WEBVTT 00:01.380 --> 00:03.780 Shall we begin now? 00:03.780 --> 00:06.360 So as usual, and as promised, 00:06.356 --> 00:11.776 I will tell you what we have done so far, and that's all you 00:11.784 --> 00:15.924 really need to know, to follow what's going to 00:15.924 --> 00:17.584 happen next. 00:17.580 --> 00:22.230 The first thing we learned is if you're studying a particle 00:22.226 --> 00:26.206 living in one dimension, that's all I'm going to do the 00:26.214 --> 00:29.504 whole time because it's mathematically easier and there 00:29.497 --> 00:33.447 is not many new things you gain by going to higher dimensions. 00:33.450 --> 00:38.070 There's a particle somewhere in this one-dimensional universe. 00:38.070 --> 00:43.700 Everything you need to know about that particle is contained 00:43.701 --> 00:49.431 in a function called the wave function, and is denoted by the 00:49.427 --> 00:51.047 symbol ψ. 00:51.050 --> 00:54.080 By the way, everything I'm doing now is called kinematics. 00:54.080 --> 00:57.310 In other words, kinematics is a study of how to 00:57.309 --> 01:00.609 describe a system completely at a given time. 01:00.609 --> 01:02.909 For example, in classical mechanics for a 01:02.912 --> 01:06.312 single particle the complete description of that particle is 01:06.310 --> 01:09.460 given by two things, where is it, 01:09.460 --> 01:13.170 and what its momentum is. 01:13.170 --> 01:18.090 Dynamics is the question of how this changes with time. 01:18.090 --> 01:21.010 If you knew all you could know about the particle now can you 01:21.007 --> 01:22.027 predict the future? 01:22.030 --> 01:24.580 By predict the future we mean can you tell me what x 01:24.580 --> 01:26.950 will be at a later time and p will be at a later 01:26.953 --> 01:27.353 time. 01:27.349 --> 01:29.709 That's Newtonian mechanics. 01:29.709 --> 01:32.359 So the kinematics is just how much do you need to know at a 01:32.358 --> 01:34.228 given time, just x and p. 01:34.230 --> 01:36.840 Once you've got x and p everything follows. 01:36.840 --> 01:39.300 As I mentioned to you, the kinetic energy, 01:39.300 --> 01:41.390 for example, which you write as 01:45.039 --> 01:47.989 p, or in higher dimensions the 01:47.989 --> 01:52.129 angular momentum is some cross product of position and 01:52.132 --> 01:54.782 momentum, so you can get everything of 01:54.783 --> 01:57.763 interest just by giving the position and momentum. 01:57.760 --> 02:02.890 I claim now the equivalent of this pair of numbers in this 02:02.894 --> 02:07.314 quantum world is one function, ψ(x). 02:07.310 --> 02:09.940 So it's a lot more information than you had in classical 02:09.941 --> 02:10.421 physics. 02:10.419 --> 02:12.369 In classical physics two numbers tell you the whole 02:12.367 --> 02:12.677 story. 02:12.680 --> 02:15.220 Quantum theory says "give me a whole function", 02:15.218 --> 02:17.888 and we all know a function is really infinite amount of 02:17.890 --> 02:20.560 information because at every point x the function has a 02:20.562 --> 02:22.842 height and you've got to give me all that. 02:22.840 --> 02:25.730 Only then you have told me everything. 02:25.729 --> 02:26.849 That's the definition. 02:26.848 --> 02:29.278 And the point is ψ can be real, 02:29.282 --> 02:32.152 ψ can be complex, and sometimes ψ 02:32.145 --> 02:33.215 is complex. 02:33.220 --> 02:35.670 So we can ask, you've got this function, 02:35.670 --> 02:38.630 you say it tells me everything I can know, well, 02:38.626 --> 02:41.326 what can I find out from this function? 02:41.330 --> 02:46.570 The first thing is that if you took the absolute square of this 02:46.574 --> 02:50.894 function, that is the probability density to find it 02:50.889 --> 02:53.089 at the point x. 02:53.090 --> 02:56.670 By that I mean if you multiply both by some infinitesimal 02:56.667 --> 03:00.247 Δx that is the probability that the particle 03:00.245 --> 03:03.115 will be between x and x dx. 03:03.120 --> 03:05.190 That means that you take this ψ and you square it. 03:05.188 --> 03:08.538 So you will get something that will go to 0 here, 03:08.544 --> 03:11.624 go up, go to zero, do something like that. 03:11.620 --> 03:15.660 This is ψ^(2), and that's your probability 03:15.662 --> 03:18.842 density and what we mean by density is, 03:18.840 --> 03:23.650 if the function p(x) has an area with the x-axis 03:23.647 --> 03:28.297 like p(x)dx that's the actual probability that if you 03:28.300 --> 03:32.480 look for this guy you'll find him or her or it in this 03:32.478 --> 03:35.188 interval, okay? 03:35.190 --> 03:42.840 So we will make the requirement that the total probability to 03:42.837 --> 03:46.787 find it anywhere add up to 1. 03:46.788 --> 03:50.938 That is a convention because--well, 03:50.943 --> 03:52.903 in some sense. 03:52.900 --> 03:54.990 It's up to you how you want to define probability. 03:54.990 --> 03:58.620 You say, "What are the odds I will get through this 03:58.617 --> 04:00.067 course, 50/50?" 04:00.068 --> 04:02.658 That doesn't add up to 1 that adds up to 100, 04:02.659 --> 04:06.309 but it gives you the impression the relative odds are equal. 04:06.310 --> 04:08.150 So you can always give odds. 04:08.150 --> 04:11.090 Jimmy the Greek may tell you something, 7 is to 4 something's 04:11.087 --> 04:11.967 going to happen. 04:11.969 --> 04:13.779 They don't add up to 1 either. 04:13.780 --> 04:18.090 I mean, 7 divided by 11 is one thing and 4 divided by 11 is the 04:18.089 --> 04:19.689 absolute probability. 04:19.689 --> 04:24.299 So in quantum theory the wave function you're given need not 04:24.302 --> 04:29.232 necessarily have the property that its square integral is 1, 04:29.230 --> 04:31.610 but you can rescale it by a suitable number, 04:31.610 --> 04:34.970 I mean, if it's not 1, but if it's 100 then you divide 04:34.968 --> 04:38.898 it by 10 and that function will have a square integral of 1. 04:38.899 --> 04:41.789 That's the convention and it's a convenience, 04:41.793 --> 04:45.283 and I will generally assume that we have done that. 04:45.279 --> 04:48.169 And I also pointed out to you that the function ψ 04:48.172 --> 04:51.572 and the function 3 times ψ stand for the same situation in 04:51.565 --> 04:52.785 quantum mechanics. 04:52.790 --> 04:55.380 So this ψ is not like any other ψ. 04:55.379 --> 04:57.779 And if ψ is a water wave 3 inches versus 04:57.781 --> 05:00.571 30 inches are not the same situation, they describe 05:00.572 --> 05:02.362 completely different things. 05:02.360 --> 05:05.190 But in quantum mechanics ψ and a multiple of ψ 05:05.185 --> 05:08.115 have the same physics because the same relative odds are 05:08.117 --> 05:09.287 contained in them. 05:09.290 --> 05:11.490 So given one ψ you're free to multiply it by 05:11.485 --> 05:13.785 any number, in fact, real or complex and 05:13.788 --> 05:15.968 that doesn't change any prediction, 05:15.970 --> 05:19.890 so normally you multiply it by that number which makes the 05:19.887 --> 05:22.977 square integral in all of space equal to 1. 05:22.980 --> 05:26.100 Such a function is said to be normalized. 05:26.100 --> 05:29.360 If it's normalized the advantage is the square directly 05:29.358 --> 05:32.618 gives you the absolute probability density and integral 05:32.619 --> 05:34.309 of that will give you 1. 05:34.310 --> 05:35.730 That's one thing we learned. 05:35.730 --> 05:38.070 You understand now? 05:38.069 --> 05:42.249 What are the possible functions I can ascribe with the particle? 05:42.250 --> 05:46.740 Whatever you like within reason; it's got to be a single value 05:46.737 --> 05:49.007 and it cannot have discontinuous jumps. 05:49.009 --> 05:51.959 Beyond that anything you write down is fine. 05:51.959 --> 05:54.169 That's like saying what are the allowed positions, 05:54.170 --> 05:56.880 or allowed momentum for a particle in classical mechanics? 05:56.879 --> 05:59.319 Anything, there are no restrictions except x 05:59.322 --> 06:01.182 should be real and p should be real. 06:01.180 --> 06:03.570 You can do what you want. 06:03.569 --> 06:07.279 Similarly all possible functions describe possible 06:07.281 --> 06:08.571 quantum states. 06:08.569 --> 06:09.919 It's called a quantum state. 06:09.920 --> 06:12.840 It's this crazy situation where you don't know where it is and 06:12.839 --> 06:14.659 you give the odds by squaring ψ. 06:14.660 --> 06:18.390 That's called a quantum state and it's given by a function 06:18.386 --> 06:18.906 ψ. 06:18.910 --> 06:25.310 All right, now I also said there is one case where I know 06:25.312 --> 06:27.372 what's going on. 06:27.370 --> 06:29.310 So let me give you one other case. 06:29.310 --> 06:31.730 Maybe I will ask you to give me one case. 06:31.730 --> 06:36.290 The particle is known to be very close to x = 5 06:36.293 --> 06:41.293 because I just saw it there and ε later I know it's 06:41.286 --> 06:45.416 still got to be there because I just saw it. 06:45.420 --> 06:52.620 Now what function will describe that situation? 06:52.620 --> 06:54.490 You guys know this. 06:54.490 --> 06:57.390 Want to guess? 06:57.389 --> 07:00.249 What will ψ look like so that the particle 07:00.247 --> 07:02.787 is almost certainly near x = 5? 07:02.790 --> 07:04.920 Student: > 07:04.920 --> 07:06.060 Prof: Yeah? 07:06.060 --> 07:07.570 Centered where? 07:07.569 --> 07:09.149 Student: Centered at 5. 07:09.149 --> 07:11.999 Prof: At 5, everybody agree with that? 07:12.000 --> 07:13.630 I mean the exact shape we don't know. 07:13.629 --> 07:17.519 Maybe that's why you're hesitating, but here is the 07:17.521 --> 07:22.501 possible function that describes a particle that's location isn't 07:22.502 --> 07:25.152 known to within some accuracy. 07:25.149 --> 07:26.259 So one look at it, it tells you, 07:26.264 --> 07:27.744 "Hey, this guy's close to 5." 07:27.740 --> 07:30.130 I agree that you can put a few wiggles on it, 07:30.129 --> 07:32.649 or you can make it taller or shorter if you change the shape 07:32.646 --> 07:36.296 a bit, but roughly speaking here is 07:36.302 --> 07:39.382 what functions, describing particles of 07:39.377 --> 07:42.137 reasonably well know location, look like. 07:42.139 --> 07:45.559 They're centered at the point which is the well-known 07:45.557 --> 07:46.277 location. 07:46.279 --> 07:50.249 On the other hand, I'm going to call is ψ 07:50.254 --> 07:51.614 x = 5. 07:51.610 --> 07:54.670 That is a function, and the subscript you put on 07:54.665 --> 07:57.715 the function is a name you give the function. 07:57.720 --> 08:00.460 We don't go to a party and say, "Hi, I am human." 08:00.459 --> 08:04.299 You say, "I'm so and so," because that tells you 08:04.302 --> 08:07.812 a little more than whatever species you belong to. 08:07.810 --> 08:11.620 Similarly these are all normalizable wave functions, 08:11.615 --> 08:14.895 but x = 5 is one member of the family, 08:14.899 --> 08:18.109 which means I'm peaked at x = 5. 08:18.110 --> 08:20.880 Another function I mentioned is the function 08:20.877 --> 08:22.807 ψ_p(x). 08:22.810 --> 08:27.370 That's the function that describes a particle of momentum 08:27.372 --> 08:28.272 p. 08:28.269 --> 08:30.489 We sort of inferred that by doing the double slit 08:30.488 --> 08:31.088 experiment. 08:31.089 --> 08:32.499 That function looks like this. 08:32.500 --> 08:42.090 Some number A times e^(ipx/ℏ). 08:42.090 --> 08:44.430 Now you can no longer tell me you have no feeling for these 08:44.432 --> 08:47.102 exponentials because it's going to be all about the exponential. 08:47.100 --> 08:48.910 I've been warning you the whole term. 08:48.908 --> 08:51.128 Get used to those complex exponentials. 08:51.129 --> 08:51.939 It's got a real part. 08:51.940 --> 08:55.010 It's got an imaginary part, but more natural to think of a 08:55.008 --> 08:57.698 complex number as having a modulus and a phase, 08:57.700 --> 08:59.220 and I'm telling you it's a constant modulus. 08:59.220 --> 09:00.280 I don't know what it is. 09:00.278 --> 09:05.028 But the phase factor should look like ipx/ℏ. 09:05.028 --> 09:08.238 So if I wrote a function e to the i times 09:08.235 --> 09:10.905 96x/ℏ, and I said, "What's going 09:10.908 --> 09:11.678 on?" 09:11.678 --> 09:14.438 Well, that's a particle whose momentum is 96. 09:14.440 --> 09:18.330 So the momentum is hidden in the function right in the 09:18.331 --> 09:19.361 exponential. 09:19.360 --> 09:21.350 It's everything x of the i, the x and the 09:21.354 --> 09:21.784 ℏ. 09:21.778 --> 09:24.828 Whatever is sitting there that's the momentum. 09:24.830 --> 09:29.400 I am going to study such states pretty much all of today. 09:29.399 --> 09:31.649 So let's say someone says, "Look, I produced a 09:31.652 --> 09:33.592 particle in a state of momentum p. 09:33.590 --> 09:35.220 Here it is. 09:35.220 --> 09:38.460 Let's normalize this guy." 09:38.460 --> 09:42.530 To normalize the guy you've got to take ψ^(2) and you've got 09:42.530 --> 09:46.410 to take the dx and you've got to get it equal to 1. 09:46.408 --> 09:50.018 If you take the absolute square of this, A absolute 09:50.019 --> 09:51.919 square is some fixed number. 09:51.918 --> 09:55.378 I hope you all know the absolute value of that is 1 09:55.384 --> 09:57.884 because that times its conjugate, 09:57.879 --> 10:00.609 which is e^(−ipx/ℏ) will just give you 10:00.613 --> 10:01.983 e^(0) which is 1. 10:01.980 --> 10:12.010 I want 1 times dx over all of space to be equal to 1. 10:12.009 --> 10:15.329 That's a hopeless task because you cannot pick an A to 10:15.331 --> 10:17.401 make that happen, because all of space, 10:17.404 --> 10:20.124 the integral of dx over all of space is the length of 10:20.116 --> 10:23.746 the universe you're living in, and if that's infinite no 10:23.754 --> 10:26.084 finite A will do it. 10:26.080 --> 10:30.370 So that poses a mathematical challenge, and people circumvent 10:30.371 --> 10:31.661 it in many ways. 10:31.658 --> 10:34.428 One is to say, "Let's pretend our 10:34.433 --> 10:37.213 universe is large and finite." 10:37.210 --> 10:40.130 It may even be the case because we don't know. 10:40.129 --> 10:42.969 And I'm doing quantum mechanics in which I'm fooling around in a 10:42.967 --> 10:44.767 tiny region like atoms and molecules, 10:44.769 --> 10:47.809 and it really doesn't matter if the universe even goes beyond 10:47.811 --> 10:48.421 this room. 10:48.419 --> 10:49.929 It goes beyond this room. 10:49.929 --> 10:51.029 It goes beyond the planet. 10:51.029 --> 10:52.369 It goes beyond the solar system. 10:52.370 --> 10:55.580 I grant you all that, but I say allow me to believe 10:55.577 --> 10:59.747 that if it goes sufficiently far enough it's a closed universe. 10:59.750 --> 11:03.820 So a closed universe is like this. 11:03.820 --> 11:07.690 A closed one-dimensional universe is a circle. 11:07.690 --> 11:11.000 In that universe if you throw a rock it'll come back and hit you 11:10.995 --> 11:11.725 from behind. 11:11.730 --> 11:14.530 In fact you can see the back of your head in this universe 11:14.534 --> 11:16.754 because everything goes around in a circle. 11:16.750 --> 11:21.750 All right, so that's the world you take. 11:21.750 --> 11:24.320 Now that looks kind of artificial for the real world, 11:24.320 --> 11:27.000 which we all agree seems to be miles and miles long, 11:27.000 --> 11:30.010 but I don't care for this purpose what L is as long 11:30.010 --> 11:30.910 as it's finite. 11:30.908 --> 11:33.748 If L is finite, any number you like, 11:33.750 --> 11:37.400 then the ψ of p of x will 11:37.404 --> 11:41.674 look like 1/√L e^(ipx/ℏ). 11:41.669 --> 11:43.119 Do you agree? 11:43.120 --> 11:46.240 If you take the absolute square of this you'll get a 1/L. 11:46.240 --> 11:47.420 This'll become 1. 11:47.418 --> 11:51.428 The integral of 1 of L over the length of space is just 11:51.427 --> 11:51.687 1. 11:51.690 --> 11:55.050 So that's the normalized wave function. 11:55.048 --> 11:59.248 Now this is also a very realistic thing if in practice 11:59.253 --> 12:03.223 your particle is restricted to live in a circle. 12:03.220 --> 12:05.300 Again, there are a lot of experiments being done, 12:05.298 --> 12:08.488 including at Yale, where there's a tiny metallic 12:08.486 --> 12:10.406 ring, a nano scale object, 12:10.407 --> 12:13.987 and the electrons are forced to lived in that ring. 12:13.990 --> 12:18.240 So the ring has a radius and this L is just 2ΠR 12:18.238 --> 12:20.588 where R is the radius. 12:20.590 --> 12:23.600 There L is very real. 12:23.600 --> 12:24.710 It's not something you cooked up. 12:24.710 --> 12:26.950 It's the size of the ring, but sometimes even if you're 12:26.951 --> 12:29.811 not doing particle in a ring, if you're doing particle in a 12:29.807 --> 12:32.807 line you just pretend that the line closes in on itself. 12:32.808 --> 12:36.528 That if you start at the origin and you go on the two sides it 12:36.528 --> 12:37.258 closes in. 12:37.259 --> 12:41.739 If this is x = 0 you go right and you go left they all 12:41.741 --> 12:44.881 meet at the back and it's a closed ring. 12:44.879 --> 12:50.189 So let's imagine what life looks like for a particle forced 12:50.193 --> 12:54.413 to live in a ring of circumference L. 12:54.408 --> 12:59.218 The normalized wave function looks like this of momentum 12:59.217 --> 13:00.177 p. 13:00.178 --> 13:06.268 This is 1/√L e^(ipx/ℏ). 13:06.269 --> 13:11.109 The probability to find this guy at some point x which 13:11.105 --> 13:15.615 is the absolute value of ψ^(2) is just 1/L. 13:15.620 --> 13:18.220 That means the probability is constant over the entire ring. 13:18.220 --> 13:19.370 We don't know where it is. 13:19.370 --> 13:22.360 You can find it anywhere with equal probability. 13:22.360 --> 13:26.960 It's always true that if you know the momentum you don't know 13:26.956 --> 13:28.026 where it is. 13:28.028 --> 13:35.198 Now let's ask one other question. 13:35.200 --> 13:39.540 Here is the circle in which I'm living. 13:39.538 --> 13:42.038 If you look at the real part and imaginary part with their 13:42.042 --> 13:43.932 sines and cosines they kind of oscillate. 13:43.929 --> 13:44.909 Do you understand that? 13:44.908 --> 13:46.918 When the x varies they oscillate. 13:46.918 --> 13:50.768 And one requirement you make that if you go all the way 13:50.774 --> 13:54.634 around and come back it's got to close in on itself. 13:54.629 --> 13:58.659 Because if you increase x from anywhere by an 13:58.658 --> 14:01.328 amount L, which is going all the way 14:01.330 --> 14:03.350 around the circle, you've got to come back to 14:03.354 --> 14:04.094 where you start. 14:04.090 --> 14:07.570 The function has to come back where you started meaning it's a 14:07.565 --> 14:08.985 single valued function. 14:08.990 --> 14:11.500 If you say what's ψ here you've got to get one 14:11.499 --> 14:11.959 number. 14:11.960 --> 14:13.190 That means if you start at some point, 14:13.190 --> 14:15.450 you go on moving, you follow the ψ, 14:15.450 --> 14:18.100 you go all the way around and you come back you shouldn't have 14:18.104 --> 14:18.674 a mismatch. 14:18.669 --> 14:20.019 It should agree. 14:20.019 --> 14:24.669 So the only allowed functions are those obeying the condition 14:24.673 --> 14:27.623 ψ(x L) = ψ(x). 14:27.620 --> 14:29.670 You understand that? 14:29.668 --> 14:33.238 Take any point you like, follow the function for a 14:33.241 --> 14:34.701 distance L. 14:34.700 --> 14:39.250 That means you come back and the function better come back. 14:39.250 --> 14:43.980 So a function like e to the −x^(2) is not a 14:43.976 --> 14:47.936 good function to go around a circle and come back. 14:47.940 --> 14:51.320 If you go in real space, if you go on all the way it 14:51.323 --> 14:53.783 doesn't come back to where you are. 14:53.779 --> 14:56.889 So you've got the right functions which have the 14:56.888 --> 15:00.788 property that when you add L to them you come back where you 15:00.789 --> 15:01.319 are. 15:01.320 --> 15:09.290 That's a condition of single valuedness. 15:09.288 --> 15:15.638 So that means in this function if I take it at some point 15:15.635 --> 15:21.635 e^(ipx) at some point x then I add to it 15:21.643 --> 15:25.673 L, namely I'm getting 15:25.668 --> 15:31.768 e^(ipx/ℏ) times e^(ipL/ℏ). 15:31.769 --> 15:36.059 That has to agree with the starting value which is 15:36.061 --> 15:37.901 e^(ipx/ℏ). 15:37.899 --> 15:40.469 In other words I'm comparing the wave function at the point 15:40.471 --> 15:42.071 x and the point x L. 15:42.070 --> 15:45.390 See, if your world is infinite this is x, 15:45.386 --> 15:48.136 this is x L, this is x 2L, 15:48.139 --> 15:50.469 they're all different points. 15:50.470 --> 15:54.070 What the function does here has nothing to do with what it does 15:54.073 --> 15:55.753 here, but if you wrapped out the 15:55.754 --> 15:58.474 region back into itself what it does when you go a distance 15:58.465 --> 16:00.845 L is no longer independent of what it does at 16:00.847 --> 16:01.967 the starting point. 16:01.970 --> 16:04.460 It has to be the same thing. 16:04.460 --> 16:07.130 Therefore, I'm just applying the test. 16:07.129 --> 16:10.529 I'm saying take the function at x L, factorize it this 16:10.528 --> 16:13.758 way, demand that it be equal to a function of x. 16:13.759 --> 16:22.209 These cancel and you learn then that e^(ipL/ℏ) should 16:22.210 --> 16:23.180 be 1. 16:23.179 --> 16:24.389 Now how can that be 1? 16:24.389 --> 16:29.769 Well, one way is p = 0, but I hope you know that it's 16:29.774 --> 16:31.514 not the only way. 16:31.509 --> 16:35.289 Do you know how else it can be 1 should p be 0? 16:35.288 --> 16:38.888 Student: > 16:38.889 --> 16:39.619 Prof: Pardon me? 16:39.620 --> 16:41.600 Student: > 16:41.600 --> 16:42.720 Prof: I didn't hear that, sorry. 16:42.720 --> 16:44.610 Student: It's infinite. 16:44.610 --> 16:46.240 Prof: I didn't hear that again. 16:46.240 --> 16:47.910 Student: It's infinite > 16:47.908 --> 16:49.818 Prof: You still have to say it louder. 16:49.820 --> 16:52.330 Student: If it is infinite 16:52.332 --> 16:54.392 > 16:54.389 --> 16:55.309 Prof: Any other answers? 16:55.309 --> 16:55.969 Yeah? 16:55.970 --> 16:58.380 Student: If it's a multiple of 2Π. 16:58.379 --> 17:00.279 Prof: Is that what you said multiple of 2Π? 17:00.279 --> 17:01.469 Student: Sure. 17:01.470 --> 17:02.250 Prof: Good. 17:02.250 --> 17:04.300 I'm glad you didn't say it loud enough. 17:04.299 --> 17:05.129 Okay good. 17:05.130 --> 17:08.940 It's a multiple of 2Π because any trigonometry 17:08.938 --> 17:12.158 function if you add 2Π, or 4Π, or 6Π 17:12.157 --> 17:15.267 whose argument doesn't change then you should never forget the 17:15.271 --> 17:18.181 fact that this exponential is the sum of two trigonometric 17:18.181 --> 17:22.311 functions cosine i sine, and they all come back. 17:22.308 --> 17:25.918 Therefore, it is too strong to say p should be 0. 17:25.920 --> 17:33.610 p should be such that pL/ℏ is 2Π 17:33.607 --> 17:40.087 times any integer when the integer can be 0, 17:40.089 --> 17:46.119 plus minus 1, plus minus 2 etcetera. 17:46.118 --> 17:55.128 That means p has to be equal to 2Πℏ/L times 17:55.132 --> 18:02.082 m where m is an integer, positive, 18:02.076 --> 18:04.436 negative, 0. 18:04.440 --> 18:07.090 Now this is a very big moment in your life. 18:07.089 --> 18:11.079 Why is it a big moment? 18:11.079 --> 18:12.529 Yes? 18:12.529 --> 18:13.949 You don't know? 18:13.950 --> 18:17.710 Well if you haven't done it before, this is the first time 18:17.714 --> 18:21.154 you're able to deduce the quantization of a dynamical 18:21.151 --> 18:22.011 variable. 18:22.009 --> 18:26.109 This is the first time you realize this is the quantum of 18:26.105 --> 18:27.345 quantum theory. 18:27.348 --> 18:30.158 The allowed momenta for this particle living in there, 18:30.160 --> 18:32.260 you might think it can zip around at any speed it likes, 18:32.259 --> 18:39.169 it cannot, especially in a ring of nano proportions these values 18:39.169 --> 18:42.569 of p are all discrete. 18:42.569 --> 18:43.629 p times.. 18:43.630 --> 18:47.450 2Πℏ/L times 0 is here, times 1 is here, 18:47.445 --> 18:49.725 times 2 is here, 3 is here, -1, 18:49.734 --> 18:50.274 -2. 18:50.269 --> 18:54.859 These are the only allowed values of p. 18:54.858 --> 18:57.368 So that's the case of quantization, 18:57.368 --> 19:01.288 and the quantization came from demanding that the wave function 19:01.294 --> 19:04.844 had a certain behavior that's mathematically required. 19:04.838 --> 19:08.708 The behavior in question is single valuedness. 19:08.710 --> 19:10.820 Now I can say this in another way. 19:10.818 --> 19:13.908 Let's write the same relationship in another way. 19:13.910 --> 19:16.130 So let me go here. 19:16.130 --> 19:21.400 So I had the allowed values of p are 2Πℏ/L 19:21.396 --> 19:22.886 times m. 19:22.890 --> 19:27.200 I can write it as p times L/2Π 19:27.195 --> 19:29.625 is equal to mℏ. 19:29.630 --> 19:35.120 L/2Π is the radius of the circle. 19:35.118 --> 19:39.328 So I find that p times R is equal to 19:39.327 --> 19:40.527 mℏ. 19:40.529 --> 19:43.559 You guys know what p times R is for a particle 19:43.560 --> 19:45.720 moving in a circle at momentum p? 19:45.720 --> 19:49.550 What is the momentum times the radial distance to the center? 19:49.548 --> 19:51.198 Student: Angular momentum. 19:51.200 --> 19:52.840 Prof: Angular momentum. 19:52.838 --> 19:57.168 That's usually denoted by a quantity L in quantum 19:57.173 --> 19:58.123 mechanics. 19:58.118 --> 20:03.978 So angular momentum is an integral multiple of ℏ. 20:03.980 --> 20:06.360 That's something you will find even in high school people will 20:06.356 --> 20:08.926 tell you angular momentum is an integral multiple of ℏ. 20:08.930 --> 20:11.770 Where does it come from and how does it come from quantum 20:11.770 --> 20:12.380 mechanics? 20:12.380 --> 20:17.240 Here is one simple context in which you can see the angular 20:17.238 --> 20:20.588 momentum is quantized to these values. 20:20.588 --> 20:25.748 Now what I will do quite often is to write the state ψ 20:25.750 --> 20:30.530 as ψ of p this way, e^(2Π), I'm sorry, 20:30.528 --> 20:34.718 e^(ipx/ℏ), but to remind myself that p 20:34.719 --> 20:39.929 is quantized to be integer multiples of some basic quantum 20:39.933 --> 20:43.443 where the multiple is just m, 20:43.440 --> 20:48.850 I may also write the very same function the ψ's of m 20:48.846 --> 20:52.506 is 1/√L e^(ix/ℏ), 20:52.509 --> 20:57.489 but for p you put the allowed value which is 20:57.491 --> 21:00.981 2Πℏ/L times m. 21:00.980 --> 21:02.510 And what do you get? 21:02.509 --> 21:16.779 You get 1/√L times e^(2Πimx/L). 21:16.778 --> 21:18.898 They're all oscillating exponentials, 21:18.901 --> 21:22.321 but you realize that the label p and the label m are 21:22.317 --> 21:23.317 equally good. 21:23.318 --> 21:25.938 If I tell you what m is you know what the momentum is 21:25.940 --> 21:27.850 because you just multiply by this number. 21:27.848 --> 21:32.258 So quite often I'll refer to this wave function by this label 21:32.259 --> 21:35.419 m which is as good as the label p. 21:35.420 --> 21:39.400 The nice thing about the label m is that m ranges 21:39.396 --> 21:40.676 over all integers. 21:40.680 --> 21:42.090 p is a little more complicated. 21:42.088 --> 21:45.988 p is also quantized, but the allowed values are not 21:45.992 --> 21:49.352 integers, but integers times this funny number. 21:49.348 --> 21:50.448 In the limit in which L is very, 21:50.450 --> 21:52.800 very large, compared to ℏ, 21:52.798 --> 21:55.278 the spacing between the allowed values becomes very, 21:55.279 --> 21:59.769 very close, and you may not even realize that p is 21:59.766 --> 22:02.166 taking only discrete values. 22:02.170 --> 22:04.540 So when you do a microscopic problem where L is 1 22:04.535 --> 22:06.985 meter the spacing between one allowed p and another 22:06.986 --> 22:09.476 allowed p will be so small you won't notice it. 22:09.480 --> 22:12.700 So even if you lived in a real ring of circumference 1 meter 22:12.695 --> 22:16.075 the momenta that you'll find in the particle will look like any 22:16.076 --> 22:17.436 momentum is possible. 22:17.440 --> 22:20.370 That's because the allowed values of p of so densely 22:20.365 --> 22:22.025 close, packed, that you don't know 22:22.027 --> 22:24.877 whether you've got this one, or that one or something in 22:24.878 --> 22:27.618 between because you cannot measure it that well. 22:27.618 --> 22:31.338 So it'll smoothly go into the classical world of all allowed 22:31.335 --> 22:33.975 momenta if L becomes macroscopic. 22:33.980 --> 22:36.630 And the notion of macroscopic is " how big is big". 22:36.630 --> 22:39.680 Well, it should be comparable to ℏ. 22:39.680 --> 22:47.070 I mean, it should be much bigger than ℏ then 22:47.066 --> 22:50.756 it'll become continuous. 22:50.759 --> 22:54.979 So now I'm going to ask the following question. 22:54.980 --> 22:58.780 If I have a particle in this world, 22:58.779 --> 23:03.239 in this one-dimensional ring and I plot the wave function, 23:03.240 --> 23:11.400 some function ψ(x), suppose it's not one of these 23:11.401 --> 23:12.541 functions? 23:12.539 --> 23:14.389 It's not e^(ipx/ℏ). 23:14.390 --> 23:16.690 It's some random thing I wrote here. 23:16.690 --> 23:22.050 Of course it meets itself when you go around a circle. 23:22.049 --> 23:23.489 That's a periodic function. 23:23.490 --> 23:24.920 Be very careful. 23:24.920 --> 23:27.280 A periodic function doesn't mean it oscillates with a 23:27.280 --> 23:27.690 period. 23:27.690 --> 23:30.330 In this case periodic means when I go around the loop it 23:30.327 --> 23:31.907 comes back to a starting value. 23:31.910 --> 23:35.150 It doesn't do something like this where the two don't match. 23:35.150 --> 23:36.680 That's what I mean by periodic. 23:36.680 --> 23:39.710 It doesn't mean it's a nice oscillatory function. 23:39.710 --> 23:43.220 These guys are periodic and oscillatory with the period. 23:43.220 --> 23:45.990 These are periodic only in the sense that if you go around the 23:45.994 --> 23:48.684 ring you come back to the starting value of the function. 23:48.680 --> 23:51.670 So I give you some function like this and I ask you what's 23:51.674 --> 23:52.994 going on with this guy. 23:52.990 --> 23:56.510 What can you say about the particle? 23:56.509 --> 24:01.279 So can you tell me anything now given this function 24:01.281 --> 24:03.001 ψ(x)? 24:03.000 --> 24:08.890 Does it tell you any information? 24:08.890 --> 24:12.030 You mean if I draw the function like that, you get no 24:12.030 --> 24:13.360 information from it. 24:13.359 --> 24:15.909 Is that what you're saying? 24:15.910 --> 24:17.160 You must know--yes? 24:17.160 --> 24:19.430 Student: You square it you get the probability 24:19.430 --> 24:20.680 Prof: Yes, look. 24:20.680 --> 24:23.430 If you knew that you've got to say that because if I think that 24:23.430 --> 24:26.270 you didn't realize that I know we are both in serious trouble. 24:26.269 --> 24:27.529 That's correct. 24:27.528 --> 24:29.828 I want to reinforce the notion over and over again. 24:29.828 --> 24:31.868 Wave functions should tell you something. 24:31.868 --> 24:34.098 Square it you get the probability. 24:34.098 --> 24:36.008 If you don't square it don't think it's the probability 24:36.006 --> 24:37.026 because it can be negative. 24:37.029 --> 24:38.689 It can even be complex. 24:38.690 --> 24:41.400 So don't forget if you square it you get the probability. 24:41.400 --> 24:43.560 Define a certain position. 24:43.558 --> 24:45.478 That means if you went around with this little 24:45.477 --> 24:48.077 Heisenberg microscope all over the ring and you catch 24:48.077 --> 24:49.577 it and you say, "Good, I found it 24:49.577 --> 24:50.607 here," and you do that many, 24:50.609 --> 24:51.979 many times. 24:51.980 --> 24:55.330 By many, many times I mean you take a million particles in a 24:55.328 --> 24:58.508 million rings each in exactly this quantum state and make 24:58.508 --> 25:01.318 measurements, then your histogram will look 25:01.319 --> 25:03.419 like the square of this function. 25:03.420 --> 25:05.160 But there is more to life than just saying, 25:05.160 --> 25:07.160 "Where is the particle?," 25:07.157 --> 25:09.917 because in classical mechanics you also ask, 25:09.920 --> 25:12.080 "What is its momentum." 25:12.078 --> 25:16.428 The question I'm asking you is, "What is the momentum you 25:16.432 --> 25:20.642 will get when you measure the momentum of a particle in this 25:20.644 --> 25:21.934 quantum state? 25:21.930 --> 25:24.960 You know the answer only on a few special cases. 25:24.960 --> 25:27.970 If by luck your function happened to look like one of 25:27.973 --> 25:31.103 these functions--right now I've not told you what ψ 25:31.104 --> 25:31.514 is. 25:31.509 --> 25:33.999 It's whatever you like, but if it looked like one of 25:34.000 --> 25:36.640 these you're in good shape because then the momentum is 25:36.635 --> 25:38.585 whatever p you find up here, 25:38.589 --> 25:40.049 but it may not look like that. 25:40.049 --> 25:42.729 This guy doesn't look like that. 25:42.730 --> 25:47.050 So then the question is if you measure momentum what answer 25:47.051 --> 25:48.171 will you get. 25:48.170 --> 25:54.720 Now that is something--anybody know what the answer is? 25:54.720 --> 25:58.230 Now I accept your silence because you're not supposed to 25:58.232 --> 25:59.002 know this. 25:59.000 --> 26:02.430 This is a postulate in quantum mechanics. 26:02.430 --> 26:03.100 It's not logic. 26:03.099 --> 26:04.219 It's not mathematics. 26:04.220 --> 26:07.720 No one could have told you 300 years ago this is the right 26:07.717 --> 26:08.267 answer. 26:08.269 --> 26:10.649 So this is another postulate just like saying, 26:10.652 --> 26:13.142 ψ^(2) is probability defined at x. 26:13.140 --> 26:15.150 There is a new postulate. 26:15.150 --> 26:17.220 It addresses the following question. 26:17.220 --> 26:19.820 If I shift my attention from position, 26:19.818 --> 26:23.068 to momentum, and I ask, "What are the 26:23.074 --> 26:27.524 odds for getting different answers for momentum?" 26:27.519 --> 26:30.089 That answer's actually contained in the same function 26:30.093 --> 26:32.323 ψ of x in the following fashion. 26:32.318 --> 26:38.058 Take this function ψ(x) and write it as a sum over 26:38.061 --> 26:43.571 p of these functions, ψ_p of x 26:43.567 --> 26:47.417 with some coefficient A_p. 26:47.420 --> 26:50.960 I can also write it equally well as the same function 26:50.957 --> 26:55.037 labeled by integer m and I want to call the coefficient m. 26:55.038 --> 26:59.168 They're exactly the same thing, p and m are 26:59.171 --> 27:00.131 synonymous. 27:00.130 --> 27:01.190 The same function. 27:01.190 --> 27:06.430 This function is called ψ_m because they 27:06.425 --> 27:11.065 contain the same information on the momentum. 27:11.068 --> 27:14.288 So either you can write it this way if you want to see the 27:14.291 --> 27:17.561 momentum highlighted, or you can write the function 27:17.557 --> 27:21.697 this way if you want to see the quantum number m highlighted, 27:21.700 --> 27:24.050 but they stand for the same physics. 27:24.048 --> 27:27.928 If m is equal to 4 it means the cosine and the sine contained in 27:27.932 --> 27:31.882 the complex exponential finish 4 complete oscillations as they go 27:31.875 --> 27:33.165 around the cycle. 27:33.170 --> 27:36.010 All right, so here's what you're told. 27:36.009 --> 27:39.109 Take the arbitrary periodic function. 27:39.108 --> 27:43.028 Write it as a sum of these functions, each of definite 27:43.032 --> 27:45.552 momentum, with some coefficient. 27:45.548 --> 27:49.018 Then the probability that you will get a momentum p 27:49.019 --> 27:51.479 when you measure it, which is the same as the 27:51.483 --> 27:53.883 probability you will get the corresponding m, 27:53.880 --> 28:07.980 is nothing but the absolute square of this coefficient. 28:07.980 --> 28:12.790 In other words, anyway, this is a postulate. 28:12.789 --> 28:14.669 Let me repeat the postulate. 28:14.670 --> 28:16.170 Somebody gives you a function. 28:16.170 --> 28:20.010 You write the function as a sum of all these periodic functions, 28:20.009 --> 28:23.749 each with the index m, multiply each with a suitable 28:23.751 --> 28:27.431 number so that they add up to give you the function that's 28:27.429 --> 28:28.719 provided to you. 28:28.720 --> 28:32.880 Once you've done that the coefficient squared with the 28:32.880 --> 28:37.670 particular value m is the probability you will get that 28:37.669 --> 28:41.279 value for m or the corresponding momentum. 28:41.279 --> 28:43.929 So there are two questions one can ask at this point. 28:43.930 --> 28:47.800 First question is what makes you think that you can write any 28:47.797 --> 28:51.017 function I give you as a sum of these functions. 28:51.019 --> 28:52.059 Realize what this means. 28:52.058 --> 28:55.848 I'm saying I can write any function as 28:55.847 --> 29:01.887 e^(2Πimx/L)√L times A_m. 29:01.890 --> 29:05.850 I'm writing out this function explicitly for you. 29:05.848 --> 29:09.268 Now that is a mathematical result I will not prove here, 29:09.269 --> 29:13.109 it's called Fourier series and it tells you that every periodic 29:13.106 --> 29:15.296 function, namely that which comes back to 29:15.299 --> 29:17.779 itself when you go around a period length L, 29:17.778 --> 29:21.378 can be written as a sum of these periodic functions with 29:21.380 --> 29:23.410 suitably chosen coefficients. 29:23.410 --> 29:31.420 It can always be done. 29:31.420 --> 29:34.800 That is analogous to the statement that if you are say 29:34.798 --> 29:38.048 living in three dimensions and there is a vector 29:38.048 --> 29:41.468 V, and you pick for yourself three 29:41.467 --> 29:44.967 orthonormal vectors, 29:44.970 --> 29:48.320 i, j and k, then any vector 29:48.317 --> 29:52.017 V can be written as V_x times 29:52.022 --> 29:55.162 i V_y times j 29:55.156 --> 29:58.146 V_z times k. 29:58.150 --> 30:00.070 In other words, I challenge you to write any 30:00.074 --> 30:02.454 arrow in three dimensions starting from the origin and 30:02.446 --> 30:04.726 pointing in any direction of any finite length. 30:04.730 --> 30:07.710 I'll build it up for you using some multiple of i, 30:07.708 --> 30:09.888 some of j, and some of k. 30:09.890 --> 30:11.270 We know that can be done in fact. 30:11.269 --> 30:12.899 That's if you want the technical definition of 30:12.904 --> 30:13.564 three-dimension. 30:13.559 --> 30:14.269 Yes? 30:14.269 --> 30:18.639 Student: With the Fourier case would there be one 30:18.643 --> 30:21.223 unique way of writing ________? 30:21.220 --> 30:21.740 Prof: Good point. 30:21.740 --> 30:22.320 That's correct. 30:22.319 --> 30:23.029 There will be a unique way. 30:23.029 --> 30:23.669 Student: There is? 30:23.670 --> 30:24.550 Prof: There is. 30:24.548 --> 30:28.848 You agree in three dimensions there is no other mixture except 30:28.845 --> 30:29.615 this one. 30:29.618 --> 30:33.058 If somebody comes with the second way of writing it you can 30:33.059 --> 30:36.619 show that the second way will coincide with the first way. 30:36.618 --> 30:40.038 So the expansion of a function, in what are called these 30:40.038 --> 30:43.578 trigonometric or exponential functions and it's called the 30:43.582 --> 30:46.932 Fourier series of the function, has unique coefficients. 30:46.930 --> 30:49.300 And I'll tell you right now what the formula for the 30:49.295 --> 30:51.645 coefficient is, but first I'm telling you that 30:51.646 --> 30:54.676 just like it's natural to build a vector out of some building 30:54.682 --> 30:56.442 blocks i, j and 30:56.438 --> 31:00.008 k, it's natural to build up periodic functions with these 31:00.012 --> 31:02.342 building blocks the ψ_m. 31:02.338 --> 31:05.548 The only difference is there you need only three guys. 31:05.548 --> 31:08.808 Here you need an infinite number of them because a range 31:08.814 --> 31:12.024 of m goes from minus to plus infinity, all integers. 31:12.019 --> 31:14.949 But it's still remarkable that given all of them you can build 31:14.949 --> 31:17.669 any function you like, including this thing I just 31:17.671 --> 31:21.141 wrote down arbitrarily, can be built. 31:21.140 --> 31:23.090 The fact that you can prove it, that you can do it, 31:23.088 --> 31:25.238 I don't want to prove because it's kind of tricky, 31:25.240 --> 31:30.060 but I will prove the second part of it which is given that 31:30.063 --> 31:35.313 such an expansion exists how do I find these coefficients given 31:35.309 --> 31:36.579 a function? 31:36.578 --> 31:42.138 So let's ask a similar question in the usual case of vectors. 31:42.140 --> 31:45.320 How do I find the coefficients? 31:45.318 --> 31:48.388 Suppose I write the vector V as e_1 31:48.390 --> 31:51.190 times V_1 e_2 times 31:51.194 --> 31:53.634 V_2 e_3 times 31:53.630 --> 31:55.060 V_3. 31:55.058 --> 31:55.858 Don't worry e_1, 31:55.858 --> 31:57.158 e_2 and e_3 are the 31:57.160 --> 31:58.770 usual guys, e_1 is 31:58.773 --> 32:01.153 i, e_2 is j and 32:01.148 --> 32:03.048 e_3 is k. 32:03.048 --> 32:08.728 People like to do that because in mathematics you may want to 32:08.730 --> 32:12.310 go to 96 dimensions, but we've only got 26 letters, 32:12.305 --> 32:14.495 so if you stuck to i, j and k you're 32:14.501 --> 32:17.111 going to have trouble, but with numbers you never run 32:17.106 --> 32:18.126 out of numbers. 32:18.130 --> 32:21.350 So you label all the dimensions by some number, 32:21.345 --> 32:24.625 which in this case happens to go from 1 to 3. 32:24.630 --> 32:27.210 You also know that these vectors i and j 32:27.205 --> 32:28.995 have some very interesting properties, 32:29.003 --> 32:30.903 i⋅i is 1. 32:30.900 --> 32:33.010 That's the same as j⋅j. 32:33.009 --> 32:35.019 That's the same as k⋅k. 32:35.019 --> 32:37.319 And that i⋅k 32:37.323 --> 32:39.323 and i⋅j 32:39.315 --> 32:40.555 are 0 and so on. 32:40.558 --> 32:44.198 Namely the dot product of one guy with himself is 1, 32:44.198 --> 32:46.908 and any one with anything else is 0. 32:46.910 --> 32:49.670 That just tells you they all have unit length and they're 32:49.674 --> 32:50.914 mutually perpendicular. 32:50.910 --> 32:53.370 I want to write this as e_i 32:53.372 --> 32:55.772 ⋅ e_j, 32:55.771 --> 32:57.731 but this could be 1,2 or 3. 32:57.730 --> 32:59.080 That could be 1,2 or 3. 32:59.078 --> 33:02.278 I want to say this is equal to 1 if i is equal to 33:02.278 --> 33:02.918 j. 33:02.920 --> 33:07.050 This is equal to 0 if i is not equal to 33:07.046 --> 33:07.916 j. 33:07.920 --> 33:09.900 This is a usual vector analysis. 33:09.900 --> 33:13.210 I'm just saying the dot product of basis vectors has this 33:13.210 --> 33:14.970 property, 1 if they match, 33:14.972 --> 33:18.372 2 if they're different, so there's a shortcut for this 33:18.374 --> 33:21.594 and that's write the symbol δ_ij. 33:21.592 --> 33:24.932 δ_ij is called Kronecker's 33:24.925 --> 33:25.565 delta. 33:25.568 --> 33:30.828 Kronecker's in a lot of things, but this is one place where his 33:30.828 --> 33:33.288 name has been immortalized. 33:33.288 --> 33:35.768 He just said instead of saying this all the time, 33:35.769 --> 33:37.379 1 if they're equal, 0 if they're different, 33:37.380 --> 33:40.290 why don't you call it my symbol, the Kronecker's symbol, 33:40.290 --> 33:41.880 δ_ij. 33:41.880 --> 33:44.800 It's understood that this whole thing simply says 33:44.798 --> 33:46.498 δ_ij. 33:46.501 --> 33:47.781 This is shorthand. 33:47.779 --> 33:50.499 That means if on the left hand side there are two guys with 33:50.499 --> 33:53.449 indices i and j if the indices are equal the right 33:53.452 --> 33:56.162 hand side is 1, indices are unequal right hand 33:56.160 --> 33:56.810 side is 0. 33:56.808 --> 34:00.428 Do you understand that this gives you the fact that each 34:00.425 --> 34:04.235 vector is of length 1 and that each is perpendicular to the 34:04.239 --> 34:05.159 other two. 34:05.160 --> 34:09.400 Now that is what we can use now to find out. 34:09.400 --> 34:12.780 So let me write the vector V in this notation as 34:12.782 --> 34:16.352 e_i times V_ii from 1 to 34:16.353 --> 34:16.733 3. 34:16.730 --> 34:21.050 You're all familiar with this way to write the sum? 34:21.050 --> 34:23.410 So I come with a certain vector. 34:23.409 --> 34:25.029 The vector is not defined in any axis. 34:25.030 --> 34:27.650 It's just an arrow pointing in some direction. 34:27.650 --> 34:29.460 It's got a magnitude and direction. 34:29.460 --> 34:31.840 And I say, "Can you write the vector in terms of i, 34:31.844 --> 34:33.004 j and k?" 34:33.000 --> 34:34.940 And the answer is, "Yes, of course I 34:34.938 --> 34:35.518 can." 34:35.519 --> 34:37.609 So here's your vector V. 34:37.610 --> 34:39.480 Here is, if you like, e_1, 34:39.476 --> 34:41.606 e_2 and e_3. 34:41.610 --> 34:42.960 The claim is some mixture of e_1, 34:42.960 --> 34:44.340 e_2, e_3 will add 34:44.338 --> 34:44.998 up to this V. 34:45.000 --> 34:47.070 That's granted, but how much? 34:47.070 --> 34:48.110 How much e_1 do I need? 34:48.110 --> 34:49.600 How much e_2 do I need? 34:49.599 --> 34:52.429 There's a very simple trick for that. 34:52.429 --> 34:54.719 Anybody know what that trick is? 34:54.719 --> 34:59.159 You might know that trick. 34:59.159 --> 35:03.549 You've seen it anywhere? 35:03.550 --> 35:05.180 Here is the trick. 35:05.179 --> 35:08.889 Suppose you want to find V_2? 35:08.889 --> 35:11.499 You take the dot product of both these things with 35:11.503 --> 35:12.733 e_2. 35:12.730 --> 35:17.180 Take e_2 dot this, and take dot product with 35:17.175 --> 35:18.875 e_2. 35:18.880 --> 35:22.910 What happens is you will get--the dot product can go 35:22.909 --> 35:23.619 inside. 35:23.619 --> 35:25.879 You'll get e_i ⋅ 35:25.875 --> 35:28.535 e_2 times V_i where 35:28.541 --> 35:30.081 i goes from 1 to 3. 35:30.079 --> 35:31.599 What is e_i ⋅ 35:31.603 --> 35:32.463 e_2? 35:32.460 --> 35:32.960 e_i ⋅ 35:32.956 --> 35:33.766 e_2 is δ_i2. 35:33.768 --> 35:39.908 That means if this index size is equal to 2 you get 1. 35:39.909 --> 35:41.719 If not equal to 0 you strike out. 35:41.719 --> 35:43.389 You get 0. 35:43.389 --> 35:46.509 So of all the three terms in this only one will survive. 35:46.510 --> 35:49.530 That's the one when i is equal to 2 in which case you 35:49.525 --> 35:50.185 will get 1. 35:50.190 --> 35:53.930 That's multiplying V_2 so it'll 35:53.925 --> 35:56.465 give you V_2. 35:56.469 --> 36:00.609 So to find the component number 3 you take the dot product of 36:00.606 --> 36:03.776 the given vector with e_3, 36:03.780 --> 36:05.590 and that will give you, you can see, 36:05.590 --> 36:07.870 that will give you V_3 or 36:07.865 --> 36:10.305 V_2 or whatever you like. 36:10.309 --> 36:15.429 I'm going to use a similar trick now in our problem. 36:15.429 --> 36:17.669 The trick I'm going to use is the following. 36:17.670 --> 36:23.100 So the analogy is just like you had V = sum over i 36:23.096 --> 36:27.486 e_i times V_i, 36:27.489 --> 36:30.349 I have ψ of x is equal to sum 36:30.346 --> 36:34.076 over m of some A_m times the 36:34.079 --> 36:37.229 function ψ_m of x. 36:37.230 --> 36:37.860 You understand that? 36:37.860 --> 36:39.940 ψ_m is a particular function which I 36:39.938 --> 36:44.848 don't want to write every time, but if you insist it is 36:44.846 --> 36:51.776 2Πimx/L divided by √L. 36:51.780 --> 36:54.620 So I'm trying to find this guy. 36:54.619 --> 36:55.539 How much is it? 36:55.539 --> 36:57.279 That's the question. 36:57.280 --> 36:59.610 Now here we had a nice rule. 36:59.610 --> 37:01.960 The rule says e_i ⋅ 37:01.960 --> 37:04.660 e_j is δ_ij. 37:04.659 --> 37:07.989 That was helpful in finding the coefficients. 37:07.989 --> 37:11.219 There's a similar rule on the right hand side which I will 37:11.224 --> 37:13.784 show you and we can all verify it together. 37:13.780 --> 37:18.870 The claim is ψ_m*(x) 37:18.869 --> 37:23.819 times ψ_n(x) dx 37:23.818 --> 37:32.158 from 0 to L is in fact δ_mn. 37:32.159 --> 37:36.409 So the basis vectors ψ_m are like 37:36.405 --> 37:38.525 e_i. 37:38.530 --> 37:40.250 The dot product of two basis vectors being 37:40.248 --> 37:42.258 δ_ij is the same here, 37:42.260 --> 37:46.110 like same integral, but one of them star times the 37:46.114 --> 37:50.914 other one is 1 if it's the same function and 0 if it's not the 37:50.913 --> 37:52.333 same function. 37:52.329 --> 37:54.599 Let's see if this is true. 37:54.599 --> 37:57.439 If m is equal to n, can you do this in 37:57.440 --> 37:58.110 your head? 37:58.110 --> 38:02.260 If m is equal to n what do we have? 38:02.260 --> 38:05.740 This number times this conjugate is just 1. 38:05.739 --> 38:07.629 You just get 1/L. 38:07.630 --> 38:11.130 An integral of 1/L dx, so if you want I will write it 38:11.125 --> 38:16.855 here, it's 2Πi times 38:16.864 --> 38:28.054 n −mx/L dx from 0 to L. 38:28.050 --> 38:29.390 Do you understand that? 38:29.389 --> 38:31.529 You take the conjugate of the first function. 38:31.530 --> 38:34.860 That where's it's a -m here, and take the second function 38:34.864 --> 38:37.134 which is e^(2Πin)^(/L) 38:37.128 --> 38:38.258 times x. 38:38.260 --> 38:42.030 I'll wait until you have time to digest that. 38:42.030 --> 38:44.120 The product of ψ_m* with 38:44.123 --> 38:47.183 ψ_n you combine the two exponentials, 38:47.179 --> 38:50.459 but the thing that had m in it has a -m here 38:50.458 --> 38:52.528 because you conjugated everything. 38:52.530 --> 38:54.330 So I'm saying, "What is the integral 38:54.329 --> 38:55.229 going to be?" 38:55.230 --> 38:58.290 If n is equal to m you can see that in 38:58.289 --> 38:59.009 your head. 38:59.010 --> 39:01.410 This is e^(0). 39:01.409 --> 39:02.949 That is just 1. 39:02.949 --> 39:04.299 The integral of dx is L. 39:04.300 --> 39:05.380 That cancels the L. 39:05.380 --> 39:08.820 You get 1. 39:08.820 --> 39:11.320 That's certainly true if m is equal to n. 39:11.320 --> 39:15.740 If m is not equal to n, suppose it is 6? 39:15.739 --> 39:17.599 It doesn't matter. 39:17.599 --> 39:21.439 This will complete 6 full oscillations in the period, 39:21.440 --> 39:24.810 the sine and the cosine, but whenever you integrate a 39:24.809 --> 39:28.439 sine or a cosine over some number of full periods you get 39:28.440 --> 39:28.830 0. 39:28.829 --> 39:32.849 So this exponential, when integrated over a full 39:32.853 --> 39:37.913 cycle, if it's got a non-zero exponent integer exponent will 39:37.905 --> 39:39.185 give you 0. 39:39.190 --> 39:43.300 So you see the remarkable similarity between usual vector 39:43.302 --> 39:45.582 analysis and these functions. 39:45.579 --> 39:47.049 This is an arbitrary vector. 39:47.050 --> 39:49.370 This is an arbitrary function. 39:49.369 --> 39:50.899 e_1, e_2, 39:50.898 --> 39:52.388 e_3 are basis vectors; 39:52.389 --> 39:55.359 ψ_m are if you want basis function. 39:55.360 --> 39:58.220 I can build any vector out of these unit vectors. 39:58.219 --> 40:01.439 I can build any function out of these basis functions. 40:01.440 --> 40:04.560 And finally, if I want to find out a 40:04.557 --> 40:07.407 coefficient, what should I do? 40:07.409 --> 40:08.569 You want to find the coefficient 40:08.574 --> 40:09.444 A_n. 40:09.440 --> 40:14.330 What did I do here to find V_j? 40:14.329 --> 40:17.719 You take V⋅ e_j where 40:17.717 --> 40:20.557 j could be whatever number you picked. 40:20.559 --> 40:23.169 Because if you take the dot product of the two sides when 40:23.168 --> 40:25.588 you take dot product of e_j the only 40:25.590 --> 40:27.360 term who survives is i = j. 40:27.360 --> 40:28.680 That'll give you the V_j. 40:28.679 --> 40:32.199 So similarly here I claim the following is true. 40:32.199 --> 40:37.769 If you do the integral of ψ_n* x 40:37.766 --> 40:43.756 times the given function dx from 0 to L you 40:43.760 --> 40:47.400 will get A_n. 40:47.400 --> 40:48.530 So once I show this I'm done. 40:48.530 --> 40:51.410 Now if you don't have the stomach for this proof you don't 40:51.405 --> 40:52.915 have to remember this proof. 40:52.920 --> 40:53.810 That's up to you. 40:53.809 --> 40:56.719 See, I don't know how much you guys want to know. 40:56.719 --> 40:59.519 I'm trying to keep the stuff I just tell you without proof to a 40:59.518 --> 40:59.968 minimum. 40:59.969 --> 41:03.059 I felt bad telling you that every function can be expanded 41:03.059 --> 41:04.849 this way, but the coefficients being 41:04.851 --> 41:06.741 given by the formula is not too far away, 41:06.739 --> 41:09.439 so I want to show you how it's done. 41:09.440 --> 41:12.640 You may not know the details why this is working, 41:12.639 --> 41:15.469 but you should certainly know that if you want coefficient 41:15.474 --> 41:18.464 number 13 you've got to take ψ_13* and multiply 41:18.460 --> 41:20.550 with the given function and integrate. 41:20.550 --> 41:24.160 That you're supposed to know, so why does this work? 41:24.159 --> 41:26.189 So let's see what this does. 41:26.190 --> 41:30.410 We are trying to take ψ_n*(x). 41:30.409 --> 41:35.719 The given function looks like a sum A_m 41:35.724 --> 41:41.884 ψ_m(x) dx 0 to L summed over 41:41.875 --> 41:43.225 m. 41:43.230 --> 41:47.740 So this summation you see you can bring the ψ 41:47.742 --> 41:49.812 in here if you like. 41:49.809 --> 41:52.529 It doesn't matter. 41:52.530 --> 41:56.570 Then do the integral over x then you will find this 41:56.572 --> 41:59.482 is giving me--maybe I'll write it here. 41:59.480 --> 42:03.510 That is going to be equal to sum over m 42:03.514 --> 42:07.374 A_m of ψ_m of 42:07.371 --> 42:12.221 ψ_n* x ψ_m(x) 42:12.215 --> 42:14.965 dx, and that is going to be 42:14.974 --> 42:16.534 δ_mn. 42:16.530 --> 42:19.740 That means I will vanish unless m equals n, 42:19.737 --> 42:22.827 and when m equals n I will give you 1. 42:22.829 --> 42:25.699 That means the only term that survives from all these terms is 42:25.697 --> 42:27.717 the one where m matches n, 42:27.719 --> 42:39.639 so the thing that comes out is A_n. 42:39.639 --> 42:45.339 Once again, you will see this in my notes, but do you have any 42:45.338 --> 42:49.448 idea of what I did or where this is going? 42:49.449 --> 42:53.189 In quantum theory if you want to know what'll happen if I 42:53.186 --> 42:57.116 measure momentum for a particle living in a ring you have to 42:57.123 --> 43:01.063 write the given function in terms of these special functions 43:01.061 --> 43:04.601 each item defined as a definite momentum with suitable 43:04.597 --> 43:05.997 coefficients. 43:06.000 --> 43:10.230 The rule for finding coefficient A_n 43:10.233 --> 43:14.063 is to do this integral of ψ_n*. 43:14.059 --> 43:15.839 This one, this is the rule. 43:15.840 --> 43:18.700 A_n is the integral of 43:18.699 --> 43:21.409 ψ_n*ψ dx. 43:21.409 --> 43:25.299 And once you found the coefficients for all possible 43:25.297 --> 43:29.467 n then the probability that you will have some momentum 43:29.474 --> 43:34.014 corresponding to m is just A_m^(2). 43:34.010 --> 43:35.090 That is a recipe. 43:35.090 --> 43:38.520 What the recipe tells you is if your function is made up as a 43:38.518 --> 43:42.118 special function with a definite momentum of course you will get 43:42.117 --> 43:45.087 that momentum as the answer when you measure it. 43:45.090 --> 43:49.350 If your function is a sum over many different momentum 43:49.353 --> 43:54.183 functions then you can get any of the answers in the sum, 43:54.179 --> 43:57.139 but if it had a big coefficient in the expansion is more likely 43:57.135 --> 43:58.085 to be that answer. 43:58.090 --> 44:00.460 If it had a small coefficient it's less likely. 44:00.460 --> 44:05.300 If it had no coefficient you won't get that momentum at all. 44:05.300 --> 44:08.300 That's like saying if you had ψ(x) it's likely 44:08.298 --> 44:10.658 where it's big, unlikely where it's small and 44:10.655 --> 44:12.205 impossible where it is 0. 44:12.210 --> 44:13.280 So that's your job. 44:13.280 --> 44:15.830 Anytime someone gives you a function you have to find these 44:15.827 --> 44:17.667 coefficients A_n then look 44:17.672 --> 44:18.202 at them. 44:18.199 --> 44:20.339 They'll tell you what the answer is. 44:20.340 --> 44:21.580 So that's what I'm going to do now. 44:21.579 --> 44:26.249 I'm going to take some trial functions and go through this 44:26.248 --> 44:30.838 machinery of finding the coefficients and reading off the 44:30.835 --> 44:31.815 answers. 44:31.820 --> 44:37.060 So maybe if I do an example you'll see where this is going. 44:37.059 --> 44:41.539 So let's take an example where I'm going to pick first of all a 44:41.536 --> 44:45.866 very benign function then maybe a more difficult function. 44:45.869 --> 44:51.459 The function I want to pick is this. 44:51.460 --> 44:56.870 Some number n cosine 6Πx/L, 44:56.873 --> 45:01.283 somebody gives you that function. 45:01.280 --> 45:04.390 That is not a state of definite momentum because it is not 45:04.394 --> 45:06.914 e to the i something x. 45:06.909 --> 45:09.469 So we already know when you measure momentum you won't get a 45:09.465 --> 45:10.155 unique answer. 45:10.159 --> 45:12.929 You'll get many answers, but what are the many answers? 45:12.929 --> 45:18.009 What are the many odds is what we're asking. 45:18.010 --> 45:21.740 I forgot to mention one thing in my postulate. 45:21.739 --> 45:25.949 What I forgot to mention is that for all this to be true it 45:25.954 --> 45:29.974 is important that the functions, the momentum functions, 45:29.974 --> 45:33.054 are all normalized and the given function is also 45:33.052 --> 45:33.952 normalized. 45:33.949 --> 45:37.049 You should first normalize your function then expand it in terms 45:37.045 --> 45:39.645 of these normalized functions of definite momentum. 45:39.650 --> 45:42.710 Only then the squares of the coefficient are the absolute 45:42.706 --> 45:43.576 probabilities. 45:43.579 --> 45:46.799 By that I mean if you do this calculation, 45:46.800 --> 45:50.810 and you then went and added all these A_m_ 45:50.809 --> 45:55.369 squares, you will find amazingly it adds 45:55.365 --> 45:56.365 up to 1. 45:56.369 --> 46:00.289 Because you can show mathematically that if 46:00.289 --> 46:05.889 ψ*ψ dx is 1 then the coefficients of expansion 46:05.889 --> 46:08.409 squared will also be 1. 46:08.409 --> 46:11.519 So if you took a normalized ψ then the probabilities you 46:11.523 --> 46:14.853 get are absolute probabilities because they will add up to 1. 46:14.849 --> 46:21.809 There's also a mathematical result which I am not showing. 46:21.809 --> 46:23.859 All right, so let's go to this problem. 46:23.860 --> 46:28.140 So the first job is, normalize your ψ. 46:28.139 --> 46:30.959 So how to normalize this function I'm going to demand 46:30.960 --> 46:33.620 that if you square ψ and you integrate it, 46:33.619 --> 46:40.969 so I say N^(2) times integral of cosine square as 46:40.969 --> 46:47.919 6Πx/L dx from 0 to L should be 1. 46:47.920 --> 46:51.380 Now you don't have to look up the table of integrals because 46:51.376 --> 46:54.656 when you take a cosine squared or a sine squared over any 46:54.655 --> 46:57.815 number of full cycles the average value is a half. 46:57.820 --> 47:02.820 That means over the length L this integral will be 47:02.818 --> 47:03.978 L/2. 47:03.980 --> 47:08.700 So you want N^(2)L/2 to be 1 or you want n to be square 47:08.702 --> 47:10.332 root of 2/L. 47:10.329 --> 47:18.469 So the normalized function looks like square root of 47:18.472 --> 47:24.222 2/L cosine 6Πx/L. 47:24.219 --> 47:27.079 So that's the first job. 47:27.079 --> 47:30.699 Second is you can ask now what are the coefficients 47:30.702 --> 47:32.372 A_n. 47:32.369 --> 47:38.109 So A_n is going to be integral 47:38.108 --> 47:43.848 1/√L e^(-2Πinx/L) 47:43.847 --> 47:51.707 times this function square root of 2/L cosine 6Πx/L 47:51.708 --> 47:53.328 dx. 47:53.329 --> 47:53.959 Are you with me? 47:53.960 --> 47:55.060 That's the rule. 47:55.059 --> 47:56.819 Take the function, multiply it by 47:56.820 --> 48:00.260 ψ_n*, which is this guy here, 48:00.255 --> 48:04.545 this is the ψ_n*, this is the ψ 48:04.547 --> 48:07.227 that's given to you, and you're integrating the 48:07.233 --> 48:08.453 product in the integral. 48:08.449 --> 48:10.309 That'll give you A_n. 48:10.309 --> 48:13.709 But I claim, yeah, if you want you can do 48:13.710 --> 48:17.450 this integrals, but I think there's a quicker 48:17.454 --> 48:19.074 way to do that. 48:19.070 --> 48:23.200 Have any idea of what the quicker way just by looking at 48:23.204 --> 48:23.584 it? 48:23.579 --> 48:25.929 In other words, if you can guess the expansion 48:25.925 --> 48:27.275 I'll say I will take it. 48:27.280 --> 48:35.700 Can you guess what the answer looks like without doing the 48:35.695 --> 48:36.725 work? 48:36.730 --> 48:41.500 In other words I want you to write this function as a sum 48:41.501 --> 48:45.081 over exponentials just by looking at it. 48:45.079 --> 48:49.039 Can you tell me what it is? 48:49.039 --> 48:54.019 I want you to write it in the form sum over m 48:54.018 --> 48:57.728 A_m e^(2Πimx/L). 48:57.730 --> 49:01.990 You can find the A_m by doing 49:01.987 --> 49:06.717 all this nasty work, but I'm saying in this problem 49:06.717 --> 49:09.647 there's a much quicker way. 49:09.650 --> 49:14.200 You see it anywhere? 49:14.199 --> 49:17.959 What's the relation between trigonometric functions and 49:17.958 --> 49:19.628 exponential functions? 49:19.630 --> 49:20.260 Yep? 49:20.260 --> 49:21.980 Student: Euler's formula? 49:21.980 --> 49:22.880 Prof: And what does it say? 49:22.880 --> 49:27.680 Student: e^(ix) = cosine x i sine 49:27.675 --> 49:28.535 x. 49:28.539 --> 49:31.349 Prof: Yes, but now I want to go the other 49:31.351 --> 49:31.711 way. 49:31.710 --> 49:34.140 It is certainly true that cosine θ, 49:34.139 --> 49:37.989 I'm sorry, e^(iθ) is cosine θ 49:37.985 --> 49:39.945 I sine θ. 49:39.949 --> 49:44.049 I told you, you forget the formula at your own peril. 49:44.050 --> 49:48.900 The conjugate of that is e^(-iθ) is cosine 49:48.896 --> 49:51.856 θ -i sine θ. 49:51.860 --> 49:56.140 If you add these two you'll find cosine θ 49:56.143 --> 50:00.243 is (e^(iθ) e^(-iθ))/2, 50:00.239 --> 50:04.969 and if you subtract them and divide by 2i you'll find 50:04.965 --> 50:08.805 sine θ is e to the minus over 2i. 50:08.809 --> 50:12.919 I wanted you to be familiar with complex numbers enough so 50:12.920 --> 50:17.100 that when you see a cosine the two exponentials jump out at 50:17.103 --> 50:17.683 you. 50:17.679 --> 50:20.399 Otherwise you will be doing all these hard integrals that you 50:20.398 --> 50:21.258 don't have to do. 50:21.260 --> 50:25.810 That's like saying sine squared cosine squared is 1, 50:25.809 --> 50:28.219 but you don't look it up. 50:28.219 --> 50:29.329 That's something you know. 50:29.329 --> 50:31.999 What you look up is your Social Security number or mother's 50:32.003 --> 50:32.653 maiden name. 50:32.650 --> 50:34.460 You're allowed to forget those things. 50:34.460 --> 50:35.970 You look in a book. 50:35.969 --> 50:37.229 That's the name. 50:37.230 --> 50:40.350 But this you have to know because you cannot go anywhere 50:40.347 --> 50:43.577 without this because if you don't know it all the time you 50:43.579 --> 50:46.299 must have done these trigonometry calculations in 50:46.302 --> 50:47.042 school. 50:47.039 --> 50:49.539 You've got to plug in the right stuff at the right time for 50:49.536 --> 50:50.696 things to all cancel out. 50:50.699 --> 50:51.989 You cannot say, "I will look it up," 50:51.992 --> 50:53.172 because you don't know what to look up. 50:53.170 --> 50:58.480 So everything should be in your head, and the minimum you should 50:58.480 --> 51:00.840 know is this, the minimum. 51:00.840 --> 51:09.800 Therefore, I can come to this function here and I can write it 51:09.804 --> 51:13.344 in terms of-- what I'm telling you is 51:13.338 --> 51:16.598 ψ(x), which was given to us, 51:16.599 --> 51:21.949 is equal to the square root of 2/L times cosine 51:21.951 --> 51:29.531 6Πx/L, but I'm going to write it as 51:29.532 --> 51:41.452 square root of 2/L times ½e^(6Πix/L) 51:41.452 --> 51:46.422 e^(-6Πix/L). 51:46.420 --> 51:53.130 So that I will write it very explicitly as 1/√2 times 51:53.130 --> 51:59.960 e^(6Πix/L)/√L (1/√2)e^(-6Πix/L) 51:59.958 --> 52:04.008 divided by √L. 52:04.010 --> 52:08.080 In other words, what I've done is rather than 52:08.081 --> 52:13.731 doing integrals I just massaged the given function and managed 52:13.726 --> 52:18.536 to write it as a sum over normalized functions, 52:18.539 --> 52:22.579 as I said, with definite momentum with some coefficients. 52:22.579 --> 52:25.119 In other words, here it is in the form that we 52:25.123 --> 52:25.523 want. 52:25.518 --> 52:34.738 A_m e^(2Πimx/L). 52:34.739 --> 52:39.279 You agree that I have got it to the form I want? 52:39.280 --> 52:40.670 You see that? 52:40.670 --> 52:43.700 You take the cosine, write it as sum of 52:43.695 --> 52:45.915 exponentials, then put factors of 52:45.920 --> 52:48.670 √L so that that's a normalized function, 52:48.670 --> 52:52.720 and that's a normalized function, and everybody else is 52:52.724 --> 52:53.554 A. 52:53.550 --> 52:56.150 So what do you find here? 52:56.150 --> 53:00.040 What are the A's for this problem? 53:00.039 --> 53:03.419 By comparing the two what do you find are the A's in 53:03.423 --> 53:04.303 this problem? 53:04.300 --> 53:07.530 What is A_14? 53:07.530 --> 53:09.910 Let me ask you this. 53:09.909 --> 53:16.889 If you compare this to this one what m are you getting? 53:16.889 --> 53:19.299 Do that in your head. 53:19.300 --> 53:27.490 If you compare this to this one what is m? 53:27.489 --> 53:29.459 Student: 3. 53:29.460 --> 53:29.830 Prof: Pardon me? 53:29.829 --> 53:30.299 Student: 3. 53:30.300 --> 53:33.280 Prof: m is 3 for this guy, 53:33.280 --> 53:37.130 so this is really ψ_3 and this is 53:37.130 --> 53:42.320 ψ_-3 because you can see there are two momenta in 53:42.320 --> 53:43.660 the problem. 53:43.659 --> 53:46.539 And you can stare at them, you can see right away. 53:46.539 --> 53:51.819 Therefore, A_3 is 1/√2, 53:51.817 --> 53:57.327 and A_-3 is also 1/√2. 54:10.409 --> 54:19.909 All other A's are 0 because they don't have a role. 54:19.909 --> 54:22.549 So you might think every term must appear. 54:22.550 --> 54:23.420 It need not. 54:23.420 --> 54:27.440 So this is a good example that tells you only two of the m's 54:27.440 --> 54:29.690 make it to the final summation. 54:29.690 --> 54:33.100 All the other m's are 0 and they happen to come with equal 54:33.103 --> 54:34.903 coefficients, 1 over root 2. 54:34.900 --> 54:37.700 The square of that is 1 over 2, and you can see these 54:37.697 --> 54:39.577 probabilities nicely add up to 1. 54:39.579 --> 54:43.089 I told you if you normalize the initial function the probability 54:43.092 --> 54:44.992 for everything will add up to 1. 54:44.989 --> 54:47.209 So this is a particle. 54:47.210 --> 54:50.590 If a particle is in a wave function cosine 6Πx/L, 54:50.590 --> 54:54.490 which is a real wave function, and you can plot that guy going 54:54.487 --> 54:57.137 around the circle, it describes a particle whose 54:57.135 --> 54:58.715 momentum, if you measure, 54:58.724 --> 55:01.354 will give you only 1 of 2 answers, 55:01.349 --> 55:09.609 m = 3 is p = 2Πℏ/L times 3 or - 3 55:09.614 --> 55:14.464 plus or minus 6Πℏ/L. 55:14.460 --> 55:15.350 You can see that too. 55:15.349 --> 55:17.069 I mean, just look at this function. 55:17.070 --> 55:22.650 If you call it e^(ipx) p is 6Πℏ/L, 55:22.646 --> 55:28.436 so this particle has only two possible answers when you 55:28.436 --> 55:30.686 measure momentum. 55:30.690 --> 55:34.040 So it is not as good as the single exponential which has 55:34.043 --> 55:35.633 only one momentum in it. 55:35.630 --> 55:39.070 This is made up of two possible momenta, but you won't get 55:39.072 --> 55:40.042 anything else. 55:40.039 --> 55:44.229 You will not get any other momentum if you measure this. 55:44.230 --> 55:48.100 So if you got m = 14 as a momentum there's something 55:48.096 --> 55:48.626 wrong. 55:48.630 --> 55:54.590 It's still probabilities, but it tells you that there is 55:54.585 --> 55:58.805 non-0 probability only for these two. 55:58.809 --> 56:02.299 Now in a minute I will take on a more difficult problem where 56:02.300 --> 56:05.860 you cannot look at the answer, you cannot look at the function 56:05.860 --> 56:08.930 ψ and just by fiddling with it bring it to this form. 56:08.929 --> 56:09.609 You understand? 56:09.610 --> 56:12.930 It is very fortunate for you that I gave you cosine which is 56:12.932 --> 56:16.542 just the sum of two exponentials so the two what are called plane 56:16.536 --> 56:20.026 wave exponentials are staring at you and you pick them up. 56:20.030 --> 56:23.140 I can write other functions, crazy functions for which you 56:23.139 --> 56:26.139 will have to do the integral to find the coefficient. 56:26.139 --> 56:30.629 But I'm going to tell you one other postulate of quantum 56:30.630 --> 56:31.610 mechanics. 56:31.610 --> 56:34.060 In the end I will assemble all the postulates for you. 56:34.059 --> 56:35.709 I'm going to tell you one more postulate. 56:35.710 --> 56:39.110 It's called the measurement postulate. 56:39.110 --> 56:44.250 The measurement postulate says that if you make a measurement, 56:44.250 --> 56:48.010 and you found the particle to be at a certain location 56:48.007 --> 56:49.997 x, then right after the 56:49.996 --> 56:53.566 measurement the wave function of the particle will be a spike at 56:53.574 --> 56:56.704 the point x because you know that you found it at 56:56.699 --> 57:00.159 x it means if that has any meaning at all if you repeat 57:00.164 --> 57:03.524 the measurement immediately afterwards you've got to get the 57:03.516 --> 57:04.706 same answer. 57:04.710 --> 57:08.530 Therefore, your initial function could have looked like 57:08.525 --> 57:12.765 that, but after the measurement it collapses to a function at 57:12.766 --> 57:15.096 the point where you found it. 57:15.099 --> 57:17.539 This is called the collapse of the wave function. 57:17.539 --> 57:22.409 It goes from being able to be found anywhere to being able to 57:22.409 --> 57:25.979 be found only where you found it just now. 57:25.980 --> 57:28.030 It won't stay that way for long, but right after 57:28.030 --> 57:29.560 measurement that's what it'll be. 57:29.559 --> 57:32.999 But the state of the system changes following the 57:32.996 --> 57:33.996 measurement. 57:34.000 --> 57:36.700 And if you measured x it'll turn into a wave 57:36.697 --> 57:39.557 function with well defined x which we know is a 57:39.559 --> 57:42.419 spike at x equal to wherever you found it. 57:42.420 --> 57:47.860 Similarly, if you measured momentum and you found it at-- 57:47.860 --> 57:49.960 if you measure momentum, first of all you'll get only 57:49.960 --> 57:52.530 one of two answers, m = 3 or m = -3. 57:52.530 --> 57:56.260 If you got m = 3 the state after the measurement will 57:56.264 --> 57:57.344 reduce to this. 57:57.340 --> 57:59.500 This guy will be gone. 57:59.500 --> 58:04.680 This will be the state. 58:04.679 --> 58:07.939 So from being able to have two momenta which are equal and 58:07.938 --> 58:11.428 opposite the act of measurement will force it to be one or the 58:11.427 --> 58:11.997 other. 58:12.000 --> 58:14.280 It can give you either one, but once you've got it that's 58:14.280 --> 58:14.810 the answer. 58:14.809 --> 58:16.199 It's like the double slit. 58:16.199 --> 58:18.409 It can be here and it can be there. 58:18.409 --> 58:20.769 It is not anywhere in particular, but if you shine 58:20.766 --> 58:23.316 light and you catch it, right after the measurement it 58:23.317 --> 58:25.287 is in front of one slit or the other. 58:25.289 --> 58:26.929 Think of this as double slit. 58:26.929 --> 58:30.179 There's some probability for 3 and some for -3, 58:30.177 --> 58:33.987 but if you catch it at 3 it'll collapse to this one. 58:33.989 --> 58:37.599 So what happens is in the sum over many terms the answer will 58:37.597 --> 58:40.967 correspond to one of them, and whichever one you got only 58:40.965 --> 58:42.765 that one term will remain. 58:42.768 --> 58:46.508 Everything will be deleted from the wave function. 58:46.510 --> 58:49.960 So the act of measurement filters out from the sum, 58:49.960 --> 58:53.630 the one term corresponding to the one answer that you got, 58:53.630 --> 58:57.980 this is called the collapse of the wave function. 58:57.980 --> 59:01.480 So in classical mechanics when you measure the position of a 59:01.481 --> 59:03.381 particle nothing much happens. 59:03.380 --> 59:05.700 It doesn't even know you measured it because there are 59:05.704 --> 59:08.034 ways to measure it without affecting it in any way. 59:08.030 --> 59:10.930 So if had a momentum p at a position x before 59:10.925 --> 59:13.815 the measurement it's the answer right after the measurement 59:13.822 --> 59:16.222 because you can do noninvasive measurements. 59:16.219 --> 59:20.059 In quantum theory there are no such measurements in general. 59:20.059 --> 59:23.449 In general the measurement will change the wave function from 59:23.451 --> 59:26.731 being in one of many options to the one option you got, 59:26.730 --> 59:29.070 but the answer depends on what you measure. 59:29.070 --> 59:32.040 With the same wave function on a ring, let's say, 59:32.043 --> 59:35.703 if you measure position and you found it here that'll be the 59:35.697 --> 59:36.377 answer. 59:36.380 --> 59:40.310 If you measured momentum and you got 5 it'll be something 59:40.306 --> 59:42.266 with 5 oscillations in it. 59:42.268 --> 59:44.878 So it'll collapse to that particular function and what it 59:44.882 --> 59:46.892 collapses it depends on what you measure. 59:46.889 --> 59:49.479 And for a long time I'm going to focus only on x and 59:49.478 --> 59:49.968 p. 59:49.969 --> 59:51.949 Of course there are other things you can measure and I 59:51.952 --> 59:53.302 don't want to go there right now, 59:53.300 --> 59:56.920 but if you measure x it collapses to a spike at that 59:56.922 --> 59:57.612 location. 59:57.610 --> 1:00:01.720 If you measure p it collapses to the one term 1:00:01.722 --> 1:00:05.592 wherever that was, that one e^(ipx) in the 1:00:05.594 --> 1:00:06.244 sum. 1:00:06.239 --> 1:00:09.819 So another interesting thing is the only measurement, 1:00:09.820 --> 1:00:13.890 only answers you will get in the measurement are the allowed 1:00:13.885 --> 1:00:15.465 values of momentum. 1:00:15.469 --> 1:00:18.509 You'll never get a momentum that's not allowed. 1:00:18.510 --> 1:00:22.130 And once you get one of the allowed answers there are two 1:00:22.125 --> 1:00:23.735 things I'm telling you. 1:00:23.739 --> 1:00:27.729 One is the probability you will get that answer is proportional 1:00:27.731 --> 1:00:31.081 to the square of that coefficient in the expansion of 1:00:31.079 --> 1:00:32.559 the given function. 1:00:32.559 --> 1:00:35.109 In our problem there are only two non-zero coefficients. 1:00:35.110 --> 1:00:37.470 Both happen to be 1/√2. 1:00:37.469 --> 1:00:38.639 It happened to be an equal mixture, 1:00:38.639 --> 1:00:41.309 but you can easily imagine some other problem where this is 1:00:41.306 --> 1:00:42.896 1/√6, and something that is 1:00:42.900 --> 1:00:44.300 1/√6, and something that is 1:00:44.298 --> 1:00:46.338 1/√3, they should all add up to 1 1:00:46.338 --> 1:00:48.048 when you square and add them. 1:00:48.050 --> 1:00:51.820 Then you can get all those answers with those 1:00:51.818 --> 1:00:53.188 probabilities. 1:00:53.190 --> 1:00:56.550 So the last thing I'm going to do is just one more example of 1:00:56.547 --> 1:00:59.907 this where you actually have to do an integral and you cannot 1:00:59.905 --> 1:01:02.475 just read off the answer by looking at it. 1:01:02.480 --> 1:01:10.580 Then we're done with this whole momentum thing. 1:01:10.579 --> 1:01:15.199 I will write the postulates later, so I don't want to write 1:01:15.202 --> 1:01:18.632 it in my handwriting, but one final time. 1:01:18.630 --> 1:01:20.850 Measurement of x collapses the function 1:01:20.853 --> 1:01:22.883 ψ(x) to a spike at x. 1:01:22.880 --> 1:01:25.130 Measurement of p collapses ψ 1:01:25.130 --> 1:01:28.740 to that particular plane wave with that particular p or 1:01:28.742 --> 1:01:30.462 m on the exponent. 1:01:30.460 --> 1:01:32.640 And after that that's what's taken to be. 1:01:32.639 --> 1:01:35.259 People always ask, "How do we know what state 1:01:35.257 --> 1:01:37.017 the quantum system is in?" 1:01:37.018 --> 1:01:38.938 Who tells you what ψ(x) is? 1:01:38.940 --> 1:01:40.820 It's the act of measurement. 1:01:40.820 --> 1:01:44.590 If you measure the guy and you found him at x = 5 the 1:01:44.588 --> 1:01:47.078 answer is ψ is a big spike there. 1:01:47.079 --> 1:01:49.869 If you measure momentum and you've got m = 3 the 1:01:49.865 --> 1:01:53.215 answer is that particular wave function with 3 on the exponent. 1:01:53.219 --> 1:01:58.919 So measurements are a way to prepare states. 1:01:58.920 --> 1:02:03.000 By the way, it's very important that if you had a system like 1:02:03.000 --> 1:02:06.740 this the probability for getting a certain x, 1:02:06.739 --> 1:02:10.039 say at this x, is proportional to the square 1:02:10.038 --> 1:02:11.158 of that number. 1:02:11.159 --> 1:02:14.869 Once you took the state and didn't measure x, 1:02:14.869 --> 1:02:18.139 but measured momentum it'll become one of these oscillatory 1:02:18.139 --> 1:02:20.339 functions with a definite wavelength. 1:02:20.340 --> 1:02:23.280 It's a complex exponential, but I'm showing you the real 1:02:23.284 --> 1:02:23.664 part. 1:02:23.659 --> 1:02:27.209 Now if you measure position, in fact the square of this will 1:02:27.208 --> 1:02:27.808 be flat. 1:02:27.809 --> 1:02:30.879 Remember e^(ipx) is flat. 1:02:30.880 --> 1:02:33.970 So in classical mechanics if I measure position, 1:02:33.967 --> 1:02:37.317 and I measure momentum, and I measure position again 1:02:37.317 --> 1:02:39.877 I'll keep getting the same answers. 1:02:39.880 --> 1:02:41.380 I see where it is. 1:02:41.380 --> 1:02:43.040 I see how fast it's moving. 1:02:43.039 --> 1:02:44.359 Again, I see where it is. 1:02:44.360 --> 1:02:47.980 If I do all of this in rapid succession you will get the same 1:02:47.981 --> 1:02:49.491 answer xp xp xp. 1:02:49.489 --> 1:02:52.629 In quantum theory once you measure x it'll become a 1:02:52.628 --> 1:02:54.058 big spike at that point. 1:02:54.059 --> 1:02:56.639 You can get all kinds of answers p. 1:02:56.639 --> 1:02:59.199 If you measure p you've got an answer. 1:02:59.199 --> 1:03:01.419 That answer is a new wave function which is completely 1:03:01.416 --> 1:03:01.706 flat. 1:03:01.710 --> 1:03:03.730 That means if you measure x you'll no longer get 1:03:03.728 --> 1:03:04.438 the old x. 1:03:04.440 --> 1:03:07.030 In fact you can get any x. 1:03:07.030 --> 1:03:09.970 That's why you can never filter out a state with well defined 1:03:09.969 --> 1:03:12.709 x and p because states of well defined x 1:03:12.713 --> 1:03:15.303 are very spiky, and states of well-defined 1:03:15.300 --> 1:03:18.630 p are very broad, so you cannot have it both ways. 1:03:18.630 --> 1:03:22.520 And that's what I want to show you in this final example. 1:03:22.518 --> 1:03:26.348 I'm going to take the following wave function on this ring. 1:03:26.349 --> 1:03:31.599 The function I'm going to take is, ψ is some 1:03:31.601 --> 1:03:35.951 ne^(−α|x|), mod x [ 1:03:35.952 --> 1:03:37.852 |x| ]means this is x = 0. 1:03:37.849 --> 1:03:42.129 To the right it falls exponentially and to the left it 1:03:42.132 --> 1:03:43.912 falls exponentially. 1:03:43.909 --> 1:03:45.379 Is it clear what I'm saying here? 1:03:45.380 --> 1:03:48.170 This is my ring and I'm trying to plot the function. 1:03:48.170 --> 1:03:52.280 It is highest at the origin and falls exponentially equally for 1:03:52.280 --> 1:03:54.470 positive and negative x. 1:03:54.469 --> 1:03:58.839 So that's the meaning of mod x. 1:03:58.840 --> 1:04:02.800 So how far can you go before ψ becomes negligible? 1:04:02.800 --> 1:04:06.660 Well, that's when e^(-x) is a big number. 1:04:06.659 --> 1:04:10.189 So I'm going to assume that when you go all the way around 1:04:10.186 --> 1:04:12.656 half the circle, I'm going to assume that 1:04:12.661 --> 1:04:15.261 αL is much bigger than 1. 1:04:15.260 --> 1:04:18.550 That means its function dies very quickly spreading 1:04:18.545 --> 1:04:20.775 negligible beyond some distance. 1:04:20.780 --> 1:04:24.180 How far does a function live? 1:04:24.179 --> 1:04:28.549 Roughly speaking you can go a distance Δx so that 1:04:28.552 --> 1:04:31.782 α times Δx is roughly 1. 1:04:31.780 --> 1:04:35.830 Because if you plot this exponential you ask, 1:04:35.829 --> 1:04:38.609 when does it come to say half its value or one fourth of its 1:04:38.614 --> 1:04:41.414 value, you'll find it's some number of 1:04:41.409 --> 1:04:42.709 order 1/α. 1:04:42.710 --> 1:04:50.160 So this is a particle whose position has an uncertainty of 1:04:50.157 --> 1:04:52.507 order 1/α. 1:04:52.510 --> 1:04:55.410 So you can make it very narrow in space so you know pretty much 1:04:55.414 --> 1:04:57.294 where it is or you can make it broad, 1:04:57.289 --> 1:04:58.909 but I want to consider only those problems, 1:04:58.909 --> 1:05:03.019 where even if it's broad it's dead by the time you go to the 1:05:03.018 --> 1:05:04.758 other side to the back. 1:05:04.760 --> 1:05:08.160 That's for mathematical convenience. 1:05:08.159 --> 1:05:12.229 So this is the state and I want to ask myself any question we 1:05:12.231 --> 1:05:12.911 can ask. 1:05:12.909 --> 1:05:16.059 First question I can ask is if I look for its position what 1:05:16.059 --> 1:05:16.819 will I find? 1:05:16.820 --> 1:05:18.280 I think we have done it many, many times. 1:05:18.280 --> 1:05:26.620 You square the guy you get n^(2)e^(-2α|x|). 1:05:26.619 --> 1:05:27.529 So that's the shape. 1:05:27.530 --> 1:05:28.790 That shape looks the same. 1:05:28.789 --> 1:05:31.739 If you square an exponential you get another exponential. 1:05:31.739 --> 1:05:38.949 But now let me demand that this integral dx be equal to 1:05:38.947 --> 1:05:39.417 1. 1:05:39.420 --> 1:05:41.230 So what is that integral? 1:05:41.230 --> 1:05:44.370 I hope you can see that this function is an even function of 1:05:44.369 --> 1:05:46.339 x because it's mod x. 1:05:46.340 --> 1:05:52.450 So it's double the answer I get for positive x. 1:05:52.449 --> 1:05:55.069 Oh yeah, sorry, not minus infinity. 1:05:55.070 --> 1:05:59.520 It's −L/2 to L/2. 1:05:59.518 --> 1:06:03.058 You can go this way L/2 and we can go that way 1:06:03.063 --> 1:06:03.953 L/2. 1:06:03.949 --> 1:06:09.799 So it's n^(2) is 2 times e to the -α 1:06:09.800 --> 1:06:13.700 x 2α x dx. 1:06:13.699 --> 1:06:15.169 Student: Should it be L over 2? 1:06:15.170 --> 1:06:16.050 Prof: Pardon me? 1:06:16.050 --> 1:06:17.830 Student: Should it be L over 2. 1:06:17.829 --> 1:06:20.619 Prof: Yes, thank you. 1:06:20.619 --> 1:06:24.919 So I'm going to now assume that in the upper limit of the 1:06:24.918 --> 1:06:29.908 integration instead of going up to L/2 I go to infinity. 1:06:29.909 --> 1:06:33.809 It doesn't matter because this guy is dead long before that. 1:06:33.809 --> 1:06:35.099 That's why I made that choice. 1:06:35.099 --> 1:06:40.459 So that I'm going to write this 2 times N^(2) times 0 to 1:06:40.463 --> 1:06:43.583 infinity e^(-2αx) dx. 1:06:43.579 --> 1:06:45.289 That's a pretty trivial integral. 1:06:45.289 --> 1:06:47.889 It's just 1/2α. 1:06:47.889 --> 1:06:49.559 If you want I will write it out. 1:06:49.559 --> 1:06:54.919 It's e^(-2αx)/-2α 1:06:54.918 --> 1:06:59.238 from 0 to infinity. 1:06:59.239 --> 1:07:01.659 At the upper limit when you put infinity you get 0. 1:07:01.659 --> 1:07:04.499 At the lower limit when you put x = 0 you get 1. 1:07:04.500 --> 1:07:09.870 There's a minus sign from this and you get 1:07:09.867 --> 1:07:12.877 N^(2)/α. 1:07:12.880 --> 1:07:18.640 It should be 1, or N is equal to the 1:07:18.637 --> 1:07:20.967 √α. 1:07:20.969 --> 1:07:23.839 So my normalized wave function, this is the first order of 1:07:23.835 --> 1:07:30.125 business, is square root of α 1:07:30.125 --> 1:07:36.415 e^(−α|x )^(|). 1:07:36.420 --> 1:07:38.050 I just squared it and I integrated it. 1:07:38.050 --> 1:07:41.130 The only funny business I did was instead of cutting off the 1:07:41.130 --> 1:07:44.260 upper integral at L/2 I cut if off at infinity because 1:07:44.264 --> 1:07:46.884 e^(−L/2) is e to the minus nine 1:07:46.876 --> 1:07:48.306 million, let's say. 1:07:48.309 --> 1:07:51.469 So I don't care if it's nine million or infinity. 1:07:51.469 --> 1:07:55.489 To make the life simpler I just did it that way. 1:07:55.489 --> 1:08:02.729 Now I want to ask you, what is A(p)? 1:08:02.730 --> 1:08:07.980 A(p), the coefficient of the 1:08:07.981 --> 1:08:15.861 expansion remember is e^(−ipx/ℏ)/√L 1:08:15.858 --> 1:08:24.038 times ψ(x) dx from −L/2 to 1:08:24.043 --> 1:08:26.673 L/2. 1:08:26.670 --> 1:08:30.120 Now I'm going to work with p rather than m. 1:08:30.119 --> 1:08:31.209 I will go back and forth. 1:08:31.210 --> 1:08:34.230 You should use to the notion that the momentum can be either 1:08:34.233 --> 1:08:37.263 labeled by the actual momentum or the quantum number m which 1:08:37.256 --> 1:08:39.866 tells you how much momentum you have in multiples of 1:08:39.869 --> 1:08:41.099 2Πℏ/m. 1:08:41.100 --> 1:08:42.710 So you've got to do this integral. 1:08:42.710 --> 1:08:44.650 So let's write this integral. 1:08:44.649 --> 1:08:51.869 This looks like −L/2 to L/2. 1:08:51.868 --> 1:08:59.868 In fact I'm going to change this integral to minus infinity 1:08:59.867 --> 1:09:07.037 to plus infinity because this function e^(ipx/ℏ) 1:09:07.037 --> 1:09:13.377 times e^(−α|x|) dx. 1:09:13.380 --> 1:09:16.600 Do you understand that these limits can be made to be plus 1:09:16.604 --> 1:09:20.114 and minus infinity because area under a graph that's falling so 1:09:20.113 --> 1:09:22.233 rapidly, whether it's between minus and 1:09:22.225 --> 1:09:24.285 plus L/2 or minus and plus infinity, 1:09:24.289 --> 1:09:25.509 is going to be the same. 1:09:25.510 --> 1:09:29.890 It's just that this integral is so much easier to do. 1:09:29.890 --> 1:09:34.700 Now you cannot jump out and do this integral because it's a mod 1:09:34.698 --> 1:09:35.938 x here. 1:09:35.939 --> 1:09:38.609 So mod x is not x, it is x when 1:09:38.610 --> 1:09:41.440 it's positive and it's -x when it's negative. 1:09:41.439 --> 1:09:44.199 So you've got to break this integral into two parts. 1:09:44.198 --> 1:09:49.148 One part where x is positive from 0 to infinity, 1:09:49.150 --> 1:09:52.730 I'm sorry, I also forgot a root, α 1:09:52.726 --> 1:09:55.016 and A√L. 1:09:55.020 --> 1:09:56.560 Do you see that? 1:09:56.560 --> 1:10:04.060 So this is really square root of α/L times 1:10:04.060 --> 1:10:12.120 e^(-αx) e^(−ipx/ℏ) dx 1:10:12.118 --> 1:10:19.898 plus another integral from minus infinity to 0 e^( 1:10:19.899 --> 1:10:27.539 αx) times e^(−ipx/ℏ) dx. 1:10:27.538 --> 1:10:30.048 I split the integral into two parts. 1:10:30.050 --> 1:10:31.760 So I didn't make a mistake here. 1:10:31.760 --> 1:10:35.810 This really is e^( αx) because x is 1:10:35.805 --> 1:10:36.625 negative. 1:10:36.630 --> 1:10:38.710 So what one does in such situations, 1:10:38.710 --> 1:10:40.740 I'm going to do it quickly and you can go home and check it, 1:10:40.738 --> 1:10:43.228 just calculus, change the variable from 1:10:43.228 --> 1:10:45.518 x to -x everywhere. 1:10:45.520 --> 1:10:49.100 In the terms of new variable this will make a -x. 1:10:49.100 --> 1:10:51.310 That'll become x. 1:10:51.310 --> 1:10:54.180 dx will become minus of the new variable. 1:10:54.180 --> 1:10:56.740 The limits will be plus infinity to 0, 1:10:56.739 --> 1:11:00.339 and you can flip that for another change of sign 0 to 1:11:00.340 --> 1:11:01.240 infinity. 1:11:01.238 --> 1:11:03.368 So that was a very rapid slight-of-hand, 1:11:03.368 --> 1:11:05.168 but I don't want to delay that. 1:11:05.170 --> 1:11:08.900 This is just--you go home and if you want check that if 1:11:08.904 --> 1:11:11.814 x goes to -x you get that. 1:11:11.810 --> 1:11:17.200 So you notice this is the complex conjugate of this one. 1:11:17.198 --> 1:11:19.978 Whatever function I'm integrating here is the 1:11:19.979 --> 1:11:23.329 conjugate of it because this is real, αx, 1:11:23.327 --> 1:11:25.977 and -ipx has become ipx. 1:11:25.979 --> 1:11:29.359 So if I find the first part of the integral I just take that 1:11:29.363 --> 1:11:31.373 times its conjugate and I'm done. 1:11:31.369 --> 1:11:33.219 So what do I get for that? 1:11:33.220 --> 1:11:37.880 I get square root of α/L times-- 1:11:37.880 --> 1:11:43.240 remember integral e^(-αx) 1:11:43.244 --> 1:11:48.044 dx from 0 to infinity is 1/α, 1:11:48.038 --> 1:11:55.768 but what I have here is dx e^(-α) ip/ℏ 1:11:55.769 --> 1:12:05.269 x_0 to infinity plus the complex conjugate. 1:12:05.270 --> 1:12:08.580 Now you may be very nervous about doing this integral with a 1:12:08.582 --> 1:12:11.952 complex number in it because real we all know the integral is 1:12:11.949 --> 1:12:14.139 just 1/α e^(-α). 1:12:14.140 --> 1:12:17.220 It turns out that it's true even if it's got an imaginary 1:12:17.220 --> 1:12:19.860 part as long as you have a positive real part. 1:12:19.859 --> 1:12:22.159 In other words, the answer here doesn't depend 1:12:22.161 --> 1:12:23.441 on this guy being real. 1:12:23.439 --> 1:12:29.139 So it's really α over L times 1 over 1:12:29.141 --> 1:12:35.561 α ip/ℏ plus a complex conjugate which is 1:12:35.557 --> 1:12:40.427 α − ip/ℏ. 1:12:40.430 --> 1:12:45.600 Now you should be able to combine these two denominators 1:12:45.595 --> 1:12:51.045 and you get square root of α/L divided by α^(2) 1:12:51.045 --> 1:12:56.395 plus p^(2) over ℏ^(2) times 2α. 1:12:56.399 --> 1:12:58.649 Again, this is something you can go and check, 1:12:58.653 --> 1:13:01.463 but I don't want to wait until everyone can do this thing 1:13:01.456 --> 1:13:03.756 because I want to tell you the punch line. 1:13:03.760 --> 1:13:05.730 So this is what it looks like. 1:13:05.729 --> 1:13:09.089 A(p) looks like a whole bunch of numbers I'm not going 1:13:09.086 --> 1:13:11.656 to worry about, but look at the denominator. 1:13:11.658 --> 1:13:15.438 It's α^(2) p^(2) over ℏ^(2), 1:13:15.443 --> 1:13:18.843 or if you want multiply by ℏ^(2). 1:13:18.840 --> 1:13:23.600 There are some other numbers I'm not interested in. 1:13:23.600 --> 1:13:24.980 The numbers are not important. 1:13:24.979 --> 1:13:29.739 How does it vary with p is all I'm asking you to think 1:13:29.743 --> 1:13:30.383 about. 1:13:30.380 --> 1:13:34.840 I'm sorry, A(p), this is just A(p), 1:13:34.836 --> 1:13:39.756 but I want the A(p) squared that looks like the 1:13:39.756 --> 1:13:41.516 square of this. 1:13:41.520 --> 1:13:46.820 All I want you to notice is that this function is peaked at 1:13:46.818 --> 1:13:52.298 p = 0 and falls very rapidly as p increases. 1:13:52.300 --> 1:13:54.790 When p is 0 you've got the biggest height. 1:13:54.788 --> 1:13:57.478 When does it become half as big or one fourth as big? 1:13:57.479 --> 1:14:01.169 Roughly when p^(2) is equal to h^(2)α^(2) 1:14:01.172 --> 1:14:04.562 because that's when these numbers become comparable, 1:14:04.560 --> 1:14:09.320 therefore when p is ℏα this function 1:14:09.322 --> 1:14:14.592 will have a denominator which is twice what it had here or maybe 1:14:14.586 --> 1:14:15.836 one fourth. 1:14:15.840 --> 1:14:18.120 I'm not worried about factors like 1 and 2. 1:14:18.118 --> 1:14:22.628 The point is in momentum space, in momentum you can get all 1:14:22.628 --> 1:14:26.838 kinds of values of p, but the odds decrease very 1:14:26.840 --> 1:14:30.440 rapidly for p bigger than ℏα. 1:14:30.439 --> 1:14:33.299 So the most likely value is 0, but that's the spread. 1:14:33.300 --> 1:14:36.620 And Δp is ℏα, 1:14:36.618 --> 1:14:39.908 or α times Δp is ℏ, 1:14:39.908 --> 1:14:45.738 and that is the uncertainty principle because α 1:14:45.735 --> 1:14:48.645 is just Δx. 1:14:48.649 --> 1:14:50.189 By the way, I will publish these notes too, 1:14:50.192 --> 1:14:52.252 so you don't have to worry if you didn't write everything 1:14:52.248 --> 1:14:52.578 down. 1:14:52.579 --> 1:14:53.759 I suggest you--yes? 1:14:53.760 --> 1:14:56.850 Student: Can you go over again what cc is? 1:14:56.850 --> 1:14:58.320 Prof: Complex conjugate. 1:14:58.319 --> 1:14:59.839 That's what I did. 1:14:59.840 --> 1:15:03.160 Whatever number this one is the other guy is obtained by 1:15:03.158 --> 1:15:05.148 changing i to -i. 1:15:05.149 --> 1:15:07.379 Look, all I want you to notice is this. 1:15:07.380 --> 1:15:12.850 I took a function whose width is roughly 1/α. 1:15:12.850 --> 1:15:15.560 Then I looked at what kind of momenta I can get. 1:15:15.560 --> 1:15:19.780 Then I find that the narrower the function bigger the spread 1:15:19.780 --> 1:15:22.500 in the possible momenta you can get. 1:15:22.500 --> 1:15:25.640 So squeezing it in x broadens it out in p. 1:15:25.640 --> 1:15:27.900 And that's the origin of the uncertainty principle. 1:15:27.899 --> 1:15:29.349 It's simply a mathematical result. 1:15:29.350 --> 1:15:32.390 The functions which are narrow in x have a Fourier 1:15:32.391 --> 1:15:34.621 series which is very broad in p. 1:15:34.618 --> 1:15:37.638 The quantum mechanics relates p to momentum and 1:15:37.636 --> 1:15:39.796 therefore the uncertainty principle. 1:15:39.800 --> 1:15:42.040 So anyway, I'll give you some homework on this, 1:15:42.041 --> 1:15:44.671 and you can also fill in the blanks of this derivation, 1:15:44.671 --> 1:15:46.281 which I think is very useful. 1:15:46.279 --> 1:15:50.999