CHEM 125a - Lecture 10 - Reality and the Orbital Approximation

Lecture 10 - Reality and the Orbital Approximation

Overview

In discussions of the Schrödinger equation thus far, the systems described were either one-dimensional or involved a single electron. After discussing how increased nuclear charge affects the energies of one-electron atoms and then discussing hybridization, this lecture finally addresses the simple fact that multi-electron systems cannot be properly described in terms of one-electron orbitals.

Resources

Professor McBride's website resource for CHEM 125 (Fall 2008)

http://webspace.yale.edu/chem125_oyc/#L10

This website may include third-party materials pertaining to relevant topics, provided for the user's convenience. Yale does not control or take responsibility for the content of any off-site pages or linked sites.

Assignment

Reading assignments, problem sets, PowerPoint presentations, and other resources for this lecture can be accessed from Professor McBride's on-campus course website, which was developed for his Fall 2008 students. Please see Resources section below.

Course Media

Transcript

html

Audio

mp3

Low Bandwidth Video

mov [100MB]

High Bandwidth Video

mov [500MB]