47:00.161 --> 47:02.331 and yet it is not completely uninteresting, 47:02.327 --> 47:04.387 because it's got these fluctuations. 47:04.389 --> 47:08.049 It's those fluctuations that tickle the atom and make it come 47:08.047 --> 47:10.607 from an excited state to a ground state. 47:10.610 --> 47:14.740 Okay, so unless you tamper with the atom in some fashion, 47:14.742 --> 47:17.622 it will remain in a stationary state. 47:17.619 --> 47:19.729 Those states are states of definite energy. 47:22.385 --> 47:23.415 without time in it. 47:23.420 --> 47:25.530 H Y = E Y is called the time 47:27.099 --> 47:30.529 and that's what most of us do most of the time. 47:30.530 --> 47:32.830 The problem can be more complicated. 47:32.829 --> 47:35.089 It can involve two particles, can involve ten particles. 47:35.090 --> 47:38.190 It may not involve this force, may involve another force, 47:38.190 --> 47:41.630 but everybody is spending most of his time or her time solving 47:45.409 --> 47:47.779 because that's where things will end up. 47:47.780 --> 47:52.410 All right, I've only shown you that the probability to find 47:52.407 --> 47:56.157 different positions doesn't change with time. 47:56.159 --> 47:58.949 I will show you the probability to find different anything 47:58.947 --> 48:00.267 doesn't change with time. 48:00.268 --> 48:03.158 Nothing will change with time, not just x probability, 48:03.163 --> 48:04.613 so I'll do one more example. 48:04.610 --> 48:09.220 Let's ask, what's the probability to find a momentum 48:09.224 --> 48:10.224 p? 48:10.219 --> 48:12.189 What are we supposed to do? 48:12.190 --> 48:16.480 We're supposed to take e^(ipx)^(/ 48:16.480 --> 48:22.860 ℏ )times the function at some time t 48:22.860 --> 48:25.610 and do that integral. 48:25.610 --> 48:28.600 I'm sorry, you should take that and do that integral, 48:28.603 --> 48:31.313 and then you take the absolute value of that. 48:31.309 --> 48:33.409 And that's done at every time. 48:33.409 --> 48:37.659 You take the absolute value and that's the probability to get 48:37.664 --> 48:39.584 momentum p, right? 48:39.579 --> 48:41.509 The recipe was, if you want the probability, 48:41.510 --> 48:43.760 take the given function, multiply to the conjugate of 48:43.755 --> 48:45.955 Y_p and do the integral, 48:45.960 --> 48:51.590 dL and dx. 48:51.590 --> 48:54.380 Y(x,t) in general has got complicated time 48:54.382 --> 48:56.162 dependence, but not our Y. 48:56.159 --> 48:57.479 Remember our Y? 48:57.480 --> 49:03.990 Our Y looks like Y(x) times e^( 49:03.992 --> 49:07.492 −iEt/ℏ). 49:07.489 --> 49:10.919 But when you take the absolute value, this has nothing to do 49:10.918 --> 49:11.848 with x. 49:11.849 --> 49:14.629 You can pull it outside the integral--or let me put it 49:14.626 --> 49:15.356 another way. 49:15.360 --> 49:17.740 Let's do the integral and see what you get. 49:17.739 --> 49:21.169 You will find A_p looks like 49:21.172 --> 49:23.752 A_p (0)e^(−iEt/ 49:23.748 --> 49:25.308 ℏ). 49:25.309 --> 49:26.769 Do you see that? 49:26.768 --> 49:30.048 If the only thing that happens to Y is that you get an 49:30.045 --> 49:33.205 extra factor at later times, only thing that happens to the 49:33.208 --> 49:36.388 A_p is it gets the extra factor at later times. 49:36.389 --> 49:42.099 But the probability to find momentum p is the 49:42.101 --> 49:48.261 absolute value square of that, and in the absolute value 49:48.260 --> 49:51.620 process, this guy is gone. 49:51.619 --> 49:54.159 You follow that? 49:54.159 --> 49:57.569 Since the wave function changes by a simple phase factor, 49:57.570 --> 50:01.340 the coefficient to have a definite momentum also changes 50:01.342 --> 50:05.322 by the same phase factor.This is called a phase factor, 50:05.320 --> 50:08.100 exponential of modulus 1, but when you take the absolute 50:08.103 --> 50:12.433 value, the guy doesn't do anything. 50:12.429 --> 50:14.499 Now you can replace p by some other variable. 50:14.500 --> 50:15.190 It doesn't matter. 50:15.190 --> 50:17.520 The story is always the same. 50:17.518 --> 50:22.458 So a state of definite energy seems to evolve in time, 50:22.460 --> 50:24.430 because e^(ipx)^(/ ℏ), 50:24.429 --> 50:26.919 but none of the probabilities change with time. 50:26.920 --> 50:28.390 It's absolutely stationary. 50:28.389 --> 50:30.539 Just put anything you measure. 50:30.539 --> 50:33.439 That's why those states are very important. 50:33.440 --> 50:40.920 Okay, now I want to caution you that not every solution looks 50:40.922 --> 50:42.422 like this. 50:42.420 --> 50:43.280 That's the question you raised. 50:43.280 --> 50:45.490 I'm going to answer that question now. 50:45.489 --> 50:48.559 Let's imagine that I find two solutions to the 50:51.360 --> 50:54.340 Solution Y_1 looks like 50:54.335 --> 50:59.765 Y_1(x,t), looks like e^(ipx)^(/ 50:59.773 --> 51:04.263 ℏ )Y_1, 51:04.264 --> 51:07.494 Y_E1(x). 51:07.489 --> 51:10.629 That's one solution for energy E_1. 51:10.630 --> 51:16.170 Then there's another solution, Y_2 (x) 51:16.172 --> 51:21.172 looks like e^(ipx) ^(/ℏ) Y 51:21.170 --> 51:23.080 _E2(x). 51:23.079 --> 51:25.659 This function has all the properties I mentioned, 51:25.657 --> 51:27.427 namely nothing depends on time. 51:27.429 --> 51:29.839 That has the same property. 51:33.327 --> 51:36.367 linear equation, it's also true that this 51:36.369 --> 51:38.849 Y, which is Y_1 51:38.853 --> 51:43.443 Y_2, add this one to this one, 51:43.440 --> 51:45.800 is also a solution. 51:45.800 --> 51:47.870 I think I have done it many, many times. 51:47.869 --> 51:50.129 If you take a linear equation, Y_1 obeys the 51:53.320 --> 51:55.670 Add the left hand side to the left hand side and right hand 51:55.666 --> 51:57.716 side to the right hand side, you will find that if 51:57.722 --> 52:00.092 Y_1 obeys it and Y_2 does, 52:00.090 --> 52:02.280 Y_1 Y_2 also obeys 52:02.284 --> 52:02.504 it. 52:02.500 --> 52:04.690 Not only that, it can be even more general. 52:04.690 --> 52:07.890 You can multiply this by any number, 52:07.889 --> 52:10.859 Y_1(x,t), any constant, 52:10.860 --> 52:12.350 A_2 Y_2 52:12.351 --> 52:13.631 (x,t), but A_1 and 52:13.628 --> 52:14.668 A_2 don't depend on time. 52:16.519 --> 52:17.969 Can you see that? 52:17.969 --> 52:21.179 That's superposition of solutions. 52:21.179 --> 52:22.959 It's a property of linear equations. 52:26.347 --> 52:29.057 equation, therefore you can add solutions. 52:29.059 --> 52:32.719 But take a solution of this form. 52:32.719 --> 52:34.769 Even though Y_1 is a 52:34.766 --> 52:37.206 product of some F and a Y, 52:37.210 --> 52:38.690 and Y_2 is a product of some 52:38.690 --> 52:40.340 F_2 and Y_2, 52:40.340 --> 52:45.360 the sum is not a product of some F and some Y. 52:45.360 --> 52:47.800 You cannot write it as a product, you understand? 52:47.800 --> 52:49.540 That's a product, and that's a product, 52:49.536 --> 52:52.276 but their sum is not a product, because you cannot pull out a 52:52.280 --> 52:54.520 common function of time from the two of them. 52:54.518 --> 52:57.658 They have different time dependence. 52:57.659 --> 53:01.419 But that is also a solution. 53:01.420 --> 53:06.330 In fact, now you can ask yourself, what is the most 53:06.327 --> 53:10.937 general solution I can build in this problem? 53:10.940 --> 53:14.970 Well, I think you can imagine that I can now write 53:14.967 --> 53:20.057 Y(x) and t as A_EY 53:20.063 --> 53:23.873 _E(x,t), sum over all the allowed 53:23.867 --> 53:24.477 Es. 53:28.309 --> 53:29.219 Do you agree? 53:31.829 --> 53:34.009 You add them all up, multiply by any constant 53:34.010 --> 53:35.990 A_E, that also satisfies 53:37.480 --> 53:41.160 So now I'm suddenly manufacturing more complicated 53:41.159 --> 53:42.059 solutions. 53:42.059 --> 53:45.209 The original modest goal was to find a product form, 53:45.210 --> 53:47.830 but once you got the product form, you find if you add them 53:47.827 --> 53:49.627 together, you get a solution that's no 53:49.625 --> 53:52.175 longer a product of x and a product of t, 53:52.179 --> 53:53.729 function of x and a function of t, 53:53.730 --> 53:55.680 because this guy has one time dependence; 53:55.679 --> 53:58.229 another term is a different time dependence. 53:58.230 --> 54:00.280 You cannot pull them all out. 54:00.280 --> 54:03.140 So we are now manufacturing solutions that don't look like 54:03.137 --> 54:03.987 their products. 54:03.989 --> 54:07.239 This is the amazing thing about solving the linear equation. 54:07.239 --> 54:10.479 You seem to have very modest goals when you start with a 54:10.476 --> 54:12.126 product form, but in the end, 54:12.125 --> 54:16.065 you find that you can make up a linear combination of products. 54:16.070 --> 54:21.430 Then the only question is, will it cover every possible 54:21.434 --> 54:23.824 situation you give me? 54:23.820 --> 54:26.200 In other words, suppose you come to me with an 54:26.195 --> 54:27.565 arbitrary initial state. 54:27.570 --> 54:29.320 I don't know anything about it, and you say, 54:29.322 --> 54:30.672 "What is its future?" 54:30.670 --> 54:32.270 Can I handle that problem? 54:32.268 --> 54:35.088 And the answer is, I can, and I'll tell you why 54:35.090 --> 54:36.010 that is true. 54:36.010 --> 54:41.720 Y(x) and t looks like A_E. 54:41.719 --> 54:45.949 I'm going to write this more explicitly as 54:45.945 --> 54:52.125 Y_E(x)e^(- ipx/ℏ). 54:52.130 --> 54:56.740 Look at this function now at t = 0. 54:56.739 --> 55:01.809 At t = 0, I get Y(x) and 0 55:01.807 --> 55:08.417 to be ΣA_E Y_E(x). 55:08.420 --> 55:12.660 In other words, I can only handle those 55:12.661 --> 55:17.911 problems whose initial state looks like this. 55:17.909 --> 55:23.579 But my question is, should I feel limited in any 55:23.581 --> 55:26.601 way by the restriction? 55:26.599 --> 55:27.759 Do you follow what I'm saying? 55:27.760 --> 55:30.090 Maybe I'll say it one more time. 55:30.090 --> 55:34.020 This is the most general solution I'm able to manufacture 55:34.023 --> 55:37.343 that looks like this, A_E 55:37.335 --> 55:42.125 Y_E(x)e^(- ipx/ℏ). 55:42.130 --> 55:44.860 It's a sum over solution to the product form with variable, 55:44.858 --> 55:46.738 each one with a different coefficient. 55:49.820 --> 55:53.080 If I take that solution and say, "What does it do at 55:53.077 --> 55:54.297 t = 0?" 55:54.300 --> 55:56.610 I find it does the following. 55:56.610 --> 56:04.060 At t = 0, it looks like this. 56:04.059 --> 56:09.589 So only for initial functions of this form I have the future. 56:09.590 --> 56:14.330 But the only is not a big only, because every function you can 56:14.329 --> 56:19.069 give me at t = 0 can always be written in this form. 56:19.070 --> 56:22.200 It's a mathematical result that says that just like sines and 56:22.202 --> 56:25.492 cosines and certain exponentials are a complete set of functions 56:25.490 --> 56:27.110 for expanding any function. 56:27.110 --> 56:30.290 The mathematical theory tells you that the solutions of H 56:30.289 --> 56:33.489 Y = E Y, if you assemble all of them, 56:33.487 --> 56:36.977 can be used to build up an arbitrary initial function. 56:36.980 --> 56:42.500 That means any initial function you give me, I can write this 56:42.503 --> 56:47.663 way, and the future of that initial state is this guy. 56:47.659 --> 56:48.329 Yes? 56:48.329 --> 56:52.979 Student: > 56:52.980 --> 56:53.650 Prof: Yes. 56:53.650 --> 56:56.580 Lots of mathematical restrictions, 56:56.579 --> 56:57.999 single valued. 56:58.000 --> 57:01.800 Physicists usually don't worry about those restrictions till of 57:01.800 --> 57:03.580 course they get in trouble. 57:03.579 --> 57:07.229 Then we go crawling back to the math guys to help us out. 57:07.230 --> 57:10.510 So just about anything you can write down, by the way physics 57:10.512 --> 57:13.632 works, things tend to be continuous and differentiable. 57:13.630 --> 57:15.640 That's the way natural things are. 57:15.639 --> 57:19.279 So for any function we can think of it is true. 57:19.280 --> 57:21.770 You go the mathematicians, they will give you a function 57:21.766 --> 57:24.026 that is nowhere continuous, nowhere differentiable, 57:24.025 --> 57:25.785 nowhere defined, nowhere something. 57:25.789 --> 57:28.579 That's what makes them really happy. 57:28.579 --> 57:31.929 But they are all functions the way they've defined it, 57:31.929 --> 57:33.489 but they don't happen in real life, 57:33.489 --> 57:36.139 because whatever happens here influences what happens on 57:36.144 --> 57:38.734 either side of it, so things don't change in a 57:38.733 --> 57:39.843 discontinuous way. 57:39.840 --> 57:41.300 Unless you apply an infinite force, 57:41.300 --> 57:43.060 an infinite potential, infinite something, 57:43.059 --> 57:45.609 everything has got what's called C infinity, 57:45.610 --> 57:47.990 can differentiate any number of times. 57:47.989 --> 57:49.449 So we don't worry about the restriction. 57:49.449 --> 57:54.089 So in the world of physicists' functions, you can write any 57:54.094 --> 57:57.864 initial function in terms of these functions. 57:57.860 --> 58:01.240 So let me tell you then the process for solving the 58:04.559 --> 58:05.529 Are you with me? 58:05.530 --> 58:08.270 You come and give me Y(x, 0), 58:08.269 --> 58:10.879 and you say, "As a function of time, 58:10.880 --> 58:13.360 where is it going to end up?" 58:13.360 --> 58:14.220 That's your question. 58:14.219 --> 58:15.609 That's all you can ask. 58:15.610 --> 58:17.500 Initial state, final state. 58:17.500 --> 58:23.120 This is given, this is needed. 58:23.119 --> 58:26.079 So I'll give you a 3 step solution. 58:26.079 --> 58:36.169 Step 1, find A_E= Y_E 58:36.168 --> 58:45.068 *(x) Y(x,0). 58:45.070 --> 58:54.160 Step 2, Y(x) and t = this A_E 58:54.164 --> 59:00.534 that you got times e^(-ipx/ 59:00.530 --> 59:08.260 ℏ)Y _E(x). 59:08.260 --> 59:11.650 So what I'm telling you is, the fate of a function Y 59:11.648 --> 59:15.268 with the wiggles and jiggles is very complicated to explain. 59:15.268 --> 59:17.698 Some wiggle goes into some other wiggle that goes into some 59:17.704 --> 59:19.304 other wiggle as a function of time, 59:19.300 --> 59:22.760 but there is a basic simplicity underlying that evolution. 59:22.760 --> 59:24.630 The simplicity is the following. 59:24.630 --> 59:29.270 If at t = 0 you expand your Y as such a sum, 59:29.268 --> 59:31.798 where the coefficients are given by the standard rule, 59:31.800 --> 59:35.720 then as time goes away from t = 0, 59:35.719 --> 59:39.549 all you need to do is to multiply each coefficient by the 59:39.545 --> 59:43.025 particular term involving that particular energy. 59:43.030 --> 59:49.200 And that gives you the Y at later times. 59:49.199 --> 59:54.329 A state of definite energy in this jargon will be the one in 59:54.327 --> 59:58.497 which every term is absent except 1, maybe E = 59:58.498 --> 1:00:00.408 E_1. 1:00:00.409 --> 1:00:02.869 That is the kind we study. 1:00:02.869 --> 1:00:06.279 That state has got only 1 term in the sum and its time 1:00:06.284 --> 1:00:10.024 evolution is simply given by this and all probabilities are 1:00:10.021 --> 1:00:10.861 constant. 1:00:10.860 --> 1:00:14.080 But if you mix them up with different coefficients, 1:00:14.083 --> 1:00:16.923 you can then handle any initial condition. 1:00:16.920 --> 1:00:21.790 So we have now solved really for the future of any quantum 1:00:21.786 --> 1:00:23.576 mechanical problem. 1:00:23.579 --> 1:00:28.969 So I'm going to give you from now to the end of class concrete 1:00:28.969 --> 1:00:30.649 examples of this. 1:00:30.650 --> 1:00:35.140 But I don't mind again answering your questions, 1:00:35.139 --> 1:00:40.869 because it's very hard for me to put myself in your place. 1:00:40.869 --> 1:00:44.619 So I'm trying to remember when I did not know quantum 1:00:44.621 --> 1:00:48.231 mechanics, sitting in some sandbox and some kid was 1:00:48.228 --> 1:00:50.318 throwing sand in my face. 1:00:50.320 --> 1:00:51.300 So I don't know. 1:00:51.300 --> 1:00:55.160 I've lost my innocence and I don't know how it looks to you. 1:00:55.159 --> 1:00:56.109 Yes. 1:00:56.110 --> 1:00:58.080 Student: For each of these problems, 1:00:58.079 --> 1:01:00.869 you have to solve that equation you gave us before to find the 1:01:00.873 --> 1:01:02.343 form of the Y_E, 1:01:02.340 --> 1:01:02.890 right? 1:01:02.889 --> 1:01:05.429 Prof: Right. 1:01:05.429 --> 1:01:10.219 So let's do the following problem. 1:01:10.219 --> 1:01:16.909 Let us take a world in which everything is inside the box of 1:01:16.909 --> 1:01:18.949 length L. 1:01:18.949 --> 1:01:24.129 And someone has manufactured for you a certain state. 1:01:24.130 --> 1:01:26.530 Let me come to that case in a minute. 1:01:26.530 --> 1:01:29.860 Let me take a simple case then I'll build up the situation you 1:01:29.858 --> 1:01:30.238 want. 1:01:30.239 --> 1:01:35.739 Let's first take a simple case where at t = 0 1:01:35.735 --> 1:01:40.045 Y(x,0) = the square root of 1:01:40.047 --> 1:01:45.217 2/Lsine(n px/L). 1:01:45.219 --> 1:01:51.249 That is just a function with n oscillations. 1:01:51.250 --> 1:01:54.060 You agree, that's a state of definite energy. 1:01:54.059 --> 1:01:59.069 The energy of that state, E_n, 1:01:59.068 --> 1:02:03.638 is ℏ^(2) p^(2)n^(2)/ 1:02:03.641 --> 1:02:05.711 2mL^(2). 1:02:05.710 --> 1:02:08.240 We did that last time. 1:02:08.239 --> 1:02:09.699 And the reason, why were we so interested in 1:02:09.699 --> 1:02:10.309 these functions? 1:02:10.309 --> 1:02:12.429 Now I can tell you why. 1:02:12.429 --> 1:02:15.459 If this is my initial state, let me take a particular 1:02:15.460 --> 1:02:17.760 n, then the state at any future 1:02:17.760 --> 1:02:21.480 time, Y(x,t), is very simple here, 1:02:21.476 --> 1:02:24.966 the square root of 2/Lsine(n 1:02:24.972 --> 1:02:29.502 px/L), times e^(-ipx/ 1:02:29.496 --> 1:02:33.986 ℏ), where energy is 1:02:33.994 --> 1:02:39.064 n^(2)p ^(2) 1:02:39.063 --> 1:02:45.773 ℏ^(2) /2mL^(2). 1:02:45.769 --> 1:02:46.559 That's it. 1:02:46.559 --> 1:02:50.739 That is the function of time. 1:02:50.739 --> 1:02:53.639 All I've done to that initial state is multiply by 1:02:53.637 --> 1:02:56.417 e^(-iEt), but E is not some random 1:02:56.418 --> 1:02:57.068 number. 1:02:57.070 --> 1:03:00.540 E is labeled by n and E_nis whatever you 1:03:00.539 --> 1:03:01.199 have here. 1:03:01.199 --> 1:03:05.009 That's the time dependence of that state. 1:03:05.010 --> 1:03:09.900 It's very clear that if you took the absolute value of this 1:03:09.896 --> 1:03:14.696 Y, this guy has absolute value = 1 at all times. 1:03:14.699 --> 1:03:16.929 It's like saying cos t depends on time, 1:03:16.929 --> 1:03:20.789 sine t depends on time, but cos^(2) sine^(2), 1:03:20.789 --> 1:03:23.029 cos^(2 )t sine^(2) t seems to depend on 1:03:23.025 --> 1:03:25.275 time, but it doesn't. 1:03:25.280 --> 1:03:28.230 So this seems to depend on time and it does, but when you take 1:03:28.228 --> 1:03:29.918 the absolute value, it goes away. 1:03:29.920 --> 1:03:31.490 That's the simplest problem. 1:03:31.489 --> 1:03:34.879 I gave you an initial state, the future is very simple, 1:03:34.875 --> 1:03:36.125 attach the factor. 1:03:36.130 --> 1:03:39.250 Now let's give you a slightly more complicated state. 1:03:39.250 --> 1:03:44.810 The more complicated state will be--I'm going to hide that for 1:03:44.811 --> 1:03:45.361 now. 1:03:45.360 --> 1:03:53.150 Let us take a Y(x,0) that looks 1:03:53.154 --> 1:04:01.304 like 3 times square root of 2/Lsine(2 1:04:01.302 --> 1:04:08.922 px/L) 4 times sine... 1:04:08.920 --> 1:04:14.890 This is my initial state. 1:04:14.889 --> 1:04:16.299 What does it look like? 1:04:16.300 --> 1:04:19.420 It's a sum of 2 energy states. 1:04:19.420 --> 1:04:22.690 This guy is what I would call Y_2 in my 1:04:22.690 --> 1:04:24.890 notation, the second highest state. 1:04:24.889 --> 1:04:27.669 This guy is Y_3. 1:04:27.670 --> 1:04:34.410 Everybody is properly normalized, and these are the 1:04:34.411 --> 1:04:36.031 As. 1:04:36.030 --> 1:04:40.100 So this state, if you measure its energy, 1:04:40.103 --> 1:04:42.143 what will you get? 1:04:42.139 --> 1:04:48.029 Anybody tell me what answers I can get if I measure energy now? 1:04:48.030 --> 1:04:52.260 You want to guess what are the possible energies I could get? 1:04:52.260 --> 1:04:54.200 Yes. 1:04:54.199 --> 1:04:57.399 Any of you, either of you. 1:04:57.400 --> 1:04:59.650 Can you tell? 1:04:59.650 --> 1:05:05.060 No? 1:05:05.059 --> 1:05:05.799 Yes? 1:05:05.800 --> 1:05:10.610 Student: You can get h^(2)p^(2) times 1:05:10.614 --> 1:05:13.194 4/2mL^(2), or times 9. 1:05:13.190 --> 1:05:16.700 Prof: So her answer was, you can get in my convention 1:05:16.697 --> 1:05:20.257 E_2or E_3, 1:05:20.260 --> 1:05:22.790 just put n = to 2 0r 3 That's all you have, 1:05:22.789 --> 1:05:26.049 your function written as a sum over Y_E is 1:05:26.047 --> 1:05:26.887 only 2 terms. 1:05:26.889 --> 1:05:29.449 That means they are the only 2 energies you can get. 1:05:29.449 --> 1:05:31.589 So it's not a state of definite energy. 1:05:31.590 --> 1:05:34.190 You can get either this answer or this answer. 1:05:34.190 --> 1:05:36.200 But now you can sort of see, it's more likely to get this 1:05:36.197 --> 1:05:38.017 guy, because it has a 4 in front of 1:05:38.019 --> 1:05:40.009 it, and less likely to get this guy, 1:05:40.010 --> 1:05:44.040 and impossible to get anything else. 1:05:44.039 --> 1:05:52.309 So the probability for getting n = 2 is proportional to 1:05:52.309 --> 1:05:56.949 3^(2), and the probability for getting 1:05:56.952 --> 1:06:01.262 n = 3 is proportional to 4^(2). 1:06:01.260 --> 1:06:04.000 If you want the absolute probabilities, 1:06:04.000 --> 1:06:07.910 then you can write it as 3^(2) divided by 3^(2) 4^(2), 1:06:07.909 --> 1:06:15.259 which is 4^(2), or you can write it as 3^(2) 1:06:15.255 --> 1:06:18.155 4^(2) is 5^(2). 1:06:18.159 --> 1:06:21.349 See, if you square these probabilities, 1:06:21.349 --> 1:06:23.449 you get 25,3^(2) 4^(2). 1:06:23.449 --> 1:06:26.609 If you want to get 1, I think you can see without too 1:06:26.614 --> 1:06:29.774 much trouble, if you rescale the whole thing 1:06:29.766 --> 1:06:33.146 by 1 fifth, now you'll find the total 1:06:33.146 --> 1:06:35.776 probabilities add up to 1. 1:06:35.780 --> 1:06:38.840 That's the way to normalize the function, that's the easy way. 1:06:38.840 --> 1:06:41.650 The hard way is to square all of this and integrate it and 1:06:41.646 --> 1:06:44.056 then set it = to 1 and see what you have to do. 1:06:44.059 --> 1:06:46.279 In the end, all you will have to do is divide by 5. 1:06:46.280 --> 1:06:48.330 I'm just giving you a shortcut. 1:06:48.329 --> 1:06:51.419 When you expand the Y in terms of normalized functions, 1:06:51.422 --> 1:06:53.962 then the coefficient squared should add up to 1. 1:06:53.960 --> 1:06:56.060 If they don't, you just divide them by 1:06:56.063 --> 1:06:57.203 whatever it takes. 1:06:57.199 --> 1:07:01.339 So this has got a chance 3 is to 5 of being this or that 1:07:01.342 --> 1:07:02.022 energy. 1:07:02.018 --> 1:07:05.438 But as a function of time, you will find here things vary 1:07:05.436 --> 1:07:06.166 with time. 1:07:06.170 --> 1:07:07.610 This is not going to be time independent. 1:07:07.610 --> 1:07:09.550 I want to show you that. 1:07:09.550 --> 1:07:16.320 So Y(x,t) now is going to be (3/5√(2/L 1:07:16.322 --> 1:07:21.292 ))sine(2 px/L) times 1:07:21.289 --> 1:07:24.449 e^(−i(E2)). 1:07:24.449 --> 1:07:26.379 I don't want to write the full formula for E_n 1:07:26.382 --> 1:07:27.042 every time. 1:07:27.039 --> 1:07:30.309 I'm just going to call it E_2, 1:07:30.309 --> 1:07:42.679 (4/5√(2/L))sine (3px/L) times 1:07:42.677 --> 1:07:50.097 e^(−i(E3)t/ℏ. 1:07:50.099 --> 1:07:55.659 )Now you notice that if I found the probability to be at 1:07:55.661 --> 1:07:59.341 sum x, p(x,t), I have to take the 1:07:59.340 --> 1:08:02.640 absolute square of all of this. 1:08:02.639 --> 1:08:06.309 And all I want you to notice is that the absolute square of all 1:08:06.309 --> 1:08:09.269 of this, you cannot drop these exponentials now. 1:08:09.268 --> 1:08:11.488 If you've got two of them, you cannot drop them, 1:08:11.489 --> 1:08:13.569 because when you take Y_1 1:08:13.570 --> 1:08:15.650 Y_2 absolute squared, 1:08:15.650 --> 1:08:17.540 Y_1 Y_2, 1:08:17.538 --> 1:08:20.088 you multiply it by Y_1 conjugate 1:08:20.086 --> 1:08:23.476 Y_2 conjugate, let's do that. 1:08:23.479 --> 1:08:29.059 So you want to multiply the whole thing by its conjugate. 1:08:29.060 --> 1:08:33.750 So first you take the absolute square of this. 1:08:33.750 --> 1:08:39.430 You will get (9/25)(2/L)sin^(2)(2 1:08:39.426 --> 1:08:42.626 px/L). 1:08:42.630 --> 1:08:45.380 And the absolute value of this is just 1. 1:08:45.380 --> 1:08:46.130 You see that? 1:08:46.130 --> 1:08:49.290 That is Y_1* Y_1. 1:08:49.288 --> 1:08:50.828 Then you must take Y_2* 1:08:50.831 --> 1:08:51.741 Y_2. 1:08:51.739 --> 1:09:00.069 That will be 16/25√(2/L)-- I'm sorry, no square 1:09:00.073 --> 1:09:04.803 root--2/Lsin^(2)(3px/L) times 1, 1:09:04.800 --> 1:09:08.460 because the absolute value of this guy with itself is 1. 1:09:08.460 --> 1:09:11.090 But that's not the end. 1:09:11.090 --> 1:09:15.030 You've got 2 more terms which look like Y_1 1:09:15.033 --> 1:09:18.553 ^(*)Y_2 Y_2* 1:09:18.546 --> 1:09:20.336 Y_1. 1:09:20.340 --> 1:09:23.310 I'm not going to work out all the details, but let me just 1:09:23.307 --> 1:09:25.337 show you that time dependence exists. 1:09:25.340 --> 1:09:26.750 So if you take Y_1^(*) 1:09:26.751 --> 1:09:32.651 Y_2, you will get (3/5√(2/L 1:09:32.645 --> 1:09:40.905 ))sine(2 px/L) times e^( 1:09:40.912 --> 1:09:47.562 iE2t/ℏ)^( )times-- sorry. 1:09:47.560 --> 1:09:53.770 3/5 times (4/5√(2/L))sine 1:09:53.768 --> 1:10:02.658 (3px/L) times e^((i(E2)−i(E3)t) 1:10:02.662 --> 1:10:08.202 /ℏ) 1 more term. 1:10:08.198 --> 1:10:10.378 I don't care about any of these things. 1:10:10.380 --> 1:10:14.280 I'm asking you to see, do things depend on time or 1:10:14.282 --> 1:10:14.762 not? 1:10:14.760 --> 1:10:17.390 This has no time dependence because the absolute value of 1:10:17.387 --> 1:10:18.137 that vanished. 1:10:18.140 --> 1:10:20.320 This has no time dependence, the absolute value of this 1:10:20.315 --> 1:10:20.755 vanished. 1:10:20.760 --> 1:10:23.510 But the cross terms, when you multiply the conjugate 1:10:23.506 --> 1:10:25.816 of this by this, or the conjugate of this by 1:10:25.822 --> 1:10:27.332 that, they don't cancel. 1:10:27.329 --> 1:10:29.069 That's all I want you to know. 1:10:29.069 --> 1:10:31.729 So I'll get a term like this this complex conjugate. 1:10:31.729 --> 1:10:33.579 I don't want to write that in detail. 1:10:33.578 --> 1:10:36.328 If you combine this function with the conjugate, 1:10:36.329 --> 1:10:39.549 you'll find this the conjugate will give me a cosine. 1:10:39.550 --> 1:10:54.340 So I should probably write it on another part of the board. 1:10:54.340 --> 1:10:57.300 So maybe I don't even want to write it because it's in the 1:10:57.304 --> 1:10:57.724 notes. 1:10:57.720 --> 1:11:00.830 I want you to notice the following - look at the first 1:11:00.828 --> 1:11:02.998 term, no time dependence, second term, 1:11:03.000 --> 1:11:04.350 no time dependence. 1:11:04.350 --> 1:11:08.240 The cross term has an e to the something and I claim the other 1:11:08.242 --> 1:11:11.052 cross term will have e to the - something. 1:11:11.050 --> 1:11:13.530 e to the i something or e to the -i something is 1:11:13.532 --> 1:11:14.592 the cosine of something. 1:11:14.590 --> 1:11:16.140 That's all I want you to know. 1:11:16.140 --> 1:11:21.070 So there is somewhere in the time dependence P(x,t) 1:11:21.070 --> 1:11:25.570 that's got a lot of stuff which is t independent, 1:11:25.569 --> 1:11:28.239 something that looks like a whole bunch of numbers, 1:11:28.238 --> 1:11:34.798 times cosine(E_2 - E_3)t /ℏ. 1:11:34.800 --> 1:11:38.050 That's all I want you to notice. 1:11:38.050 --> 1:11:41.130 That means the probability density will be oscillating. 1:11:41.130 --> 1:11:45.280 The particle will not be fixed; it will be bouncing back and 1:11:45.277 --> 1:11:46.977 forth between the walls. 1:11:46.979 --> 1:11:50.629 And the rate at which it bounces is given by the 1:11:50.628 --> 1:11:55.288 difference in energy between the two states you formed in the 1:11:55.287 --> 1:11:56.527 combination. 1:11:56.529 --> 1:11:59.229 So this is how a particle in general-- 1:11:59.229 --> 1:12:01.129 if you want, not the most general one, 1:12:01.130 --> 1:12:04.810 but it's a reasonably general case where you added some 1:12:04.805 --> 1:12:06.665 mixture of that-- let me see. 1:12:06.670 --> 1:12:08.260 You added 2 to 3. 1:12:08.260 --> 1:12:13.500 You added that state that state. 1:12:13.500 --> 1:12:19.030 You added 4 times fifth of that times 3 fifths of that as the 1:12:19.027 --> 1:12:20.867 initial condition. 1:12:20.869 --> 1:12:21.299 Okay? 1:12:21.300 --> 1:12:24.240 4 fifths of this one guy with 2 wiggles and 3 fifths with 3 1:12:24.235 --> 1:12:26.105 wiggles and you let it go in time, 1:12:26.109 --> 1:12:29.419 you will find then if you add these time dependences, 1:12:29.420 --> 1:12:31.150 there'll be a part that varies with time. 1:12:31.149 --> 1:12:33.259 So the density will not be constant now. 1:12:33.260 --> 1:12:37.540 It will be sloshing back and forth in the box. 1:12:37.539 --> 1:12:39.329 That's a more typical situation. 1:12:39.328 --> 1:12:41.308 So not every state, initial state, 1:12:41.305 --> 1:12:44.055 is a function of a state of definite energy. 1:12:44.060 --> 1:12:45.070 It's an admixture. 1:12:45.069 --> 1:12:48.199 I've taken the simplest case where the admixture has only 2 1:12:48.203 --> 1:12:48.963 parts in it. 1:12:48.960 --> 1:12:51.410 You can imagine taking a function made of 3 parts and 4 1:12:51.407 --> 1:12:53.937 parts and 10 parts and when you square them and all that, 1:12:53.944 --> 1:12:55.354 you'll get 100 cross terms. 1:12:55.350 --> 1:12:58.760 They'll all be oscillating at different rates. 1:12:58.760 --> 1:13:04.400 But the frequencies will always be given by the difference in 1:13:04.399 --> 1:13:09.569 frequencies, differences in energies that went into your 1:13:09.570 --> 1:13:10.700 mixture. 1:13:10.698 --> 1:13:12.548 The last problem which I'm not going to do now, 1:13:12.550 --> 1:13:14.680 I'll do next time, but I'll tell you what it is I 1:13:14.679 --> 1:13:16.319 want to do, which is really this 1:13:16.319 --> 1:13:19.699 mathematically more involved, but the idea is the same. 1:13:19.698 --> 1:13:22.378 Here I gave you the initial state on a plate. 1:13:22.380 --> 1:13:24.630 I just said, here it is, 3 fifths times 1 1:13:24.631 --> 1:13:27.951 function of definite energy, 4 fifths times another function 1:13:27.953 --> 1:13:29.253 of definite energy. 1:13:29.250 --> 1:13:32.170 The problem you really want to be able to solve right now is 1:13:32.166 --> 1:13:34.776 when somebody gives you an arbitrary initial state and 1:13:34.784 --> 1:13:37.064 says, "What happens to it?" 1:13:37.060 --> 1:13:42.320 So I'm going to consider next time a function that looks 1:13:42.322 --> 1:13:47.492 something like this - x times 1 - x is my 1:13:47.488 --> 1:13:49.688 function at time 0. 1:13:49.689 --> 1:13:52.619 That's a nice function, because it vanishes at 0, 1:13:52.619 --> 1:13:53.779 it vanishes at 1. 1:13:53.779 --> 1:13:56.599 It's a box of length L = 1. 1:13:56.600 --> 1:14:00.800 It's an allowed initial state. 1:14:00.800 --> 1:14:02.800 Then I can ask, what does this do. 1:14:02.800 --> 1:14:06.180 So you should think about how do I predict its future, 1:14:06.180 --> 1:14:07.330 what's involved? 1:14:07.328 --> 1:14:09.668 So you will see that in the notes. 1:14:09.670 --> 1:14:13.140 So what I'm going to do next time is to finish this problem 1:14:13.144 --> 1:14:15.784 and give you the final set of postulates, 1:14:15.779 --> 1:14:18.799 so that you can see what the rules of quantum mechanics are. 1:14:18.800 --> 1:14:24.000